公开(公告)号：US4556684A

公开(公告)日：1985-12-03

申请号：US644409

申请日：1984-08-27

申请人： Louis T. Gunkel ,  Charles V. Juelke

发明人： Louis T. Gunkel ,  Charles V. Juelke

IPC分类号： C07F9/12 ,  C08K5/526 ,  C08K5/52

CPC分类号： C07F9/12 ,  C08K5/526

摘要： Flame retardant polyphenylene ether resin compositions are described in which the flame retardant agent is a mixture (by weight) of the following:(a) about 1.5% to about 3.0% of: ##STR1## (b) about 15.0% to about 20.0% of: ##STR2## (c) about 23.0% to about 28.0% of: ##STR3## (d) about 47.0% to about 56.0% of: ##STR4## wherein R.sub.1 and R.sub.2 are each selected from the class consisting of hydrogen, methyl and ethyl, it being understood that when one of R.sub.1 and R.sub.2 is hydrogen the other is ethyl and when one of R.sub.1 and R.sub.2 is methyl the other is methyl, the resulting two methyl groups being in the 2,4-, 2,5-, 2,3-, 3,4- and 3,5-positions, it being further understood that the ethyl groups are almost entirely in the meta (m) and para (p) positions.

摘要翻译： 描述了阻燃聚苯醚树脂组合物，其中阻燃剂是以下的混合物（重量）：（a）约1.5％至约3.0％：（b）约15.0％至约20.0％ （c）约23.0％至约28.0％：（d）约47.0％至约56.0％的：其中R 1和R 2各自选自氢，甲基 和乙基，当R1和R2中的一个是氢时，另一个是乙基，当R 1和R 2之一是甲基时，另一个是甲基，得到的两个甲基在2,4-二 ，2,3,4a和3,5位，还可以理解的是，乙基几乎全部在间位（m）和对位（p）位。

公开(公告)号：US5281741A

公开(公告)日：1994-01-25

申请号：US611555

申请日：1990-11-13

申请人： Louis T. Gunkel ,  Henry J. Barda

发明人： Louis T. Gunkel ,  Henry J. Barda

IPC分类号： C07F9/12 ,  C07F9/09

CPC分类号： C07F9/12

摘要： A process is provided for preparing an aryl diphosphate ester containing less than 5% by weight of triarylphosphate. The process reacts a solution of a dihydroxy aromatic compound and an excess of phosphorus oxychloride in a nonaqueous solvent having a boiling point greater than 110.degree. C. The excess phosphorus oxychloride and part of the solvent are distilled from the solution at atmospheric pressure and the intermediate, a diphosphotetrachloridate solution, is reacted with a monohydric aryl compound. After extracting with an aqueous, alkaline solution the product is recovered by distilling off the remaining solvent.

摘要翻译： 提供了一种制备含有少于5％（重量）磷酸三芳酯的芳基二磷酸酯的方法。 该方法使二羟基芳族化合物和过量的三氯氧化磷溶液在沸点大于110℃的非水溶剂中反应。过量的三氯氧化磷和部分溶剂在大气压下从溶液中蒸馏出，中间体 二氯苯甲酸酯溶液与一元芳基化合物反应。 用碱性水溶液萃取后，通过蒸馏剩余的溶剂回收产物。

公开(公告)号：US5206404A

公开(公告)日：1993-04-27

申请号：US873867

申请日：1992-04-27

申请人： Louis T. Gunkel ,  Douglas G. Placek ,  Michael P. Marino, Jr. ,  John Crosby ,  Sundeep G. Shankwalkar

发明人： Louis T. Gunkel ,  Douglas G. Placek ,  Michael P. Marino, Jr. ,  John Crosby ,  Sundeep G. Shankwalkar

IPC分类号： C07F9/09 ,  C07F9/12

CPC分类号： C07F9/12

摘要： The invention is a novel composition of alkylated phenyl phosphate esters comprising by weight 1% to 20% trialkylphenyl phosphate, 10% to 50% dialkylphenyl monophenyl phosphate, 15% to 60% monoalkylphenyl diphenyl phosphate and less than 2% triphenyl phosphate and a process for preparing the composition comprising passing the composition at least once through a thin film evaporator at a temperature of about 200.degree. C. to about 250.degree. C. at a pressure sufficiently less than 5 kPa to evaporate about 5% to about 30% of the composition.

