摘要:
Aqueous compositions containing alkoxylated alcohols and hydrophobic components, method for the production and use thereof Compositions comprising, as components, a) at least two alkoxylated alcohols, b) at least one hydrophobic component selected from natural, modified natural and synthetic hydrophobic substances, c) at least 20% by weight, based on the total weight of the composition, of water, wherein the compositions have a mean hydrodynamic radius in the range from 1 to 200 nm, determined by dynamic light scattering.
摘要:
Compositions comprising the following components: (A) at least one carboxyl-containing polysiloxane which has at least one structural element of the formula Ia, Ib or Ic per molecule, (B1) at least one aprotic substance which is liquid at room temperature or (B2) at least one organic solvent, (C) up to 2% by weight, based on the weight of the composition, of water, the variables being defined as follows: R1 is hydrogen, hydroxyl, C1-C6-alkyl, C6-C14-aryl or C1-C4-alkoxy, R2 is hydrogen or C1-C6-alkyl, Z1 is C2-C25-alkylene, C3-C10-cycloalkylene, C6-C14-arylene, —[(CH2)n—NR2—(CH2)m]p, n and m are integers which are identical or different and are from 1 to 10, p is an integer from 1 to 5, A1 is C2-C20-alkylene, unsubstituted or substituted by R3 and/or R4, —CH═CR3—, R3 and R4 are identical or different and are selected from hydrogen, C1-C20-alkyl, C2-C20-alkenyl, C6-C14-aryl and C1-C4-alkoxy; it being possible for R3 and R4 to be linked to one another with formation of a mono- or bicyclic system, M are identical or different and are selected from hydrogen, alkali metal and ammonium, which may be substituted or cyclic, are prepared by a process wherein at least one amino-containing polysiloxane which has at least one structural element of the formula IIa, IIb or IIc per molecule is reacted, in the presence or absence of component (B1), with at least one dicarboxylic anhydride of the formula IIIa or at least one dicarboxylic acid derivative of the formula IIIb X being a leaving group and Z2 being C2-C25-alkylene, C3-C10-cycloalkylene, C6-C14-arylene or —[(CH2)n—NR2—(CH2)m]p, and then, if required, component (B1) or (B2) is added.
摘要:
The present invention relates to a process for dyeing leather with at least one dye F which has at least one alkaline-activable group of the formula A; where - - - - denotes the bond to the rest of the dye molecule; X is an electron-attracting radical, k is 1, 2 or 3, n is 0 or 1 and B is a CH═CH2 group or a CH2—CH2-Q group, where Q is an alkaline-detachable group, which comprises treating the leather with an aqueous float comprising at least one dye F at a pH of not less than 7.5. The present invention also relates to novel dyes which are particularly useful for reactive dyeing of leather.
摘要:
The invention relates to a process for preparing polymethylolated melamine and polymethylolated melamine compounds polyetherified with alkanol, wherein the methylolation reaction is carried out in a kneading reactor.
摘要:
The invention relates to a process for preparing polymethylolated melamine and polymethylolated melamine compounds polyetherified with alkanol, wherein the methylolation reaction is carried out in a kneading reactor.
摘要:
Processes comprising: providing an alkanolic reaction mixture, the alkanolic reaction mixture comprising: at least one alkoxycarbonylaminotriazine; at least one carbonic ester; at least one C1-C13-alkanol, which alkanol may further comprise up to two ether-bound oxygen atoms and may further comprise a substituent selected from the group consisting of C1-C4-alkyls and hydroxyls; and at least one alkali metal alkoxide or alkaline earth metal alkoxide; and subjecting the alkanolic reaction mixture to extraction with a polar extractant such that at least a portion of polar/ionic components present in the reaction mixture are removed, wherein the polar extractant is less than entirely miscible with an organic phase of the reaction mixture, to form an alkanolic phase comprising the at least one alkoxycarbonylaminotriazine and a polar phase comprising the polar extractant and the portion of polar/ionic components; and wherein the extraction is carried out with one or more selected from the group consisting of mixer/settler units, columns, centrifugal field separation extractors, and combinations thereof.
摘要:
The invention relates to a process for preparing free-flowing, pulverulent alkoxycarbonylaminotriazine from an alkanolic reaction mixture which is obtained in the preparation of alkoxycarbonylaminotriazines and comprises at least one alkoxycarbonylaminotriazine, at least one cyclic and/or acyclic carbonic ester, at least one C1-C13-alkanol which optionally comprises one or two oxygen atoms in the form of ether bonds and is optionally substituted by C1-C4-alkyl and/or hydroxyl, and also at least one alkali metal or alkaline earth metal alkoxide, with or without melamine and with or without catalyst, by atomizing and drying the reaction mixture in a spray drier.
摘要:
Process for the preparation of etherified melamine/formaldehyde condensates, in which first a methylolation of melamine with a formaldehyde component in the molar ratio of from 1:6 to 1:15, preferably at a pH of >7, is carried out. This is followed by an etherification of the resulting hydroxymethylation intermediate in the presence of a C1-C20-alkyl, preferably of a C1-C6-alcohol, particularly preferably of a C1-C4-alcohol, at a pH of 9.5 being established before, during and/or after the distillation. According to the invention, a plurality of hydroxymethylation, etherification and distillation steps follow in order to achieve an etherified melamine/formaldehyde condensate which is distinguished by a high degree of hydroxymethylation, a high solids content and a low viscosity.