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    Thermoplastic molding materials based on special graft rubber components
    1.
    发明授权
    Thermoplastic molding materials based on special graft rubber components 失效
    基于特殊接枝橡胶成分的热塑性成型材料

    公开(公告)号：US06828380B2

    公开(公告)日：2004-12-07

    申请号：US10220707

    申请日：2002-11-21

    申请人： Liqing-Lee Sun ,  Eckhard Wenz ,  Herbert Eichenauer ,  Stefan Moss ,  Heinrich Alberts ,  Hans-Bernhard Hauertmann ,  Karl Zabrocki ,  Hans-Erich Gasche ,  Ulrich Jansen

    发明人： Liqing-Lee Sun ,  Eckhard Wenz ,  Herbert Eichenauer ,  Stefan Moss ,  Heinrich Alberts ,  Hans-Bernhard Hauertmann ,  Karl Zabrocki ,  Hans-Erich Gasche ,  Ulrich Jansen

    IPC分类号： C08L5502

    CPC分类号： C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08L55/02 ,  C08L2666/14 ,  C08L2666/02

    摘要： A molding composition having good surface gloss, high elongation at break and good thermoplastic processability is disclosed. The composition contains (A) a graft polymer that is obtained by free-radical polymerization of resin-forming vinyl monomers in the presence of rubber in latex form, (B) a copolymer of styrene and acrylonitrile and an optional (C) a resin selected from the group consisting of polycarbonates, polyester-carbonates, polyesters and polyamides. The preparation of the graft polymer is characterized in that (i) before the start of the grafting polymerization reaction the rubber latex is brought to a pH of 9 to 11, (ii) the redox initiator components are employed in amounts of 0.1 to 2.5 wt. % (based on the monomers metered in) and (iii) during the entire grafting polymerization reaction the pH remains constant±0.5 and in the range of 11.0 to 8.8, and (iv) the temperature difference between the start and end of the reaction is at least 10° C.

    摘要翻译： 公开了具有良好的表面光泽度，高断裂伸长率和良好的热塑性加工性能的成型组合物。 该组合物含有（A）通过在胶乳形式的橡胶存在下形成树脂的乙烯基单体的自由基聚合获得的接枝聚合物，（B）苯乙烯和丙烯腈的共聚物和任选的（C）树脂选择 由聚碳酸酯，聚酯 - 碳酸酯，聚酯和聚酰胺组成。 接枝聚合物的制备的特征在于：（i）在接枝聚合反应开始之前，使橡胶胶乳的pH值达到9至11，（ii）氧化还原引发剂组分的用量为0.1至2.5重量％ 。 ％（基于计量的单体）和（iii）在整个接枝聚合反应期间，pH保持恒定±0.5且在11.0至8.8的范围内，和（iv）反应开始和结束之间的温度差为 至少10℃

    ABS moulding material with improved workability and a high lustre
    2.
    发明授权
    ABS moulding material with improved workability and a high lustre 失效
    ABS成型材料具有改善的加工性和高光泽

    公开(公告)号：US07074854B2

    公开(公告)日：2006-07-11

    申请号：US10204137

    申请日：2001-02-12

    申请人： Herbert Eichenauer ,  Eckhard Wenz ,  Heinrich Alberts ,  Ulrich Jansen ,  Hans-Erich Gasche

    发明人： Herbert Eichenauer ,  Eckhard Wenz ,  Heinrich Alberts ,  Ulrich Jansen ,  Hans-Erich Gasche

    IPC分类号： C08L51/04

    CPC分类号： C08L51/04 ,  C08F279/02 ,  C08F279/04 ,  C08L25/12 ,  C08L55/02 ,  C08L67/00 ,  C08L69/00 ,  C08L77/00 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/14 ,  C08L2666/04

    摘要： A Polymer compositions that features high degree of toughness, very good processability and extremely high gloss is disclosed. The composition contains (I) a graft rubber polymer obtained by emulsion polymerization of styrene and acrylonitrile in the presence of a mixture of (A) a butadiene polymer latex having a mean particle diameter d50≦250 nm, a particle size distribution width of 20 to 80 nm and a gel content of 30 to 95 wt. %, (B) a butadiene polymer latex with a mean particle diameter d50>250 to 350 nm, a particle size distribution width of 30 to 100 nm and gel content of 30 to 80 wt. %, and (C) a butadiene polymer latex (C) with a mean particle diameter d50>350 nm, a particle size distribution width of 40 to 150 nm, and a gel content of 50 to 95 wt. %. and (II) a rubber-free copolymer of styrene and acrylonitrile. At least one of (A), (B) and (C) is a product of seed polymerization.

    摘要翻译： 公开了具有高韧性，非常好的加工性和极高光泽度的聚合物组合物。 该组合物含有（I）通过苯乙烯和丙烯腈的乳液聚合得到的接枝橡胶聚合物，该混合物是（A）平均粒径d <50％= 250nm的丁二烯聚合物胶乳 ，粒径分布宽度为20〜80nm，凝胶含量为30〜95wt。 ％，（B）平均粒径d <50> 250〜350nm，粒径分布宽度为30〜100nm，凝胶含量为30〜80重量％的丁二烯聚合物胶乳。 ％，和（C）平均粒径d <50 <350纳米，粒度分布宽度为40〜150nm，凝胶含量为50〜95的丁二烯聚合物胶乳（C） 重量 ％。 和（II）苯乙烯和丙烯腈的无橡胶共聚物。 （A），（B）和（C）中的至少一种是种子聚合的产物。

    Elastic-thermoplastic graft polymers prepared by multi-stage free radical polymerization
    4.
    发明授权
    Elastic-thermoplastic graft polymers prepared by multi-stage free radical polymerization 有权

