公开(公告)号：US3594434A

公开(公告)日：1971-07-20

申请号：US3594434D

申请日：1968-04-03

申请人： STUDIENGESELLSCHAFT KOHLE MBH

发明人： WILKE GUNTHER ,  HEIMBACH PAUL ,  BRENNER WOLF-BERND

IPC分类号： C07C2/44 ,  B01J31/00 ,  C07C1/00 ,  C07C2/46 ,  C07C13/06 ,  C07C67/00 ,  C07C3/10

CPC分类号： C07C13/06 ,  C07C2/465 ,  C07C2531/12 ,  C07C2531/16 ,  C07C2601/04

摘要： A PROCESS FOR THE CATALYTIC DIMERISATION OF 1,3-DIOLEFINES IS DISCLOSED. PREFERRED DIOLEFINES ARE BUTADIENE, ISOPRENE AND PIPERYLENE. THE CATALYSTS USED ARE ONES FORMED BY MIXING A REDUCIBLE NICKEL COMPOUND AND A METAL HAVING A REDUCING ACTION WITH RESPECT TO THE REDUCIBLE NICKEL COMPOUND OR A HALOGEN-FREE ORGANOMETALLIC COMPOUND, OF WHICH METAL ALKYLS, METAL ARYLS OR METAL HYDRIDES ARE EXAMPLES, AND AN ELECTRON DONOR. THEY MAY ALSO BE FORMED BY MIXING A NICKEL COMPLEX COMPOUND WHICH CONTAINS O-VALENT NICKEL WITH AN ELECTRON DONOR. THE ELECTRON DONOR MAY BE AN ESTER OF A PHOSPHOROUS ACID OR A DIOLEFINE. THE PROCESS IS CARRIED OUT WITH INCOMPLETE CONVERSION OF THE 1,3-DIOLEFINE.

公开(公告)号：US10981846B1

公开(公告)日：2021-04-20

申请号：US16542547

申请日：2019-08-16

申请人： The United States of America, as represented by the Secretary of the Navy ,  The Trustees of Princeton University

发明人： Benjamin G. Harvey ,  Kyle E. Rosenkoetter ,  Paul Chirik ,  C. Rose Kennedy

IPC分类号： C07C5/03 ,  B01J31/02 ,  C07C2/46 ,  C10L1/16 ,  C10L1/04 ,  C07C7/04 ,  C07C2/44 ,  C07C13/26

摘要： A method for making a fuel includes reacting a conjugated diene or a mixture of conjugated dienes with a catalyst selected from the group consisting of a low valent iron catalyst stabilized with a pyridineimine ligand, an iron precatalyst coordinated to the pyridineimine ligand that is activated with a reducing agent, a low oxidation state Fe complex stabilized with a pyridineimine ligand and a coordinating ligand, and combinations thereof, thereby forming a substituted cyclooctadiene. The substituted cyclooctadiene is then hydrogenated, thereby forming cyclooctane fuel.

公开(公告)号：US3453197A

公开(公告)日：1969-07-01

申请号：US3453197D

申请日：1966-04-22

申请人： UNION CARBIDE CORP

发明人： TRECKER DAVID J ,  HENRY JOSEPH P ,  BRANDON RICHARD L

IPC分类号： C07C2/44 ,  C07C3/24

CPC分类号： C07C2/44 ,  C07C2601/04 ,  Y10S204/912 ,  Y10S204/914 ,  Y10S585/913 ,  C07C13/06

公开(公告)号：US09327265B2

公开(公告)日：2016-05-03

申请号：US13915113

申请日：2013-06-11

申请人： UOP LLC

发明人： Jeffery C. Bricker ,  John Q. Chen ,  Peter K. Coughlin

IPC分类号： C07C2/42 ,  C07C2/44 ,  C07C2/48 ,  C07C4/02 ,  B01J19/10 ,  B01J19/26 ,  B01J3/00 ,  C07C2/82 ,  C07C5/09

CPC分类号： B01J19/10 ,  B01J3/008 ,  B01J19/26 ,  B01J2219/00006 ,  B01J2219/00123 ,  B01J2219/00159 ,  B01J2219/00166 ,  C07C2/42 ,  C07C2/48 ,  C07C2/82 ,  C07C5/09 ,  Y02P30/44 ,  C07C11/24 ,  C07C15/00 ,  C07C11/04

摘要： Methods and systems are provided for converting methane in a feed stream to acetylene. The hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to a process stream having aromatic compounds. The acetylene stream can be reacted to generate larger hydrocarbon compounds, which are passed to a cyclization and aromatization reactor to generate aromatics. The method according to certain aspects includes controlling the level of carbon oxides in the hydrocarbon stream.

摘要翻译： 提供了将进料流中的甲烷转化为乙炔的方法和系统。 将烃流引入超音速反应器中并热解以将至少一部分甲烷转化为乙炔。 可以处理反应器流出物流以将乙炔转化为具有芳族化合物的工艺流。 乙炔流可以反应以产生较大的烃化合物，其被传递到环化和芳构化反应器以产生芳烃。 根据某些方面的方法包括控制烃流中的碳氧化物的含量。

公开(公告)号：US4396787A

公开(公告)日：1983-08-02

申请号：US324331

申请日：1981-11-23

申请人： Karl-Heinz Gluzek ,  Olaf Petersen ,  Wilhelm Neier ,  Gunter Strehlke ,  Karl-Heinz Heinemann

发明人： Karl-Heinz Gluzek ,  Olaf Petersen ,  Wilhelm Neier ,  Gunter Strehlke ,  Karl-Heinz Heinemann

