摘要:
Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an α-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.
摘要:
Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an α-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.
摘要:
Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an α-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.
摘要:
A process for the production of leather, wherein tanned animal hides are treated in step (A) with an aqueous liquor which comprises (a) at least one copolymer obtainable by copolymerization of (a1) at least one ethylenically unsaturated C4-C8-dicarboxylic acid or at least one derivative of an ethylenically unsaturated C4-C8-dicarboxylic acid and (a2) at least one C8-C100-α-olefin and, if appropriate, hydrolysis and/or at least partial neutralization, (b) at least one paraffin which is liquid at room temperature, (c) at least one synthetic nonionic emulsifier, the aqueous liquor being free of silicones, and furthermore silicone-free aqueous formulations and their use.
摘要:
A process for producing leather comprises treating part-processed hides, crust leathers or pelts with at least one aqueous float comprising (A) at least one amphiphilic organic copolymer, (B) at least one silicone compound having at least one carboxylic acid group or at least one carboxylic anhydride group per molecule, (C) at least one surface-active compound selected from emulsifiers having at least one phosphorus atom per molecule, (D) at least one surface-active compound selected from N-acylated amino acids, (E) at least one surface-active compound comprising at least one C10-C30-alkyl radical, branched or unbranched, or at least one polyisobutene moiety, and at least one ionic or aqueous-ionizable group, other than amphiphilic copolymer (A) and surface-active compound (C), and which is free of waxes and oils.
摘要:
A process for producing leather comprises treating part-processed hides, crust leathers or pelts with at least one aqueous float comprising (A) at least one amphiphilic organic copolymer, (B) at least one silicone compound having at least one carboxylic acid group or at least one carboxylic anhydride group per molecule, (C) at least one surface-active compound selected from emulsifiers having at least one phosphorus atom per molecule, (D) at least one surface-active compound selected from N-acylated amino acids, (E) at least one surface-active compound comprising at least one C10-C30-alkyl radical, branched or unbranched, or at least one polyisobutene moiety, and at least one ionic or aqueous-ionizable group, other than amphiphilic copolymer (A) and surface-active compound (C), and which is free of waxes and oils.
摘要:
Aqueous solutions or dispersions of copolymers obtainable by free-radical copolymerization of (a) from 20 to 90% by weight of at least one monoethylenically unsaturated C4-6-dicarboxylic acid or the anhydride thereof, as component A, (b) from 5 to 50% by weight of at least one olefin having 2 to 6 carbon atoms, as component B, (c) from 5 to 50% by weight of at least one hydrophobic comonomer from the group consisting of long-chain olefins, esters of long-chain alcohols with acrylic acid or methacrylic acid, long-chain amides of acrylic acid or methacrylic acid, and long-chain alkyl vinyl ethers, as component C, (d) from 0 to 40% by weight of further comonomers which can be copolymerized with the above monomers, as component D, where the sum of the amounts of components A, B, C and, if used, D is 100% by weight, followed by at least partial esterification or hydrolysis and neutralization and/or reaction of the carboxyl groups formed during the hydrolysis with bases, for treating leather and/or fur skins.
摘要:
Aqueous dispersions of copolymers are obtainable by free radical copolymerization of (A) at least one ethylenically unsaturated dicarboxylic anhydride, derived from at least one dicarboxylic acid of 4 to 8 carbon atoms, (B) at least one oligomer of branched or straight-chain C3-C10-alkene, at least one oligomer having an average molecular weight Mn of from 300 to 5 000 g/mol or being obtainable by oligomerization of at least 3 equivalents of C3-C10-alkene, (C) optionally at least one ethylenically unsaturated comonomer differing from (A), and optionally reaction with (D) at least one compound of the formula I a or I b and subsequent addition of water, where, in formulae I a and I b, A1 are identical or different C2-C20-alkylene, R1 is linear or branched C1-C30-alkyl, phenyl or hydrogen, and n is an integer from 1 to 200, the water content being from 30 to 99.5% by weight, based on aqueous dispersion.
摘要:
Leather and skins are water repellent in aqueous emulsion in the presence of emulsifiers with polysiloxanes which are functionalized with carboxyl groups in a comb-like manner and in which the carboxyl groups are bonded to the polymer main chain via spacer groups in the form of linear or branched C.sub.2 -C.sub.40 -alkylene groups which may be interrupted by up to 8 non-neighboring oxygen atoms or groups of the formula --NR.sup.1 --, CO-- �sic! or --CO--NR.sup.1 -- and in addition may carry up to 5 carboxyl groups or carboxamido groups of the formula --CO--NR.sup.1 R.sup.2 --, where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.4 -alkyl, the spacer groups being bonded to the polymer main chain via a direct bond or via an oxygen atom or a group of the formula --NR.sup.1 --, --CO--, --CO--NR.sup.1 -- or --CO--O--.
摘要:
Aqueous compositions containing alkoxylated alcohols and hydrophobic components, method for the production and use thereof Compositions comprising, as components, a) at least two alkoxylated alcohols, b) at least one hydrophobic component selected from natural, modified natural and synthetic hydrophobic substances, c) at least 20% by weight, based on the total weight of the composition, of water, wherein the compositions have a mean hydrodynamic radius in the range from 1 to 200 nm, determined by dynamic light scattering.