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公开(公告)号：US09637691B2
公开(公告)日：2017-05-02
申请号：US13988748
申请日：2011-11-18
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
IPC: C10G29/20 , C10G29/22 , C10G29/24 , B01D53/52 , B01D53/14 , B01D53/77 , C10L3/10 , C10L1/185 , C10L1/198
CPC classification number: C10G29/20 , B01D53/1493 , B01D53/52 , B01D53/77 , B01D2252/20 , B01D2252/2028 , B01D2256/24 , C10G29/22 , C10G29/24 , C10G2300/1033 , C10G2300/207 , C10G2300/80 , C10L1/1857 , C10L1/1985 , C10L3/103
Abstract: The present invention relates to hydrogen sulfide scavenging additive composition comprising glyoxal and a polymer compound which is polymer made from propylene oxide, which is capable of scavenging or removing hydrogen sulfide in hydrocarbons or hydrocarbon streams without causing any problem. The present invention is also relates to a method of scavenging hydrogen sulfide employing present scavenging additive composition comprising glyoxal and a polymer compound which is polymer made from propylene oxide. The present invention is also relates to a method of using hydrogen sulfide scavenging additive composition comprising glyoxal and a polymer compound which is polymer made from propylene oxide.
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2.发明授权Naphthenic acid corrosion inhibition using new synergetic combination of phosphorus compounds 有权使用磷化合物的新协同组合使用环烷酸腐蚀抑制公开(公告)号：US09228142B2
公开(公告)日：2016-01-05
申请号：US12594320
申请日：2008-04-03
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
Abstract: The present invention relates to the field of processing hydrocarbons which causes corrosion in the metal surfaces of processing units. The invention addresses the technical problem of high temperature naphthenic acid corrosion and sulphur corrosion and provides a solution to inhibit these types of corrosion. The three combination compositions are formed by three mixtures separately, with one mixture obtained by mixing compound A, which is obtained by reacting high reactive polyisobutylene (HRPIB) with phosphorous pentasulphide in presence of catalytic amount of sulphur with compound B such as trialkyl phosphate and second mixture obtained by mixing compound A with compound C such as phosphite like di-isodecyl phenyl phosphite, and third mixture obtained by mixing compound A with compound D such as a phosphonate, wherein each of these three mixtures independently provide high corrosion inhibition efficiency in case of high temperature naphthenic acid corrosion inhibition and sulphur corrosion inhibition. The invention is useful in all hydrocarbon processing units, such as, refineries, distillation columns and other petrochemical industries.
Abstract translation: 本发明涉及在处理单元的金属表面中引起腐蚀的烃的加工领域。 本发明解决了高温环烷酸腐蚀和硫腐蚀的技术问题，并提供了抑制这些腐蚀类型的溶液。 三种组合组合物分别由三种混合物形成，一种混合物通过混合化合物A，其通过使高活性聚异丁烯（HRPIB）与五硫化磷在催化量的硫存在下与化合物B如磷酸三烷基酯和第二 通过将化合物A与化合物C如亚磷酸酯如二异癸基苯基亚磷酸酯混合而获得的混合物，以及通过将化合物A与化合物D如膦酸酯混合而获得的第三混合物，其中这三种混合物中的每一种独立地提供高的腐蚀抑制效率， 高温环烷酸腐蚀抑制和硫磺腐蚀抑制。 本发明可用于所有烃处理装置，如炼油厂，蒸馏塔和其他石化行业。
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公开(公告)号：US08778172B2
公开(公告)日：2014-07-15
申请号：US13318593
申请日：2010-05-03
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
IPC: C10G17/02
CPC classification number: B01D53/52 , B01D53/1493 , C10G29/22 , C10G29/24 , C10G2300/1033 , C10G2300/207 , C10G2300/80 , C10L3/10 , C10L3/102
Abstract: The invention is related to hydrogen sulfide scavenging additive, capable of scavenging hydrogen sulfide in hydrocarbons by forming water soluble scavenged products which are capable of getting separated from hydrocarbon even at acidic pH without causing fouling and decomposition problems, consisting of aldehyde or aldehyde and polyethylene glycol [PEG], and wherein said aldehyde is glyoxylic acid. The invention is also related to a method of scavenging hydrogen sulfide employing present scavenging additive.