IPC分类号： B01J10/00 ,  B01J19/00 ,  B01J27/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/44 ,  C07C2/50 ,  C07C7/20 ,  C07C13/06 ,  C07C13/20 ,  C07C13/263 ,  C07C67/00 ,  C07C3/035

CPC分类号： C07C7/20 ,  B01J19/0013 ,  B01J19/002 ,  C07C2/44 ,  C07C2/50 ,  B01J2219/00063 ,  B01J2219/00065 ,  B01J2219/00094 ,  B01J2219/00159 ,  B01J2219/00182 ,  B01J2219/00186 ,  B01J2219/00252 ,  C07C2101/16

摘要： Formation of undesirable popcorn polymer on the walls of a reaction vessel during thermal dimerization of butadiene is prevented by coating the walls with a falling film of aqueous sodium nitrite solution.

摘要翻译： 通过用亚硝酸钠水溶液的降膜涂覆壁，防止在丁二烯的热二聚期间在反应容器的壁上形成不期望的爆米花聚合物。

公开(公告)号：US5401891A

公开(公告)日：1995-03-28

申请号：US169847

申请日：1993-12-17

申请人： Michael J. Keenan ,  David W. Sharp ,  Robert C. Schucker

发明人： Michael J. Keenan ,  David W. Sharp ,  Robert C. Schucker

IPC分类号： B01D61/36 ,  B01D71/54 ,  B01D71/64 ,  B01D71/74 ,  C07C2/44 ,  C07C2/50 ,  C07C7/144 ,  C07C13/61 ,  C07C7/00 ,  C07C1/00

CPC分类号： C07C13/61 ,  C07C2/44 ,  C07C2103/68

摘要： A process for purifying crude dicyclopentadiene which comprises the steps of: cracking the crude dicyclopentadiene to form a monomeric-containing effluent which comprises at least one monomer selected from the group consisting of: C.sub.4 acyclic dienes, C.sub.5 acyclic dienes, cyclopentadiene and methylcyclopentadiene; separating the monomeric-containing effluent into a cyclopentadiene-enriched stream and a cyclopentadiene-poor stream; dimerizing the cyclopentadiene-enriched stream to form a dimerizer effluent; contacting a membrane separator under pervaporation conditions with the dimerizer effluent wherein the C.sub.4 acyclic dienes, C.sub.5 acyclic dienes and cyclopentadiene permeate through the membrane separator and wherein a dicyclopentadiene product having a purity of at least about 98% is retained as retentate.

摘要翻译： 一种用于纯化粗二环戊二烯的方法，其包括以下步骤：裂解粗二环戊二烯以形成含单体的流出物，其包含至少一种选自以下的单体：C 4无环二烯，C5无环二烯，环戊二烯和甲基环戊二烯; 将含单体的流出物分离成富含环戊二烯的流和不饱和环戊二烯流; 使富含环戊二烯的流二聚化以形成二聚体流出物; 使膜分离器在渗透蒸发条件下与二聚化器流出物接触，其中C4无环二烯，C5无环二烯和环戊二烯渗透通过膜分离器，并且其中保留纯度至少为约98％的二环戊二烯产物作为保留物。

公开(公告)号：US5321177A

公开(公告)日：1994-06-14

申请号：US869612

申请日：1992-04-16

申请人： Takao Nakamura ,  Masaru Kawakita ,  Katsumi Minomiya

发明人： Takao Nakamura ,  Masaru Kawakita ,  Katsumi Minomiya

IPC分类号： C07C2/44 ,  C07C4/22 ,  C07C13/15 ,  C07C13/61 ,  C07C5/31 ,  C07C7/148 ,  C07C403/00

CPC分类号： C07C4/22 ,  C07C2/44 ,  C07C7/04 ,  C07C2101/10 ,  C07C2103/68

摘要： Recently, as a process for manufacturing cyclopentadiene resin-shaped articles, an attention has been given to reaction injection molding (RIM). To conduct RIM, it is necessary to use high purity dicyclopentadiene (DCPD) as the raw material. Vapor-phase thermal cracking of DCPD is usually used as a step of process for manufacturing high purity DCPD. Hithertofore, when conducting thermal cracking of DCPD, coke formation within cracking tubes is the most serious and troublesome problem. A vapor-phase thermal cracking process for resolving the problem by a very simple procedure is described herein. Further, a process for manufacturing high purity DCPD suitable as a raw material for use in RIM utilizing the vapor-phase thermal cracking process just mentioned above is also described.

摘要翻译： 近来，作为制造环戊二烯树脂制品的方法，注意反应注射成型（RIM）。 为了进行RIM，需要使用高纯度二环戊二烯（DCPD）作为原料。 DCPD的气相热裂解通常用作制造高纯度DCPD的工艺步骤。 到目前为止，当进行DCPD的热裂解时，裂化管内的焦炭形成是最严重和最麻烦的问题。 本文描述了通过非常简单的过程解决问题的气相热裂解方法。 此外，还描述了一种适用于利用上述气相热裂解方法的RIM中使用的原料的高纯度DCPD的方法。

公开(公告)号：US2631173A

公开(公告)日：1953-03-10

申请号：US6924849

申请日：1949-01-04

申请人： PHILLIPS PETROLEUM CO

发明人： HILLYER JOHN C ,  SMITH JAMES V

IPC分类号： C07C2/44

CPC分类号： C07C2/44 ,  C07C2601/18 ,  Y10S585/905 ,  C07C13/263