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    Synthesis of perhydroxydodecaborate salts and related species
    1.
    发明授权
    Synthesis of perhydroxydodecaborate salts and related species 有权
    全羟基十二硼酸盐和相关物质的合成

    公开(公告)号：US06323372B1

    公开(公告)日：2001-11-27

    申请号：US09546108

    申请日：2000-04-10

    申请人： M. Frederick Hawthorne ,  Toralf Peymann ,  Axel Hans-Joachim Herzog

    发明人： M. Frederick Hawthorne ,  Toralf Peymann ,  Axel Hans-Joachim Herzog

    IPC分类号： C07F502

    CPC分类号： C07F5/027

    摘要： New icosahedral borohydrates Cs2[closo-B12(OH)12]; Cs[closo-1-H-1-CB11(OH)11]; and closo-1,12-H2-1,12-C2B10(OH)10 are disclosed. Also set forth are their preparation by refluxing the icosahedral boranes [closo-B12H12]2−, [closo-1-CB11H12]− and closo-1,12-(CH2OH)2-1,12-C2B10H10 with a hydroxylating agent, preferably 30%w hydrogen peroxide.

    摘要翻译： 新二十面体硼氢化物Cs2 [closo-B12（OH）12]; Cs [closo-1-H-1-CB11（OH）11]; 和closo-1,12-H2-1,12-C2B10（OH）10。 还阐述了它们的制备方法是通过将二十面体硼烷[closo-B12H12] 2-，[closo-1-CB11H12]和closo-1,12-（CH2OH）2-1,12-C2B10H10与羟基化剂，优选 30％w过氧化氢。

    Ether and ester derivatives of the perborate icosahedron
    2.
    发明授权
    Ether and ester derivatives of the perborate icosahedron 有权
    过硼酸二十面体的醚和酯衍生物

    公开(公告)号：US06664426B1

    公开(公告)日：2003-12-16

    申请号：US09592214

    申请日：2000-06-12

    申请人： M. Frederick Hawthorne ,  Toralf Peymann ,  Andreas Maderna

    发明人： M. Frederick Hawthorne ,  Toralf Peymann ,  Andreas Maderna

    IPC分类号： C07F502

    CPC分类号： C07F5/027

    摘要： New boron icosahedral ethers and esters formed from Cs2[closo-B12(OH)12],; Cs[closo-1-H-1-CB11(OH)11]; and closo-1,12-H2-1,12-C2B10(OH)10 are disclosed. Also set forth are their preparation by reacting the icosahedral boranes [closo-B12H12]2−, [closo-1-CB11H12]− and closo-1,12-(CH2OH)2-1,12-C2B10H10 with an acid anhdride or acid chloride to form the ester or an alkylating agent to form the ether.

    摘要翻译： 由Cs2 [closo-B12（OH）12]形成的新的二十二面体醚和酯; Cs [closo-1-H-1-CB11（OH）11]; 和closo-1,12-H2-1,12-C2B10（OH）10。 还阐述了它们通过使二十面体硼烷[closo-B12H12] 2-，[closo-1-CB11H12] - 和closo-1,12-（CH2OH）2-1,12-C2B10H10与 酸或酰氯形成酯或烷基化剂以形成醚。

    Synthesis of permethyldodecaborate and paramagnetic dodecaborate salt
    3.
    发明授权
    Synthesis of permethyldodecaborate and paramagnetic dodecaborate salt 有权
    十二硼酸十二硼酸盐和顺磁十二硼酸盐的合成

    公开(公告)号：US06355840B1

    公开(公告)日：2002-03-12

    申请号：US09576842

    申请日：2000-05-23

    申请人： M. Frederick Hawthorne ,  Toralf Peymann

    发明人： M. Frederick Hawthorne ,  Toralf Peymann

    IPC分类号： C07F502

    CPC分类号： C07F5/05

    摘要： The dodecamethyl closo-borane dianion [closo-B12(CH3)12]2− and anion [closo-B12(CH3)12]− were synthesized and characterized. Dodecamethyl-closo dodecaborate (2−) was produced from [closo-B12H12]2−, using trimethylaluminum, and methyl iodide and modified Friedel-Crafts reaction conditions. The anion was produced from the dianion by chemical oxidation using ceric (4) ammonium nitrate in acetonitrile. The anion and dianion were both characterized by 1H and 11B NMR spectroscopy, high-resolution fast atom bombardment (FAB) mass spectrometry, cyclic voltammetry, and single-crystal X-ray diffraction. The “camouflaged” polyhedral borane anion [closo-B12(CH3)12]2−, can be used as a precursor to materials that offer a broad spectrum of novel applications ranging from drug applications and supramolecular chemistry to use as a weakly-coordinating dianion.

    摘要翻译： 合成并表征了十二甲基交联硼烷二价阴离子[closo-B12（CH3 )12] 2-和阴离子[closo-B12（CH3 )12]]。 使用三甲基铝，甲基碘和改性的Friedel-Crafts反应条件，由[closo-B12H12] 2-制备十二甲基十八硼酸盐（2-）。 通过使用硝酸铈（4）硝酸铵在乙腈中的化学氧化由二阴离子生成阴离子。 阴离子和二阴离子均以1H和11B NMR光谱，高分辨率快速原子轰击（FAB）质谱，循环伏安法和单晶X射线衍射为特征。 “伪装”多面体硼烷阴离子[closo-B12（CH3）12] 2-）可用作材料的前体，提供广泛的新型应用范围，从药物应用和超分子化学到用作弱配位二价阴离子 。