公开(公告)号：US20180015449A1

公开(公告)日：2018-01-18

申请号：US15715324

申请日：2017-09-26

Applicant: Momentive Performance Materials Inc. ,  PRINCETON UNIVERSITY

Inventor： Keith James Weller ,  Crista Carmen H. Atienza ,  Julie Boyer ,  Paul Chirik ,  Johannes G.P. Delis ,  Kenrick Lewis ,  Susan A. Nye

IPC: B01J31/18

CPC classification number: B01J31/1805 ,  B01J2231/323 ,  B01J2531/0244 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847

Abstract: Disclosed herein is the use of manganese, iron, cobalt, or nickel complexes containing tridentate pyridine di-imine ligands as hydrosilylation catalysts. These complexes are effective for efficiently catalyzing hydrosilylation reactions, as well as offering improved selectivity and yield over existing catalyst systems.

公开(公告)号：US11052383B2

公开(公告)日：2021-07-06

申请号：US15715324

申请日：2017-09-26

Applicant: Momentive Performance Materials Inc. ,  PRINCETON UNIVERSITY

Inventor： Keith James Weller ,  Crista Carmen H. Atienza ,  Julie Boyer ,  Paul Chirik ,  Johannes G. P. Delis ,  Kenrick Lewis ,  Susan A. Nye

IPC: B01J31/18

Abstract: Disclosed herein is the use of manganese, iron, cobalt, or nickel complexes containing tridentate pyridine di-imine ligands as hydrosilylation catalysts. These complexes are effective for efficiently catalyzing hydrosilylation reactions, as well as offering improved selectivity and yield over existing catalyst systems.

公开(公告)号：US10717752B2

公开(公告)日：2020-07-21

申请号：US15746448

申请日：2016-07-22

Applicant: MOMENTIVE PERFORMANCE MATERIALS INC. ,  PRINCETON UNIVERSITY

Inventor： Paul Chirik ,  Christopher Schuster ,  Julie Boyer ,  Kenrick Lewis ,  Johannes G. P. Delis ,  Aroop K. Roy

IPC: C08G77/08 ,  C07F7/18 ,  B01J31/18 ,  C07F15/06 ,  B01J31/22

Abstract: A process for producing a silylated product comprises reacting a mixture comprising (a) an unsaturated compound containing at least one unsaturated functional group, (b) a silyl hydride containing at least one silylhydride functional group, and (c) a catalyst, optionally in the presence of a solvent, to produce a dehydrogenative silylated product, a hydrosilylated product, or a combination of a dehydrogenative silylated product and a hydrosilylated product, wherein the catalyst is chosen from a pyridine diimine cobalt dicarboxylate complex or a cobalt carboxylate compound, and the process is conducted without pre-activating the catalyst via a reducing agent and/or without an initiator or promoter compound. The present catalysts have been found to be active in the presence of the silyl hydride employed in the silylation reaction.

公开(公告)号：US10981846B1

公开(公告)日：2021-04-20

申请号：US16542547

申请日：2019-08-16

Applicant: The United States of America, as represented by the Secretary of the Navy ,  The Trustees of Princeton University

Inventor： Benjamin G. Harvey ,  Kyle E. Rosenkoetter ,  Paul Chirik ,  C. Rose Kennedy

IPC: C07C5/03 ,  B01J31/02 ,  C07C2/46 ,  C10L1/16 ,  C10L1/04 ,  C07C7/04 ,  C07C2/44 ,  C07C13/26

Abstract: A method for making a fuel includes reacting a conjugated diene or a mixture of conjugated dienes with a catalyst selected from the group consisting of a low valent iron catalyst stabilized with a pyridineimine ligand, an iron precatalyst coordinated to the pyridineimine ligand that is activated with a reducing agent, a low oxidation state Fe complex stabilized with a pyridineimine ligand and a coordinating ligand, and combinations thereof, thereby forming a substituted cyclooctadiene. The substituted cyclooctadiene is then hydrogenated, thereby forming cyclooctane fuel.