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    Hydroxy-terminated copolyformals of fluorodiols with nitrodiols
    1.
    依法登记的发明
    Hydroxy-terminated copolyformals of fluorodiols with nitrodiols 失效
    氟代二醇与硝基二醇的羟基封端的共聚体

    公开(公告)号：USH730H

    公开(公告)日：1990-02-06

    申请号：US389211

    申请日：1989-08-02

    Applicant: Lori A. Nock ,  Horst G. Adolph

    Inventor： Lori A. Nock ,  Horst G. Adolph

    IPC: C08G4/00

    CPC classification number: C08G4/00

    Abstract: Energetic dihydroxy-terminated copolyformals which are formed from formalyde and fluorodiol and nitrodiol comonomers where the fluorodiol is HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF(CF.sub.3)OCF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF.sub.2 OCF.sub.2 CF.sub.2 OCF.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.2 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.4 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.6 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.8 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.10 CH.sub.2 CH.sub.2 OH, or mixtures thereof, and the nitro diol is HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 OH, HOCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 OH, or mixtures thereof.

    Copolyformals of 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane and polynitroalkyl diols
    2.
    依法登记的发明
    Copolyformals of 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane and polynitroalkyl diols 失效
    1,2-BIS（2-羟基乙基）-1,2-二胺十二烷和多羟基烷基二醇的共聚物

    公开(公告)号：USH786H

    公开(公告)日：1990-06-05

    申请号：US389239

    申请日：1989-08-02

    Applicant: Horst G. Adolph ,  Lori A. Nock

    Inventor： Horst G. Adolph ,  Lori A. Nock

    IPC: C08G4/00

    CPC classification number: C08G4/00

    Abstract: Dihydroxy-terminated copolyformals formed fromA. formaldehyde andB. a diol comonomer mixture of(1) 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane(12) and(2) a nitrodiol which is HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 , HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 OH, HOCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 N(NO.sub.2)CH.sub.2 CH.sub.2 OH, or mixtures thereof. A fraction of the nitrodiol may be replaced with an equal number of moles of a fluorodiol which is HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF(CF.sub.3)OCF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, or mixtures thereof.

    Copolyformals of 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane(12) and polyfluoroalkyl diols
    3.
    依法登记的发明
    Copolyformals of 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane(12) and polyfluoroalkyl diols 失效
    1,2-双（2-羟基乙基）-1,2-二胺十二硼烷（12）和聚氟代醇二醇的共聚物

    公开(公告)号：USH784H

    公开(公告)日：1990-06-05

    申请号：US389217

    申请日：1989-08-02

    Applicant: Horst G. Adolph ,  Lori A. Nock

    Inventor： Horst G. Adolph ,  Lori A. Nock

    IPC: C08G4/00 ,  C08G6/00

    CPC classification number: C08G4/00

    Abstract: Dihydroxy-terminated copolyformals formed fromA. formaldehyde andB. a diol comonomer mixture of(1) 1,2-bis(2-hydroxyethyl)-1,2-dicarbadodecaborane(12) and(2) a fluorodiol which is HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 HOCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF(CF.sub.3)OCF.sub.2 CF.sub.2 CF.sub.2 CH.sub.2 OH, HOCH.sub.2 CF.sub.2 OCF.sub.2 CF.sub.2 OCF.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.2 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.4 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.6 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.8 CH.sub.2 CH.sub.2 OH, HOCH.sub.2 CH.sub.2 (CF.sub.2).sub.10 CH.sub.2 CH.sub.2 OH, or mixtures thereof. A fraction of the fluorodiol may be replaced with an equal number of moles of a suitable nitrodiol.

    Bis (dinitropropyl) formal/dinitrobutyl dinitropropyl formal plasticizer
    4.
    发明授权
    Bis (dinitropropyl) formal/dinitrobutyl dinitropropyl formal plasticizer 失效
    双（二硝基丙基）甲醛/二硝基丁基二硝基丙基缩甲醛增塑剂

    公开(公告)号：US4997499A

    公开(公告)日：1991-03-05

    申请号：US612838

    申请日：1984-05-22

    Applicant: Horst G. Adolph

    Inventor： Horst G. Adolph

    IPC: C06B45/10 ,  C07C205/29

    CPC classification number: C07C205/29 ,  C06B45/105

    Abstract: A new compound 2,2-dinitrobutyl 2,2-dinitropropyl formal (DNBPF),CH.sub.3 C(NO.sub.2).sub.2 CH.sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.sub.2 CH.sub.3,and a energetic plasticizer which is a 1:1 eutectic mixture of DNBPF and bis(2,2-dinitropropyl) formal.

