公开(公告)号：US20150252487A1

公开(公告)日：2015-09-10

申请号：US14200546

申请日：2014-03-07

Applicant: MacDermid Acumen, Inc.

Inventor： Marc Mertens ,  Richard Tooth ,  Trevor Pearson ,  Roderick D. Herdman ,  Terence Clarke

IPC: C25D3/06

CPC classification number: C25D3/06 ,  C25D5/48 ,  C25D9/08 ,  Y10T428/12854

Abstract: A method of treating a substrate, wherein the substrate comprises a layer deposited from a trivalent chromium electrolyte, is described. The method includes the steps of providing an anode and the chromium(III) plated substrate as a cathode in an electrolyte comprising (i) a trivalent chromium salt; and (ii) a complexant; and passing an electrical current between the anode and the cathode to passivate the chromium(III) plated substrate. The substrate may be first plated with a plated nickel layer so that the chromium(III) plated layer is deposited over the nickel plated layer.

Abstract translation: 描述了一种处理衬底的方法，其中衬底包括由三价铬电解质沉积的层。 该方法包括以下步骤：在电解质中提供阳极和镀有铬（III）的底物作为阴极，其包括（i）三价铬盐; 和（ii）复合物; 并在阳极和阴极之间通过电流以钝化镀铬（III）的衬底。 可以首先将衬底镀覆镀镍层，以使镀铬层（III）沉积在镀镍层上。

公开(公告)号：US10415148B2

公开(公告)日：2019-09-17

申请号：US14200546

申请日：2014-03-07

Applicant: MacDermid Acumen, Inc.

Inventor： Marc Mertens ,  Richard Tooth ,  Trevor Pearson ,  Roderick D. Herdman ,  Terence Clarke

IPC: C25D11/38 ,  C25D3/06 ,  C25D9/08 ,  C25D5/48

Abstract: A method of treating a substrate, wherein the substrate comprises a layer deposited from a trivalent chromium electrolyte, is described. The method includes the steps of providing an anode and the chromium(III) plated substrate as a cathode in an electrolyte comprising (i) a trivalent chromium salt; and (ii) a complexant; and passing an electrical current between the anode and the cathode to passivate the chromium(III) plated substrate. The substrate may be first plated with a plated nickel layer so that the chromium(III) plated layer is deposited over the nickel plated layer.

公开(公告)号：US10246788B2

公开(公告)日：2019-04-02

申请号：US15667002

申请日：2017-08-02

Applicant: MacDermid Acumen, Inc.

Inventor： Trevor Pearson ,  Terence Clarke ,  Roshan V. Chapaneri

IPC: C25B9/06 ,  C25C1/10 ,  C25C7/02 ,  C25B11/12 ,  C25B1/21 ,  C23C18/20 ,  C25D5/54 ,  C23C18/22 ,  C23C18/30

Abstract: An electrolytic cell and a method of electrochemical oxidation of manganese(II) ions to manganese(III) ions in the electrolytic cell are described. The electrolytic cell comprises (1) an electrolyte solution of manganese(II) ions in a solution of 9 to 15 molar sulfuric acid; (2) a cathode immersed in the electrolyte solution; and (3) an anode immersed in the electrolyte solution and spaced apart from the cathode. Various anode materials are described including vitreous carbon, reticulated vitreous carbon, and woven carbon fibers.

公开(公告)号：US09752241B2

公开(公告)日：2017-09-05

申请号：US13677798

申请日：2012-11-15

Applicant: MacDermid Acumen, Inc.

Inventor： Trevor Pearson ,  Terence Clarke ,  Roshan V. Chapaneri

IPC: C25C1/10 ,  C25C7/02 ,  C25B11/12 ,  C25B1/21 ,  C25B9/06 ,  C23C18/20 ,  C25D5/54 ,  C23C18/22 ,  C23C18/30

CPC classification number: C25C1/10 ,  C23C18/2086 ,  C23C18/2093 ,  C23C18/22 ,  C23C18/30 ,  C25B1/21 ,  C25B9/06 ,  C25B11/12 ,  C25C7/02 ,  C25D5/54

Abstract: An electrolytic cell and a method of electrochemical oxidation of manganese (II) ions to manganese(III) ions in the electrolytic cell are described. The electrolytic cell comprises (1) an electrolyte solution of manganese(II) ions in a solution of 9 to 15 molar sulfuric acid; (2) a cathode immersed in the electrolyte solution; and (3) an anode immersed in the electrolyte solution and spaced apart from the cathode. Various anode materials are described including vitreous carbon, reticulated vitreous carbon, and woven carbon fibers.

公开(公告)号：US09534306B2

公开(公告)日：2017-01-03

申请号：US13795382

申请日：2013-03-12

Applicant: MacDermid Acumen, Inc.