公开(公告)号：US4575563A

公开(公告)日：1986-03-11

申请号：US575734

申请日：1984-02-01

申请人： Louis T. Gunkel

发明人： Louis T. Gunkel

IPC分类号： C07F9/50 ,  C07F9/53 ,  C08K5/5397

CPC分类号： C08K5/5397 ,  C07F9/5004 ,  C07F9/5304 ,  Y10S524/912

摘要： Liquid mixtures of trialkylphosphine oxides, useful as antistats in thermoplastic polymers, are obtained by alkylating excess phosphine with a mixture of higher .alpha.-olefins to give a mixture of higher alkylated phosphines and unreacted phosphine and alkylating that mixture with a lower .alpha.-olefin. This method provides a larger percentage of higher alkyl groups and a lower percentage of lower alkyl groups compared to alkylating the phosphine with all of the mixed .alpha.-olefins in a single reaction. The shift in higher alkyl groups decreases the volatility of the trialkylphosphine mixture and is an advantage when preparing plastic compositions at higher formulation temperatures.

摘要翻译： 用作热塑性聚合物中抗静电剂的三烷基氧化膦的液体混合物是通过用高级α-烯烃的混合物烷基化过量的膦得到高级烷基化膦和未反应的膦的混合物，并将该混合物与较低级α-烯烃进行烷基化而获得的。 与单一反应中的所有混合α-烯烃的膦与烷基化相比，该方法提供较大百分比的较高级烷基和较低百分比的低级烷基。 高级烷基的转变降低了三烷基膦混合物的挥发性，并且在制备温度更高的塑料组合物时是有利的。

公开(公告)号：US4981615A

公开(公告)日：1991-01-01

申请号：US396162

申请日：1989-08-21

申请人： Louis T. Gunkel

发明人： Louis T. Gunkel

IPC分类号： C07F9/12 ,  C09K21/12

CPC分类号： C09K21/12 ,  C07F9/12

摘要： A novel process is provided for producing a pure triaryl phosphate ester free from phenolics without creating an undesirable waste product. After recovery of the triaryl phosphate ester the reactio mixture residue is converted into an emulsion suitable for use as a flame retardant useful for application to carpets.

摘要翻译： 提供了一种制备不含酚类的纯三芳基磷酸酯的新方法，而不产生不需要的废产物。 在回收磷酸三芳基酯后，将反应混合物残余物转化成适合用作适用于地毯的阻燃剂的乳液。

公开(公告)号：US4766240A

公开(公告)日：1988-08-23

申请号：US42072

申请日：1987-04-24

申请人： Louis T. Gunkel ,  John Crosby

发明人： Louis T. Gunkel ,  John Crosby

IPC分类号： C07C51/083 ,  B01J27/125 ,  C07B61/00 ,  C07C51/00 ,  C07C51/373 ,  C07C65/34 ,  C07C67/00 ,  C07C59/76

CPC分类号： C07C51/373

摘要： An environmentally acceptable process is provided to synthesize a 2-(alkylbenzoyl)benzoic acid suitable for synthesizing a 2-alkylanthraquinone without further purification. Usually the crude product is isolated from the reaction mixture by a succession of steps which generate a large volume of aqueous waste. The present process eliminates or decreases these wastes and produces a product of sufficient purity for synthesizing as 2-alkylanthraquinone.

摘要翻译： 提供了一种环境可接受的方法来合成适用于合成2-烷基蒽醌的2-（烷基苯甲酰基）苯甲酸，无需进一步纯化。 通常，粗产物通过产生大量含水废物的一系列步骤从反应混合物中分离出来。 本发明方法消除或减少这些废物并产生足够纯度的产物以合成2-烷基蒽醌。

公开(公告)号：US6146610A

公开(公告)日：2000-11-14

申请号：US196881

申请日：1998-11-20

申请人： Louis T. Gunkel

发明人： Louis T. Gunkel

IPC分类号： C01B25/047 ,  C01B25/04

CPC分类号： C01B25/047

摘要： Arsenic is removed from elemental phosphorus by treating it with an oxidized form of iodine in a sufficient amount and for a sufficient time to obtain the amount of arsenic reduction desired. When iodine is the source of the oxidized iodine an oxidant is additionally used. An oxidant is optionally used when an oxidized iodine is used. The oxidant also reduces the amount of antimony present in the elemental phosphorus, and a dilute oxidant rinse removes any residual iodine source and also results in a water-white liquid phosphorus.

