公开(公告)号：US09890182B2

公开(公告)日：2018-02-13

申请号：US14270661

申请日：2014-05-06

Applicant: MOMENTIVE PERFORMANCE MATERIALS INC. ,  PRINCETON UNIVERSITY

Inventor： Crisita Carmen Hojilla Atienza ,  Aroop Kumar Roy ,  Paul J. Chirik ,  Keith J. Weller ,  Johannes G. P. Delis ,  Tianning Diao

IPC: C07F7/08 ,  B01J31/18

CPC classification number: C07F7/0812 ,  B01J31/1815 ,  B01J2231/323 ,  B01J2531/0216 ,  B01J2531/0244 ,  B01J2531/842 ,  C07F7/0803

Abstract: The present invention is directed to a selective and efficient process for the hydrosilylation of compounds containing terminally unsaturated 1,3-dienes using iron-based hydrosilylation catalysts. The resulting 1,2-addition products are useful as precursors for various silicone materials or silane- or silyl/silicone-functionalized polyolefins.

公开(公告)号：US09371340B2

公开(公告)日：2016-06-21

申请号：US14547696

申请日：2014-11-19

Applicant: Momentive Performance Materials Inc. ,  Princeton University

Inventor： Tianning Diao ,  Paul J. Chirik ,  Aroop Kumar Roy ,  Kenrick Lewis ,  Susan Nye ,  Keith J. Weller ,  Johannes G. P. Delis ,  Renyuan Yu

IPC: C08G65/22 ,  C07F7/08 ,  C07F7/18 ,  B01J31/18 ,  C07F15/06 ,  C08L83/04 ,  C08L83/14 ,  C08G59/00 ,  C08G77/38 ,  C08G77/12 ,  C08G77/20

CPC classification number: C07F7/0829 ,  B01J31/1815 ,  B01J2231/323 ,  B01J2531/0241 ,  B01J2531/0244 ,  B01J2531/845 ,  C07F7/0838 ,  C07F7/0879 ,  C07F7/1804 ,  C07F7/1876 ,  C07F15/065 ,  C08G77/12 ,  C08G77/20 ,  C08G77/38 ,  C08L83/04 ,  C08L83/14

Abstract: Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation, hydrosilylation, and crosslinking catalysts.

Abstract translation: 本文公开了含有三齿吡啶二亚胺配体的钴络合物及其作为有效和选择性脱氢甲硅烷基化，氢化硅烷化和交联催化剂的用途。

公开(公告)号：US10112961B2

公开(公告)日：2018-10-30

申请号：US15037954

申请日：2014-11-19

Applicant: THE TRUSTEES OF PRINCETON UNIVERSITY

Inventor： Paul J. Chirik ,  Tianning Diao ,  Renyuan Yu

IPC: C07F15/00 ,  C07F5/02 ,  B01J31/22 ,  C07F19/00 ,  C07F7/18 ,  C07F15/06 ,  C07F7/08 ,  B01J31/18

Abstract: In one aspect, cobalt complexes are described herein. In some embodiments, such cobalt complexes are operable as catalysts for hydroboration and borylation applications.