Inventor： Trevor Pearson ,  Terence Clarke ,  Roshan V. Chapaneri ,  Craig Robinson ,  Alison Hyslop ,  Amrik Singh

IPC: C25B1/21 ,  C25C1/10 ,  C25C7/00 ,  C25B11/12 ,  C25B9/06 ,  C09K13/04 ,  C25D5/56

CPC classification number: C25D5/34 ,  C09K13/04 ,  C09K13/06 ,  C25B1/00 ,  C25B1/21 ,  C25B9/06 ,  C25B11/0415 ,  C25B11/0431 ,  C25B11/12 ,  C25B11/14 ,  C25C1/10 ,  C25C7/00 ,  C25D5/56

Abstract: An electrolytic cell and a method of electrochemical oxidation of manganese(II) ions to manganese(III) ions in the electrolytic cell are described. The electrolytic cell comprises (1) an electrolyte solution of manganese(II) ions in a solution of at least one acid; (2) a cathode immersed in the electrolyte solution; and (3) an anode immersed in the electrolyte solution and spaced apart from the cathode. Various anode materials are described including vitreous carbon, reticulated vitreous carbon, woven carbon fibers, lead and lead alloy. Once the electrolyte is oxidized to form a metastable complex of manganese(III) ions, a platable plastic may be contacted with the metastable complex to etch the platable plastic. In addition, a pretreatment step may also be performed on the platable plastic prior to contacting the platable plastic with the metastable complex to condition the plastic surface.

Abstract translation: 描述了一种电解槽和电解槽中锰（II）离子向锰（III）离子电化学氧化的方法。 电解槽包括（1）在至少一种酸的溶液中的锰（II）离子的电解液; （2）浸入电解液中的阴极; 和（3）浸在电解质溶液中并与阴极间隔开的阳极。 描述了各种阳极材料，包括玻璃碳，网状玻璃碳，编织碳纤维，铅和铅合金。 一旦电解质被氧化形成锰（III）离子的亚稳态复合物，可镀的塑料可与亚稳态络合物接触以蚀刻可镀塑料。 此外，还可以在将可镀塑料与亚稳态复合物接触之前在可镀塑料上进行预处理步骤以调节塑料表面。

公开(公告)号：US20130186862A1

公开(公告)日：2013-07-25

申请号：US13795382

申请日：2013-03-12

Applicant: MACDERMID ACUMEN, INC.

Inventor： Trevor Pearson ,  Terence Clarke ,  Roshan V. Chapaneri ,  Craig Robinson ,  Alison Hyslop ,  Amrik Singh

IPC: C25C1/10 ,  C25C7/00

CPC classification number: C25D5/34 ,  C09K13/04 ,  C09K13/06 ,  C25B1/00 ,  C25B1/21 ,  C25B9/06 ,  C25B11/0415 ,  C25B11/0431 ,  C25B11/12 ,  C25B11/14 ,  C25C1/10 ,  C25C7/00 ,  C25D5/56

Abstract: An electrolytic cell and a method of electrochemical oxidation of manganese(II) ions to manganese(III) ions in the electrolytic cell are described. The electrolytic cell comprises (1) an electrolyte solution of manganese(II) ions in a solution of at least one acid; (2) a cathode immersed in the electrolyte solution; and (3) an anode immersed in the electrolyte solution and spaced apart from the cathode. Various anode materials are described including vitreous carbon, reticulated vitreous carbon, woven carbon fibers, lead and lead alloy. Once the electrolyte is oxidized to form a metastable complex of manganese(III) ions, a platable plastic may be contacted with the metastable complex to etch the platable plastic. In addition, a pretreatment step may also be performed on the platable plastic prior to contacting the platable plastic with the metastable complex to condition the plastic surface.

Abstract translation: 描述了一种电解槽和电解槽中锰（II）离子向锰（III）离子电化学氧化的方法。 电解槽包括（1）在至少一种酸的溶液中的锰（II）离子的电解液; （2）浸入电解液中的阴极; 和（3）浸在电解质溶液中并与阴极间隔开的阳极。 描述了各种阳极材料，包括玻璃碳，网状玻璃碳，编织碳纤维，铅和铅合金。 一旦电解质被氧化形成锰（III）离子的亚稳态复合物，可镀的塑料可与亚稳态络合物接触以蚀刻可镀塑料。 此外，还可以在将可镀塑料与亚稳态复合物接触之前在可镀塑料上进行预处理步骤以调节塑料表面。

公开(公告)号：US20130186861A1

公开(公告)日：2013-07-25

申请号：US13677798

申请日：2012-11-15

Applicant: MACDERMID ACUMEN, INC.

Inventor： Trevor Pearson ,  Terence Clarke ,  Roshan V. Chapaneri

IPC: C25C1/10 ,  C25C7/02

CPC classification number: C25C1/10 ,  C23C18/2086 ,  C23C18/2093 ,  C23C18/22 ,  C23C18/30 ,  C25B1/21 ,  C25B9/06 ,  C25B11/12 ,  C25C7/02 ,  C25D5/54

Abstract: An electrolytic cell and a method of electrochemical oxidation of manganese (II) ions to manganese(III) ions in the electrolytic cell are described. The electrolytic cell comprises (1) an electrolyte solution of manganese(II) ions in a solution of 9 to 15 molar sulfuric acid; (2) a cathode immersed in the electrolyte solution; and (3) an anode immersed in the electrolyte solution and spaced apart from the cathode. Various anode materials are described including vitreous carbon, reticulated vitreous carbon, and woven carbon fibers.

Abstract translation: 描述了一种电解槽和电解槽中锰（II）离子向锰（III）离子电化学氧化的方法。 电解槽包括（1）在9〜15摩尔硫酸的溶液中的锰（II）离子的电解液; （2）浸入电解液中的阴极; 和（3）浸在电解质溶液中并与阴极间隔开的阳极。 描述了各种阳极材料，包括玻璃碳，网状玻璃碳和编织碳纤维。