    Abstract translation: 新型化合物2,2-二硝基丁基2,2-二硝基丙基（DNBPF），CH 3 C（NO 2）2 CH 2 CH 2 OCH 2 OCH 2 C（NO 2）2 CH 3，以及能量增塑剂，其为DNBPF和双（2,2-二硝基丙基 ）正式。

    Energetic binders for plastic bonded explosives
    5.
    发明授权
    Energetic binders for plastic bonded explosives 失效
    塑料粘结炸药的能量粘合剂

    公开(公告)号：US4988397A

    公开(公告)日：1991-01-29

    申请号：US892622

    申请日：1986-04-30

    Applicant: Horst G. Adolph ,  Judah Goldwasser ,  G. William Lawrence

    Inventor： Horst G. Adolph ,  Judah Goldwasser ,  G. William Lawrence

    IPC: C06B45/10 ,  C08G2/18 ,  C08G18/56

    CPC classification number: C08G2/18 ,  C06B45/105 ,  C08G18/56

    Abstract: An energetic uncured binder composite mixture comprising(1) a hydroxy-terminated polyfluoroformal prepolymer of the general formulaHOCH.sub.2 (CF.sub.2).sub.n CH.sub.2 [OCH.sub.2 OCH.sub.2 (CF.sub.2).sub.nH.sub.2 ].sub.m OH wherein n is 3 or 4 and m is selected to provide a number average molecular weight of from about 1,000 to about 10,000 for the prepolymer; and(2) an energetic plasticizer which isbis(2,2-dinitropropyl)formal,bis(2,2-trinitroethyl)formal,bis(2-fluoro-2,2-dinitroethyl)formal,bis(2,2-difluoro-2-nitroethyl)formal,2,2-dinitropropyl 2-fluoro-2,2-dinitroethyl formal, or mixtures thereof;wherein the weight ratio of energetic plasticizer to prepolymer is from about 2:1 to about 5:1. This binder composite mixture is useful for preparing energetic plastic bonded explosives having high chemical and thermal stabilities.

    Abstract translation: 一种能量未固化的粘合剂复合材料混合物，其包含（1）通式为HOCH 2（CF 2）n CH 2 [OCH 2 OCH 2（CF 2）n CH 2] m OH的羟基封端的多氟代预聚物，其中n为3或4并且m被选择以提供数均分子量 对于预聚物为约1,000至约10,000; 和（2）能量增塑剂，其为双（2,2-二硝基丙基）甲醛，双（2,2-三硝基乙基）甲醛，双（2-氟-2,2-二硝基乙基）甲醛，双（2,2-二氟 -2-硝基乙基）甲醛，2,2-二硝基丙基2-氟-2,2-二硝基乙基甲醛或其混合物; 其中能量增塑剂与预聚物的重量比为约2:1至约5:1。 该粘合剂复合混合物可用于制备具有高化学和热稳定性的高能塑料粘结炸药。

    Acetals derived from negatively substituted aldehydes and polynitro- or halonitroethanols
    9.
    发明授权
    Acetals derived from negatively substituted aldehydes and polynitro- or halonitroethanols 失效
    衍生自负取代醛和多硝基或卤代硝基乙醇的缩醛