Abstract translation: 本发明涉及硫化氢清除添加剂，其能够通过形成水溶性清除产物来清除烃中的硫化氢，即使在酸性pH下也能与烃分离，而不引起由醛或醛和聚乙二醇组成的结垢和分解问题 [PEG]，并且其中所述醛是乙醛酸。 本发明还涉及采用清除添加剂清除硫化氢的方法。
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4.发明授权Additive and method for removal of impurities formed due to sulfur compounds in crude oils containing calcium naphthenate 有权用于除去含有环烷酸钙的原油中由于硫化合物形成的杂质的添加剂和方法公开(公告)号：US08679324B2
公开(公告)日：2014-03-25
申请号：US13519831
申请日：2010-12-28
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
IPC: C10G17/00
CPC classification number: C10G17/02 , B01D43/00 , C10G2300/205 , C10G2300/207 , C10G2300/80 , C10G2300/805 , E21B37/00 , E21B43/00
Abstract: An additive capable of avoiding formation of impurities and capable of removing or dissolving impurities formed and accumulated at the interphase of organic and aqueous layers on reaction between calcium naphthenate and sulfur compound including H2S in presence of water in mixture of crude oils containing calcium naphthenate and sulfur compound or H2S, wherein the additive is glyoxylic acid is provided. A method for avoiding formation of impurities and for removing or dissolving impurities formed and accumulated at the interphase of organic and aqueous layers on reaction between calcium naphthenate and sulfur compound including H2S in presence of water in mixture of crude oils containing calcium naphthenate and sulfur compound including H2S, comprising treating mixture of crude oils containing calcium naphthenate and sulfur compound or H2S with glyoxylic acid is also provided.
Abstract translation: 一种添加剂，其能够避免形成杂质，并且能够除去或溶解在含有环烷酸钙和硫的原油的混合物存在下，在环烷酸钙和包括H 2 S的硫化合物之间的反应中在有机层和水层的相间形成和积累的杂质 化合物或H2S，其中添加剂是乙醛酸。 一种用于在含有环烷酸钙和硫化合物的原油混合物中存在水的情况下，避免形成杂质并除去或溶解形成和积累在有机层和水层间的杂质的方法，所述杂质包括环烷酸钙和包括H 2 S在内的硫化合物之间的反应，所述原油包含 H2S还包括用乙醛酸处理含有环烷酸钙和硫化合物或H 2 S的原油的混合物。
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公开(公告)号：US20120055848A1
公开(公告)日：2012-03-08
申请号：US13318593
申请日：2010-05-03
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
CPC classification number: B01D53/52 , B01D53/1493 , C10G29/22 , C10G29/24 , C10G2300/1033 , C10G2300/207 , C10G2300/80 , C10L3/10 , C10L3/102
Abstract: The invention is related to hydrogen sulfide scavenging additive, capable of scavenging hydrogen sulfide in hydrocarbons by forming water soluble scavenged products which are capable of getting separated from hydrocarbon even at acidic pH without causing fouling and decomposition problems, consisting of aldehyde or aldehyde and polyethylene glycol [PEG], and wherein said aldehyde is glyoxylic acid. The invention is also related to a method of scavenging hydrogen sulfide employing present scavenging additive.
