摘要:
A nonaqueous electrolyte secondary battery having excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics is provided. The battery contains a negative electrode having an active material comprising Si or a Si alloy; a positive electrode; and a nonaqueous electrolyte solution, containing an electrolyte; a nonaqueous solvent including an acyclic carbonate having a halogen atom; and at least one compound selected from the group consisting of a monofluorophosphate and a difluorophosphate. A nonaqueous electrolyte in contact with a negative electrode having an active material comprising Si or a Si alloy is also provided.
摘要:
A nonaqueous electrolytic solution that can provide a high energy density nonaqueous electrolyte secondary battery having a high capacity, excellent storage characteristics, and excellent cycle characteristics and suppressing the decomposition of an electrolytic solution and the deterioration thereof when used in a high-temperature environment includes an electrolyte, a nonaqueous solvent, and a compound represented by general formula (1): wherein R1, R2, and R3 each independently represent a hydrogen atom, a cyano group, or an optionally halogen atom-substituted hydrogen group having 1 to 10 carbon atoms, with the proviso that R1 and R2 do not simultaneously represent hydrogen atoms.
摘要:
Objects of the invention are to provide nonaqueous electrolytic solutions that allow nonaqueous electrolyte secondary batteries to achieve improvements in initial battery characteristics and in battery characteristics after durability testing at the same time, and to provide nonaqueous electrolyte secondary batteries containing the nonaqueous electrolytic solutions. An aspect of the invention resides in a nonaqueous electrolytic solution for a nonaqueous electrolyte secondary battery including a positive electrode and a negative electrode capable of storing and releasing metal ions, the nonaqueous electrolytic solution including an electrolyte and a nonaqueous solvent and further including an aromatic carboxylate ester represented by Formula (1), or an aromatic carboxylate ester (I) represented by Formula (2) and at least one compound (II) selected from the group consisting of fluorine-containing cyclic carbonates, sulfur-containing organic compounds, phosphonate esters, cyano group-containing organic compounds, isocyanate group-containing organic compounds, silicon-containing compounds, aromatic compounds other than those of Formula (2), carboxylate esters represented by Formula (3), cyclic compounds having a plurality of ether bonds, monofluorophosphate salts, difluorophosphate salts, borate salts, oxalate salts and fluorosulfonate salts. Another aspect resides in a nonaqueous electrolyte secondary battery including a negative electrode and a positive electrode capable of storing and releasing lithium ions, and a nonaqueous electrolytic solution including an electrolyte and a nonaqueous solvent, the nonaqueous electrolytic solution being the nonaqueous electrolytic solution described above.
摘要:
A non-aqueous liquid electrolyte secondary battery using negative-electrode active material having Si, Sn and/or Pb, with high charge-capacity, superior characteristics including discharge-capacity retention rate over long is provided. The non-aqueous liquid electrolyte of the battery contains carbonate having unsaturated bond and/or halogen and compounds such as LiPF6 and/or LiBF4 (first lithium salt) and lithium salt different from the first lithium salt.
摘要:
Provided is a non-aqueous electrolyte solution that enables the fabrication of a non-aqueous secondary battery with which gas generation during battery use in high-temperature environments or with continuous charging is suppressed. Also provided is a non-aqueous electrolyte secondary battery that uses this non-aqueous electrolyte solution. The non-aqueous electrolyte solution is used in a non-aqueous electrolyte secondary battery that has a positive electrode having a positive electrode active material capable of absorbing and releasing a metal ion, and a negative electrode having a negative electrode active material capable of absorbing and releasing a metal ion, the non-aqueous electrolyte solution containing a compound represented by formula (1) and a nitrile compound in prescribed contents.
摘要:
A non-aqueous liquid electrolyte secondary battery using negative-electrode active material having Si, Sn and/or Pb, with high charge-capacity, superior characteristics including discharge-capacity retention rate over long is provided. Its non-aqueous liquid electrolyte contains carbonate having unsaturated bond and/or halogen and compounds like LiPF6 and/or LiBF4 (first lithium salt) and lithium salt different from said first one, represented by formula below (second lithium salt). Lil(αmXan) (In the formula, l, m and n represent integers of 1 to 10, 1 to 100 and 1 to 200, respectively. α represents boron, carbon, nitrogen, oxygen or phosphorus. Xa represents functional group having atom selected from 14th to 17th groups of periodic table at its binding-position to α. Two or more of Xa may be connected to each other to form a ring structure. However, such a case where α is boron and Xa is compound represented by (CiH2(i-2)O4)(CjH2(j-2)O4) is omitted (i and j represent integers of 2 or larger.)
摘要:
A non-aqueous liquid electrolyte secondary battery using negative-electrode active material having Si, Sn and/or Pb, with high charge-capacity, superior characteristics including discharge-capacity retention rate over long is provided. The non-aqueous liquid electrolyte of the battery contains carbonate having unsaturated bond and/or halogen and and an anhydride compound.
摘要:
An object of the invention is to provide nonaqueous electrolyte batteries having high initial efficiency, excellent initial capacity and excellent overcharge safety, and nonaqueous electrolytic solutions realizing such batteries. A nonaqueous electrolytic solution includes an electrolyte and a nonaqueous solvent, and further includes an aromatic compound represented by Formula (I) (in which R1 to R5 are independently hydrogen, a halogen, or an unsubstituted or halogen-substituted hydrocarbon group having 1 to 20 carbon atoms, R6 and R7 are independently a hydrocarbon group having 1 to 12 carbon atoms, at least two of R1 to R7 may be bonded together to form a ring, and Formula (I) satisfies at least one of the requirements (A) and (B): (A) at least one of R1 to R5 is a halogen, or an unsubstituted or halogen-substituted hydrocarbon group having 1 to 20 carbon atoms, (B) the total number of carbon atoms in R1 to R7 is 3 to 20). A nonaqueous electrolyte battery includes the nonaqueous electrolytic solution.
摘要:
A non-aqueous liquid electrolyte suitable for use in a non-aqueous liquid electrolyte secondary battery comprising a negative electrode and a positive electrode, capable of intercalating and deintercalating lithium ions, and the non-aqueous liquid electrolyte, the negative electrode containing a negative-electrode active material having at least one kind of atom selected from the group consisting of Si atom, Sn atom and Pb atom, in which the non-aqueous liquid electrolyte comprises a carbonate having at least either an unsaturated bond or a halogen atom.
摘要:
A nonaqueous electrolyte containing a monofluorophosphate and/or a difluorophosphate and a compound having a specific chemical structure or specific properties. The nonaqueous electrolyte can contain at least one of a saturated chain hydrocarbon, a saturated cyclic hydrocarbon, an aromatic compound having a halogen atom and an ether having a fluorine atom.