公开(公告)号：US5281741A

公开(公告)日：1994-01-25

申请号：US611555

申请日：1990-11-13

申请人： Louis T. Gunkel ,  Henry J. Barda

发明人： Louis T. Gunkel ,  Henry J. Barda

IPC分类号： C07F9/12 ,  C07F9/09

CPC分类号： C07F9/12

摘要： A process is provided for preparing an aryl diphosphate ester containing less than 5% by weight of triarylphosphate. The process reacts a solution of a dihydroxy aromatic compound and an excess of phosphorus oxychloride in a nonaqueous solvent having a boiling point greater than 110.degree. C. The excess phosphorus oxychloride and part of the solvent are distilled from the solution at atmospheric pressure and the intermediate, a diphosphotetrachloridate solution, is reacted with a monohydric aryl compound. After extracting with an aqueous, alkaline solution the product is recovered by distilling off the remaining solvent.

摘要翻译： 提供了一种制备含有少于5％（重量）磷酸三芳酯的芳基二磷酸酯的方法。 该方法使二羟基芳族化合物和过量的三氯氧化磷溶液在沸点大于110℃的非水溶剂中反应。过量的三氯氧化磷和部分溶剂在大气压下从溶液中蒸馏出，中间体 二氯苯甲酸酯溶液与一元芳基化合物反应。 用碱性水溶液萃取后，通过蒸馏剩余的溶剂回收产物。

公开(公告)号：US5266295A

公开(公告)日：1993-11-30

申请号：US982040

申请日：1992-11-24

申请人： Henry J. Barda

发明人： Henry J. Barda

IPC分类号： C01B7/09 ,  C07B39/00 ,  C01B7/07

CPC分类号： C07B39/00 ,  C01B7/096

摘要： Hydrogen bromide can be oxidized to bromine more effectively using hydrogen peroxide as the oxidant if a strong acid (e.g., sulfuric or phosphoric acid) is also present to increase the percent conversion of bromide to bromine.

摘要翻译： 如果还存在强酸（例如硫酸或磷酸）以增加溴化物转化为溴的百分比，则可以使用过氧化氢作为氧化剂，更有效地将溴化氢氧化成溴。

公开(公告)号：US4564468A

公开(公告)日：1986-01-14

申请号：US680930

申请日：1984-12-12

申请人： Henry J. Barda

发明人： Henry J. Barda

IPC分类号： C08G18/38 ,  C08G18/14

CPC分类号： C08G18/3846 ,  Y10S260/24 ,  Y10S428/921

摘要： A reactive fire retardant mixture useful in the preparation of polyurethane foams. The mixture contains a halogenated imide-containing polyol having the formula: ##STR1## and the corresponding ether having the formula: ##STR2## wherein R is a hydrocarbon group having the valance n+2 and is selected from the group consisting of benzene groups, naphthalene groups and alicyclic hydrocarbon groups containing 5 to 10 carbon atoms, R' is an aliphatic hydrocarbon group containing 3-12 carbon atoms, X is selected from the group consisting of bromine and chlorine, n is an integer from 1-6 and p is an integer from 2-6. They are prepared by reacting an alcohol (e.g. isopropyl alcohol), a halogenated dicarboxylic anhydride (e.g. tetrabromophthalic anhydride) and an aminopolyol (e.g. 2-amino-2-ethyl-1,3-propanediol).