    公开(公告)号：US06569951B2

    公开(公告)日：2003-05-27

    申请号：US09967311

    申请日：2001-09-28

    申请人： Herbert Eichenauer ,  Hans-Erich Gasche ,  Ulrich Jansen

    发明人： Herbert Eichenauer ,  Hans-Erich Gasche ,  Ulrich Jansen

    IPC分类号： C08F27904

    CPC分类号： C08L55/02 ,  C08F279/02 ,  C08F279/04 ,  C08L51/04 ,  C08L2666/14 ,  C08L2666/02

    摘要： An elastic-thermoplastic graft polymer prepared by a multi-stage free radical polymerization is described. The elastic-thermoplastic graft polymer is prepared by polymerizing (i) one or more monomers containing vinyl groups, and (ii) at least one molecular weight regulating compound, in the presence of (iii) at least one rubber in latex form. The ratio of monomers (M) to the molecular weight regulating compound (MWR) is altered throughout the various stages of the polymerization method. The M:MWR ratio is: from 50:1 to 400:1 in the first stage; from 100:1 to 800:1 in the second stage; and from 200:1 to 2000:1 in the third stage of the polymerization. In at least one further reaction stage of the polymerization, the monomers, in the absence of the molecular weight regulating compound, are polymerized in the presence of the rubber. This further reaction stage occurs before the first stage and/or after the third stage of the polymerization. The multi-stage polymerization is conducted such that: M:MWR (first stage)≦M:MWR (second stage)

    Polymer compositions with an improved constancy of characteristics
    9.
    发明授权
    Polymer compositions with an improved constancy of characteristics 有权
    具有改善的特性恒定性的聚合物组合物

    公开(公告)号：US06767964B2

    公开(公告)日：2004-07-27

    申请号：US10204147

    申请日：2002-08-16

    申请人： Herbert Eichenauer ,  Adolf Schmidt ,  Ulrich Jansen

    发明人： Herbert Eichenauer ,  Adolf Schmidt ,  Ulrich Jansen

    IPC分类号： C08G6348

    CPC分类号： C08L51/04 ,  C08F279/04 ,  C08L25/12 ,  C08L55/02 ,  C08L2205/02 ,  C08L2666/24 ,  C08L2666/02

    摘要： A thermoplastic molding composition that features constancy of properties, especially toughness and processability is disclosed. The composition contains a first graft rubber polymer that is a product of emulsion polymerisation of styrene and acrylonitrile in the presence of a butadiene polymer latex (A) with a mean particle diameter d50 of 80 to 220 nm, a second graft rubber polymer obtained by emulsion polymerisation of styrene and acrylonitrile in the presence of a butadiene polymer latex (B) with a mean particle diameter d50 of 340 to 480 nm, and a rubber-free copolymer of styrene and acrylonitrile. Importantly, the butadiene polymer latex (A) is the product of seed polymerization using a seed latex with a mean particle diameter of 10 to 100 nm, and the butadiene polymer latex (B) is the product of seed polymerisation using the butadiene polymer latex (A) as seed latex.

    ABS type thermoplastic moulding compounds
    10.
    发明授权
    ABS type thermoplastic moulding compounds 失效
    ABS型热塑性成型料

    公开(公告)号：US5719232A

    公开(公告)日：1998-02-17

    申请号：US424656

    申请日：1995-04-19

    申请人： Adolf Schmidt ,  Herbert Eichenauer ,  Ulrich Jansen

    发明人： Adolf Schmidt ,  Herbert Eichenauer ,  Ulrich Jansen

    IPC分类号： C08F2/22 ,  C08L55/02

    CPC分类号： C08L55/02 ,  Y10S525/902

    摘要： ABS type thermoplastic moulding compounds obtainable by A) producing a rubber latex with an average particle diameter d.sub.50 of 30 to 160 nm and a gel content of 75 to 100 wt. % B) emulsion polymerization of an amount of butadiene and optionally up to 50 wt. % (with reference to the total amount of monomer in stage B) of a comonomer in the presence of the rubber obtained in stage A, such that a rubber latex (B) with an average particle diameter d.sub.50 =220 to 330 nm and a gel content of 25 to 70 wt. % is produced, C) emulsion polymerization of 40 to 95 parts by wt. of a mixture of styrene and acrylonitrile, which optionally contains up to 50 wt. % (with reference to the total amount of monomers used in stage C) of one or more comonomers, in the presence of 5 to 60 parts by wt. (with reference to the solids) of the rubber obtained in stage B by introducing the monomer in such a way that 55 to 90 wt. % of the monomers are added within the first half of the total monomer introduction time, and D) mixing the polymer obtained in stage C, preferably after first converting it into a powder, with at least one thermoplastic vinyl resin.

    摘要翻译： ABS型热塑性成型化合物，其可通过以下方法得到：A）制备平均粒径d50为30〜160nm，凝胶含量为75〜100重量％的橡胶胶乳。 B）一定量的丁二烯的乳液聚合和任选的至多50wt。 在阶段A中获得的橡胶存在下，共聚单体的％（相对于阶段B中的单体的总量），使得平均粒径d 50 = 220〜330nm的橡胶胶乳（B）和凝胶 含量为25〜70wt。 产生％，C）乳液聚合40〜95重量份。 的苯乙烯和丙烯腈的混合物，其任选地含有至多50重量％ 在5至60重量份存在下，一种或多种共聚单体的％（相对于阶段C中使用的单体的总量）。 （相对于固体），通过以55〜90重量％的比例引入单体，得到阶段B中得到的橡胶。 在全部单体引入时间的前半部分内加入％的单体，和D）将在阶段C中获得的聚合物，优选在首先将其转化为粉末之后，与至少一种热塑性乙烯基树脂混合。