    公开(公告)号：US4062897A

    公开(公告)日：1977-12-13

    申请号：US640090

    申请日：1975-12-12

    Applicant: Horst G. Adolph

    Inventor： Horst G. Adolph

    IPC: C06B43/00 ,  C07C205/29 ,  C07C205/40 ,  C07C205/51 ,  C07C43/30

    CPC classification number: C06B43/00 ,  C07C205/29 ,  C07C205/40 ,  C07C205/51

    Abstract: Acetals of the formulas CHCl.sub.2 CH(OR).sub.2, CCl.sub.3 CH(OR).sub.2, .sub.2 CH(OR).sub.2, CF.sub.3 CH(OR).sub.2, RO.sub.2 CCH(OR).sub.2, and (RO).sub.2 HCCH(OR).sub.2 wherein R can be --CH.sub.2 CYZ(NO.sub.2), --CH.sub.2 CH.sub.2 CYZ(NO.sub.2), --CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3, --CH.sub.2 C(NO.sub.2).sub.2 CYZ(NO.sub.2), --CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 CYZ(NO.sub.2) or --CH.sub.2 C(NO.sub.2).sub.2 C(NO.sub.2).sub.2 CYZ(NO.sub.2) wherein Y and Z vary independently and can be Cl, F or NO.sub.2. These acetals are produced by contacting a negatively substituted aldehyde such as CHCl.sub.2 CHO, CCl.sub.3 CHO, CHF.sub.2 CHO, CF.sub.3 CHO, HO.sub.2 CCHO, or OHCCHO with a negatively substituted alcohol of the formula ROH wherein R is as defined above. Either FSO.sub.3 H, ClSO.sub.3 H, or CHF.sub.2 SO.sub.3 H, or CF.sub.3 SO.sub.3 H is used to catalyze the condensation. The acetals of this invention are useful as explosives.

    Abstract translation: 式CHCl 2 CH（OR）2，CCl 3 CH（OR）2，CHF 2 CH（OR）2，CF 3 CH（OR）2，RO 2 CCH（OR）2和（RO）2 HCH（OR）2）的缩醛，其中R可以是-CH 2 CYZ NO2），-CH2CH2CYZ（NO2），-CH2C（NO2）2CH3，-CH2C（NO2）2CYZ（NO2），-CH2C（NO2）2CH2CYZ（NO2）或-CH2C（NO2）2C（NO2） Y和Z独立变化，可以是Cl，F或NO2。 这些缩醛通过使负取代的醛如CHCl 2 CHO，CCl 3 CHO，CHF 2 CHO，CF 3 CHO，HO 2 CCHO或OHCCHO与式ROH的负取代的醇接触来制备，其中R如上定义。 使用FSO 3 H，ClSO 3 H或CHF 2 SO 3 H或CF 3 SO 3 H来催化冷凝。 本发明的缩醛作为炸药是有用的。

    2,2,2-Fluorodinitroethyl 2-nitroalkyl acetals and methods of preparation
    10.
    发明授权
    2,2,2-Fluorodinitroethyl 2-nitroalkyl acetals and methods of preparation 失效
    2,2,2-氟二硝基乙基2-硝基烷基缩醛及其制备方法

    公开(公告)号：US3962349A

    公开(公告)日：1976-06-08

    申请号：US483258

    申请日：1974-06-26

    Applicant: Horst G. Adolph

    Inventor： Horst G. Adolph

    IPC: C06B45/10 ,  C07C205/29 ,  C07C43/30

    CPC classification number: C07C205/29 ,  C06B45/105

    Abstract: Unsymmetrical nitro and fluoronitro acetals of the formulasROCH(CH.sub.3)OR'wherein R.noteq.R', but wherein both R and R' are selected from the group nsisting of-CH.sub.2 CXY(NO.sub.2), - CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3,-ch.sub.2 cuvcxy(no.sub.2), and-CH.sub.2 CUVCWZCXY(NO.sub.2),wherein X and Y vary independently and are selected from the group consisting of F and NO.sub.2, and wherein U, V, W, and Z vary independently and are selected from the group consisting of H, F, and NO.sub.2, are useful as energetic plasticizers in rocket propellants or explosives.

    Abstract translation: 式R CH（CH 3）OR'的不对称硝基和氟硝基缩醛，其中R NOTEQUAL R'，但其中R和R'均选自-CH 2 C X Y（NO 2）， - CH 2 C（NO 2）2 CH 3，-CH 2 CUVCXY（ NO 2）和-CH 2 CUVCWZCXY（NO 2），其中X和Y独立地变化并且选自F和NO 2，并且其中U，V，W和Z独立地变化，并且选自H， F和NO2可用作火箭推进剂或爆炸物中的高能增塑剂。

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