摘要翻译： 用于制备聚氨酯泡沫的反应性阻燃混合物。 该混合物含有具有下式的含卤化酰亚胺的多元醇：具有下式的相应的醚：其中R是具有n + 2价的烃基，并且选自苯基， 萘基和含有5〜10个碳原子的脂环族烃基，R'是含有3-12个碳原子的脂族烃基，X选自溴和氯，n是1-6的整数，p是 2-6的整数。 它们通过醇（例如异丙醇），卤代二羧酸酐（例如四溴邻苯二甲酸酐）和氨基多元醇（例如2-氨基-2-乙基-1,3-丙二醇）反应制备。

公开(公告)号：US4404361A

公开(公告)日：1983-09-13

申请号：US338531

申请日：1982-01-11

申请人： Henry J. Barda

发明人： Henry J. Barda

IPC分类号： C07D209/48 ,  C08K5/3417 ,  C07D403/12 ,  C08G73/06

CPC分类号： C08K5/3417 ,  C07D209/48

摘要： An additive flame retardant bisimide containing halogen atoms and ammonium acid tetrahalophthalate, e.g. N,N'-bis(2-ethylene tetrabromophthalimide) ammonium acid tetrabromophthalate. These compounds are useful in a variety of polymeric compositions and demonstrate increased thermal stability. They also foam on decomposition with the evolution of gas thus readily lending themselves to the preparation of flame retardant coatings.

摘要翻译： 含有卤素原子的添加剂阻燃双酰亚胺和四卤代邻苯二甲酸铵。 N，N'-双（2-乙烯四溴邻苯二甲酰亚胺）铵四溴间苯二酸铵。 这些化合物可用于各种聚合物组合物中并表现出增加的热稳定性。 它们也随着气体的逸出而分解而发泡，从而容易地适用于制备阻燃涂料。

公开(公告)号：US4689425A

公开(公告)日：1987-08-25

申请号：US927477

申请日：1986-11-06

申请人： Avinash Kachhy ,  Henry J. Barda

发明人： Avinash Kachhy ,  Henry J. Barda

IPC分类号： C07C51/00 ,  C07C51/363 ,  C07C63/70 ,  C07C67/00 ,  C07C67/307 ,  C07C69/78 ,  C07C69/76

CPC分类号： C07C69/78

摘要： A process for photochlorinating aromatic compounds in the side chain and, in particular, a process for the selective chlorination of a 2-alkyl group of 2-alkyl benzoic acid or ester is disclosed. In this process, hydrogen chloride is added to the benzoic acid or ester prior to adding chlorine in the presence of actinic radiation at a reaction temperature below the decomposition temperature of the resulting chlorinated acid or ester. A typical aromatic compound is methyl 2-methylbenzoate and the reaction is preferably carried out at a temperature ranging from about -20.degree. C. to 20.degree. C.

公开(公告)号：US4401778A

公开(公告)日：1983-08-30

申请号：US303159

申请日：1981-09-17

申请人： Henry J. Barda ,  Joseph M. Lesniewski

发明人： Henry J. Barda ,  Joseph M. Lesniewski

IPC分类号： C08K5/3417 ,  C08K5/34

CPC分类号： C08K5/3417

摘要： A flame retardant thermoplastic polymer containing a flame retardant amount of a flame retardant additive mixture. The mixture is comprised of halogenated imide-containing polyols having the formula: ##STR1## and the corresponding ethers having the formula: ##STR2## wherein R is a hydrocarbon group having the valence n+2 and is selected from the group consisting of benzene groups, naphthalene groups and alicyclic hydrocarbon groups containing 5 to 10 carbon atoms, X is selected from the group consisting of bromine and chlorine, n is an integer from 1-6 and p is an integer from 2-6. The preferred flame retardant mixture is a derivative of tetrabromophthalic anhydride.

摘要翻译： 含有阻燃剂量的阻燃添加剂混合物的阻燃热塑性聚合物。 该混合物由具有下式的含卤代酰亚胺的多元醇组成：具有下式的相应的醚：其中R是价数n + 2的烃基，并且选自苯基 ，含有5〜10个碳原子的萘基和脂环族烃基，X选自溴和氯，n是1-6的整数，p是2-6的整数。 优选的阻燃混合物是四溴邻苯二甲酸酐的衍生物。

公开(公告)号：US5025090A

公开(公告)日：1991-06-18

申请号：US473482

申请日：1990-02-01

申请人： Henry J. Barda

发明人： Henry J. Barda

IPC分类号： C07C315/00 ,  C07C317/22

CPC分类号： C07C315/00

摘要： Trivalent phosphorous compounds (e.g., phosphorous acid and dialkyl phosphites) if present in small amount during the reaction of phenol with a sulfonating agent or a phenol sulfonic acid yield a dihydroxydiphenyl sulfone product that is less colored.