Abstract translation: 本发明涉及硫化氢清除添加剂，其能够通过形成水溶性清除产物来清除烃中的硫化氢，即使在酸性pH下也能与烃分离，而不引起由醛或醛和聚乙二醇组成的结垢和分解问题 [PEG]，并且其中所述醛是乙醛酸。 本发明还涉及采用清除添加剂清除硫化氢的方法。
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Patent Agency Ranking
6.发明申请NAPHTHENIC ACID CORROSION INHIBITION USING NEW SYNERGETIC COMBINATION OF PHOSPHORUS COMPOUNDS 有权使用磷酸盐化合物的新协同组合的萘酸腐蚀抑制公开(公告)号：US20100116718A1
公开(公告)日：2010-05-13
申请号：US12594320
申请日：2008-04-03
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
Abstract: The present invention relates to the field of processing hydrocarbons which causes corrosion in the metal surfaces of processing units. The invention addresses the technical problem of high temperature naphthenic acid corrosion and sulphur corrosion and provides a solution to inhibit these types of corrosion. The three combination compositions are formed by three mixtures separately, with one mixture obtained by mixing compound A, which is obtained by reacting high reactive polyisobutylene (HRPIB) with phosphorous pentasulphide in presence of catalytic amount of sulphur with compound B such as trialkyl phosphate and second mixture obtained by mixing compound A with compound C such as phosphite like di-isodecyl phenyl phosphite, and third mixture obtained by mixing compound A with compound D such as a phosphonate, wherein each of these three mixtures independently provide high corrosion inhibition efficiency in case of high temperature naphthenic acid corrosion inhibition and sulphur corrosion inhibition. The invention is useful in all hydrocarbon processing units, such as, refineries, distillation columns and other petrochemical industries.
Abstract translation: 本发明涉及在处理单元的金属表面中引起腐蚀的烃的加工领域。 本发明解决了高温环烷酸腐蚀和硫腐蚀的技术问题，并提供了抑制这些腐蚀类型的溶液。 三种组合组合物分别由三种混合物形成，一种混合物通过混合化合物A，其通过使高活性聚异丁烯（HRPIB）与五硫化磷在催化量的硫存在下与化合物B如磷酸三烷基酯和第二 通过将化合物A与化合物C如亚磷酸酯如二异癸基苯基亚磷酸酯混合而获得的混合物，以及通过将化合物A与化合物D如膦酸酯混合而获得的第三混合物，其中这三种混合物中的每一种独立地提供高的腐蚀抑制效率 高温环烷酸腐蚀抑制和硫磺腐蚀抑制。 本发明可用于所有烃处理装置，如炼油厂，蒸馏塔和其他石化行业。
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公开(公告)号：US10787619B2
公开(公告)日：2020-09-29
申请号：US13061045
申请日：2009-08-26
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
Abstract: The present invention relates to the field of inhibition of metal corrosion in hot acidic hydrocarbons, wherein acidity is derived from presence of naphthenic acid. More particularly, it relates to a polymeric additive for inhibiting high temperature napthenic acid corrosion, wherein said polymeric additive is polymeric phosphate ester of polyisobutylene succinate ester or oxide derivative of polymeric phosphate ester of polyisobutylene succinate ester. A polymeric phosphate ester of polyisobutylene succinate ester which is capable of acting as naphthenic acid corrosion inhibitor by inhibiting naphthenic acid corrosion in crude oil/feedstock/hydrocarbon streams containing naphthenic acid, and demonstrating higher thermal stability at elevated temperature varying from about 200° C. to about 400° C. [about 400° F. to about 750° F.] is disclosed.
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8.发明申请Additive Composition for Control and Inhibition of Polymerization of Styrene, and Method of Preparation and Use Thereof 有权用于控制和抑制苯乙烯聚合的添加剂组合物及其制备和使用方法公开(公告)号：US20140200375A1
公开(公告)日：2014-07-17
申请号：US14240817
申请日：2012-08-17
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
Abstract: The present invention relates to additive composition for control and inhibition of polymerization of styrene, wherein the composition comprises amine and quinone methide, and wherein the amine is polymerization non-inhibitor amine. In one embodiment, the present invention relates to method of preparation and use of additive composition to control and inhibit polymerization of styrene, wherein the composition comprises amine and quinone methide, and wherein the amine is polymerization non-inhibitor amine. In another embodiment, the present invention relates to additive composition for control and inhibition of polymerization of styrene, wherein the composition comprises oxide treated derivative of amine and quinone methide, and wherein the amine is polymerization non-inhibitor amine, and to the method of preparation and use thereof.