摘要翻译： 通过用足够量的氧化形式的碘处理从元素磷中除去砷，并持续足够的时间以获得所需的砷还原量。 当碘是氧化碘的来源时，另外使用氧化剂。 当使用氧化碘时，任选使用氧化剂。 氧化剂还可以减少元素磷中存在的锑的量，稀释的氧化剂漂洗会去除任何残留的碘源，并且还会导致水白色液体磷。

公开(公告)号：US4897502A

公开(公告)日：1990-01-30

申请号：US105776

申请日：1987-10-07

申请人： Louis T. Gunkel ,  John Crosby

发明人： Louis T. Gunkel ,  John Crosby

IPC分类号： B01J27/138 ,  C07B61/00 ,  C07F9/12

CPC分类号： C07F9/12

摘要： A process is provided for making halogen-substituted triaryl phosphate esters which are normally solid under ambient conditions. The process comprises reacting a halogenated phenol with phosphorus oxychloride in the presence of a magnesium chloride catalyst above the melting point of the desired product. After the reaction is complete the product is recovered by adding an alcohol, such as, pentanol, 2-ethyl hexanol or hexanol and cooling the resulting mixture below the melting point of the product.

公开(公告)号：US5989509A

公开(公告)日：1999-11-23

申请号：US871037

申请日：1997-06-09

申请人： Louis T. Gunkel ,  John Crosby ,  Theodore F. Munday ,  Paul J. Beck

发明人： Louis T. Gunkel ,  John Crosby ,  Theodore F. Munday ,  Paul J. Beck

IPC分类号： C01B25/047 ,  C01B25/04

CPC分类号： C01B25/047

摘要： A process for purifying elemental phosphorus that contains antimony using an oxidizer, such as hydrogen peroxide, peroxymonosulfate, peroxydisulfate, or a hypochlorite, in a two phase system containing water and phosphorus as the two liquids. A purified elemental phosphorus having 200 ppb or less antimony content.

摘要翻译： 在含有水和磷的两相体系中，使用氧化剂如过氧化氢，过氧化一硫酸盐，过氧化二硫酸盐或次氯酸盐来纯化含有锑的元素磷的方法。 具有200ppb以下锑含量的纯化元素磷。

公开(公告)号：US5670126A

公开(公告)日：1997-09-23

申请号：US596815

申请日：1996-02-05

申请人： Louis T. Gunkel

发明人： Louis T. Gunkel

IPC分类号： C01B25/047 ,  C01B25/04 ,  C01B25/01

CPC分类号： C01B25/04

摘要： A process for purifying elemental phosphorus, by dosing a multi-phase elemental phosphorus system, having an aqueous phase and an immiscible, elemental phosphorus phase containing antimony, with a conditioning agent selected from the group consisting of iron (II) salt or iron (III) salt with free iodine; iron (II) iodide; free iodine; iron (II) sulfate; or iron (III) sulfate in an amount effective to lower the amount of antimony in the phosphorus; agitating the resultant mixture at a temperature above the melting point of phosphorus, but below the boiling point of water, and then separating the aqueous phase from the phosphorus phase to recover a phosphorus lower in antimony content.

摘要翻译： 一种通过配制具有含有锑的水相和不混溶的元素磷相的多相元素磷系统，用选自铁（II）盐或铁（III）的调节剂来提纯元素磷的方法 ）盐与游离碘; 碘化铁（II）; 游离碘; 硫酸铁（II） 或硫酸铁（III），其量可有效降低磷中的锑量; 在高于磷的熔点但低于水沸点的温度下搅拌所得混合物，然后将水相与磷相分离，以回收低于锑含量的磷。