摘要翻译： 在苯酚与磺化剂或苯酚磺酸反应期间少量存在的三价磷化合物（例如亚磷酸和亚磷酸二烷基酯）产生较少着色的二羟基二苯砜产物。

公开(公告)号：US4476268A

公开(公告)日：1984-10-09

申请号：US547782

申请日：1983-11-02

申请人： Henry J. Barda ,  Saadat Hussain

发明人： Henry J. Barda ,  Saadat Hussain

IPC分类号： C08K5/54 ,  C08L9/02

CPC分类号： C08K5/5406

摘要： A flame retarded acrylonitrile-butadiene-styrene composition having improved Izod impact strength and improved light stability. The acrylonitrile-butadiene-styrene composition of the present invention contains a flame retardant amount of a halophenoxyalkylsilane. The preferred halophenoxyalkylsilane is bis-(2,4,6-tribromophenoxy)dimethylsilane. Antimony oxide may optionally be present.

摘要翻译： 具有改进的艾佐德冲击强度和改善的光稳定性的阻燃丙烯腈 - 丁二烯 - 苯乙烯组合物。 本发明的丙烯腈 - 丁二烯 - 苯乙烯组合物含有阻燃剂量的卤代苯氧基烷基硅烷。 优选的卤代苯氧基烷基硅烷是双 - （2,4,6-三溴苯氧基）二甲基硅烷。 可以任选地存在氧化锑。

公开(公告)号：US4468480A

公开(公告)日：1984-08-28

申请号：US385782

申请日：1982-06-07

申请人： Henry J. Barda

发明人： Henry J. Barda

IPC分类号： C08G18/46 ,  C08G18/14 ,  C08G63/68

CPC分类号： C08G18/4607

摘要： A normally liquid, flame retardant polyol ester prepared by a process comprising reacting a halogen containing anhydride of a dicarboxylic acid or a mixture of said anhydrides with an aliphatic polyol having at least three hydroxy groups and an aliphatic diol, to obtain a substantially fully esterified halogen containing product in which the acid number does not exceed 10, with the optional removal of unreacted diol during the course of the reacting or subsequent to the reacting. This flame retardant polyol ester may be used in the preparation of polyurethanes or polyesters.

摘要翻译： 通过包括使二羧酸的含卤酸酐或所述酸酐的混合物与具有至少三个羟基的脂族多元醇和脂族二醇反应的方法制备的通常为液体的阻燃多元醇酯，以获得基本上完全酯化的卤素 其中酸值不超过10的含量产物，在反应过程中或反应过程中任选除去未反应的二醇。 该阻燃多元醇酯可用于制备聚氨酯或聚酯。

公开(公告)号：US07087193B2

公开(公告)日：2006-08-08

申请号：US10432111

申请日：2001-11-27

申请人： Henry J. Barda

发明人： Henry J. Barda

IPC分类号： C09K15/10 ,  C07F7/22 ,  C08K5/57 ,  C08K5/58

CPC分类号： C08K5/57 ,  C08K5/37 ,  C08K5/372 ,  C08K5/58 ,  C08L27/06

摘要： A stabilizer composition, for use in polyvinyl chloride formulations, that is a mixture of: at least one organotin sulfide; at least one organotin chloride; and at least one free mercaptan.

摘要翻译： 一种用于聚氯乙烯制剂的稳定剂组合物，其是以下物质的混合物：至少一种有机锡硫化物; 至少一种有机锡氯化物; 和至少一个游离硫醇。