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公开(公告)号:US10174140B2
公开(公告)日:2019-01-08
申请号:US14893557
申请日:2014-05-23
Applicant: Lubrizol Advanced Materials, Inc.
Inventor: John Ta-Yuan Lai , Ti Chou
IPC: C08F30/02 , C07F9/09 , C08F230/02 , C09K21/14 , C09D143/02 , C08K5/3492 , C08L33/08 , C08L43/02 , C08L75/02 , C08L75/04 , C08L77/00
Abstract: Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety and/or can be cross-linked with a cross-linking agent such as resorcinol.
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公开(公告)号:US09290639B2
公开(公告)日:2016-03-22
申请号:US14354723
申请日:2012-10-31
Applicant: Lubrizol Advanced Materials, Inc.
Inventor: John Ta-Yuan Lai , Ti Chou
IPC: C08F230/02 , C08K5/5313 , C07F9/09 , C07F9/38 , C09K21/14 , C08K5/3492 , C09D5/18 , B01D39/20
CPC classification number: C08K5/5313 , B01D39/2082 , C07F9/091 , C07F9/3808 , C07F9/3826 , C07F9/3834 , C08F230/02 , C08K5/34924 , C09D5/18 , C09K21/14
Abstract: Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety.
Abstract translation: 提供可以聚合成阻燃聚合物的非卤代单体,以及制备单体和聚合物的方法。 在最简单的方面,提供了一种单体组合物,其可以包含a)衍生自(甲基)丙烯酸,(甲基)丙烯酰胺或乙烯基苯之一的基团,b)聚磷酸酯部分,和c)胺类。 在单体组合物中,(a)的烯属不饱和单体直接或通过连接基团与b)的部分共价键合,形成前体单体单元。 c)的胺类与前体单体单元复合。 聚合物可以是单体组合物的均聚物,或具有变化a),b)和c)的单体组合物的共聚物。 在一个实施方案中,聚合物可另外包含不共价键合至聚磷酸酯部分的烯属不饱和单体。
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公开(公告)号:US20140296463A1
公开(公告)日:2014-10-02
申请号:US13851226
申请日:2013-03-27
Applicant: LUBRIZOL ADVANCED MATERIALS, INC.
Inventor: John Ta-Yuan Lai , Gary A. Anderle , Ti Chou
IPC: C08F222/02 , C08F122/02
CPC classification number: C08F222/02 , C08F122/02
Abstract: This invention relates to polymers containing structural units derived from itaconic acid which are useful, including uses as binders for fiberglass.
Abstract translation: 本发明涉及包含衍生自衣康酸的结构单元的聚合物,其可用,包括用作玻璃纤维的粘合剂。
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公开(公告)号:US20140296396A1
公开(公告)日:2014-10-02
申请号:US14354723
申请日:2012-10-31
Applicant: Lubrizol Advanced Materials, Inc.
Inventor: John Ta-Yuan Lai , Ti Chou
IPC: C08F230/02 , C08K5/3492 , C08K5/5313
CPC classification number: C08K5/5313 , B01D39/2082 , C07F9/091 , C07F9/3808 , C07F9/3826 , C07F9/3834 , C08F230/02 , C08K5/34924 , C09D5/18 , C09K21/14
Abstract: Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety.
Abstract translation: 提供可以聚合成阻燃聚合物的非卤代单体,以及制备单体和聚合物的方法。 在最简单的方面,提供了一种单体组合物,其可以包含a)衍生自(甲基)丙烯酸,(甲基)丙烯酰胺或乙烯基苯之一的基团,b)聚磷酸酯部分,和c)胺类。 在单体组合物中,(a)的烯属不饱和单体直接或通过连接基团与b)的部分共价键合,形成前体单体单元。 c)的胺类与前体单体单元复合。 聚合物可以是单体组合物的均聚物,或具有变化a),b)和c)的单体组合物的共聚物。 在一个实施方案中,聚合物可另外包含不共价键合至聚磷酸酯部分的烯属不饱和单体。
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公开(公告)号:US09783687B2
公开(公告)日:2017-10-10
申请号:US15063698
申请日:2016-03-08
Applicant: Lubrizol Advanced Materials, Inc.
Inventor: John Ta-Yuan Lai , Ti Chou
IPC: C09D5/18 , C08F230/02 , C09D143/02 , C09D7/12 , B01D29/00 , B01D39/16 , B01D46/00 , C09D161/06 , C09D161/24 , C09D175/04 , C08F8/30 , C08K5/3492
CPC classification number: C09D5/18 , B01D29/0093 , B01D39/1607 , B01D46/0001 , B01D46/0093 , C08F8/30 , C08F230/02 , C08K5/34924 , C09D7/63 , C09D143/02 , C09D161/06 , C09D161/24 , C09D175/04 , Y10T428/31935 , C08F220/56
Abstract: Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety.
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公开(公告)号:US20160185982A1
公开(公告)日:2016-06-30
申请号:US15063698
申请日:2016-03-08
Applicant: Lubrizol Advanced Materials, Inc.
Inventor: John Ta-Yuan Lai , Ti Chou
IPC: C09D5/18 , C09D161/06 , B01D29/00 , C09D161/24 , B01D39/16 , B01D46/00 , C09D143/02 , C09D175/04
CPC classification number: C09D5/18 , B01D29/0093 , B01D39/1607 , B01D46/0001 , B01D46/0093 , C08F8/30 , C08F230/02 , C08K5/34924 , C09D7/63 , C09D143/02 , C09D161/06 , C09D161/24 , C09D175/04 , Y10T428/31935 , C08F220/56
Abstract: Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety.
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