Abstract translation: 本发明涉及用于控制和抑制苯乙烯聚合的添加剂组合物，其中组合物包含胺和醌甲基化物，并且其中胺是聚合非抑制剂胺。 在一个实施方案中，本发明涉及制备和使用添加剂组合物以控制和抑制苯乙烯聚合的方法，其中所述组合物包含胺和醌甲基化物，并且其中所述胺是聚合非抑制剂胺。 在另一个实施方案中，本发明涉及用于控制和抑制苯乙烯聚合的添加剂组合物，其中所述组合物包含氧化物处理的胺和醌甲基化物的衍生物，其中胺是聚合非抑制剂胺，以及制备方法 及其用途。
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公开(公告)号：US08685233B2
公开(公告)日：2014-04-01
申请号：US12376962
申请日：2007-08-21
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
IPC: C10G17/04
Abstract: The invention relates to field of processing hydrocarbon feedstock including crude oil, wherein metals such as calcium are removed. In the face of the rising prices of crude oil, refiners are forced to process opportunity crudes such as DOBA, which pose many problems including fouling of equipment due to certain metallic salts, such as calcium napthenate. Calcium, which cannot be removed from crude oil during normal desalting process, poses very serious problems. The invention provides method for removal of calcium, wherein crude oil is mixed, with effective metal removing amount of aqueous extraction solution of an additive comprising a chemical compound selected from a group consisting of metallic acid, maleic anhydride or fumaric acid or salts or derivatives thereof, enabling separation of hydrocarboneous phase and aqueous phase containing metal ions, in crude desalter. Only hydrocarboneous phase devoid of calcium is processed further, thereby preventing fouling of equipment.
Abstract translation: 本发明涉及包括原油在内的烃原料的处理领域，其中除去诸如钙的金属。 面对原油价格上涨，炼油厂被迫处理诸如DOBA等机遇原因，造成许多问题，包括因某些金属盐造成的设备污染，如环烷酸钙。 在正常脱盐过程中不能从原油中除去的钙会造成非常严重的问题。 本发明提供了除去钙的方法，其中将原油混合，并将有效金属去除量的包含选自金属酸，马来酸酐或富马酸的化合物或其盐或衍生物的添加剂的水提取溶液 ，能够在粗脱盐剂中分离含烃相和含水相金属离子。 仅进一步处理没有钙的烃系相，从而防止设备结垢。
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10.发明申请Additive Composition and Method for Scavenging Hydrogen Sulfide in Hydrocarbon Streams 有权在烃流中清除硫化氢的添加剂组合物和方法公开(公告)号：US20130240409A1
公开(公告)日：2013-09-19
申请号：US13988748
申请日：2011-11-18
Applicant: Mahesh Subramaniyam
Inventor： Mahesh Subramaniyam
IPC: C10G29/20
CPC classification number: C10G29/20 , B01D53/1493 , B01D53/52 , B01D53/77 , B01D2252/20 , B01D2252/2028 , B01D2256/24 , C10G29/22 , C10G29/24 , C10G2300/1033 , C10G2300/207 , C10G2300/80 , C10L1/1857 , C10L1/1985 , C10L3/103
Abstract: The present invention relates to hydrogen sulfide scavenging additive composition comprising glyoxal and a polymer compound which is polymer made from propylene oxide, which is capable of scavenging or removing hydrogen sulfide in hydrocarbons or hydrocarbon streams without causing any problem. The present invention is also relates to a method of scavenging hydrogen sulfide employing present scavenging additive composition comprising glyoxal and a polymer compound which is polymer made from propylene oxide. The present invention is also relates to a method of using hydrogen sulfide scavenging additive composition comprising glyoxal and a polymer compound which is polymer made from propylene oxide.
Abstract translation: 本发明涉及包含乙二醛和聚合物化合物的硫化氢清除添加剂组合物，所述聚合物化合物是由环氧丙烷制成的聚合物，其能够清除或除去烃或烃流中的硫化氢而不引起任何问题。 本发明还涉及使用包含乙二醛和由环氧丙烷制成的聚合物的聚合物化合物的清除添加剂组合物来清除硫化氢的方法。 本发明还涉及使用包含乙二醛和聚合物化合物的硫化氢清除添加剂组合物的方法，所述聚合物化合物是由环氧丙烷制成的聚合物。
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