公开(公告)号：US5691288A

公开(公告)日：1997-11-25

申请号：US620197

申请日：1996-03-29

申请人： Major S. Dhillon

发明人： Major S. Dhillon

IPC分类号： B41N3/06 ,  B41N3/08 ,  C11D1/22 ,  C11D1/72 ,  C11D1/83 ,  C11D3/02 ,  C11D3/18 ,  C11D3/20 ,  C11D3/22 ,  C11D3/30 ,  C11D3/44

CPC分类号： B41N3/06 ,  B41N3/08 ,  C11D1/83 ,  C11D3/042 ,  C11D3/18 ,  C11D3/2044 ,  C11D3/222 ,  C11D3/30 ,  C11D1/22 ,  C11D1/72 ,  C11D3/2013 ,  C11D3/2065

摘要： A composition for finishing, preserving and cleaning lithographic printing plates which is composed of a polyol having a molecular weight in the range of from about 50 to about 3,000; a starch or dextrin hydrophilic film former; an alkyl benzene sulfonate amine salt; a composition of hydrocarbons containing less than about 10% aromatics and having a boiling point in the range of 175.degree. F. to 500.degree. F. and a flash point of above 100.degree. F.; a hydrogen, isooctyl, nonyl, decy or dodecyl substituted phenoxypoly(oxyethylene) ethanol surfactant having an HLB of 8 to 15; a C.sub.12 to C.sub.20 alcohol; mono-, di- or tri- ethanolamine; an organic or inorganic acid and water. The optional inclusion of a buffer salt and bacteriostat is preferred.

摘要翻译： 用于整理，保存和清洁平版印刷版的组合物，其由分子量在约50至约3,000范围内的多元醇组成; 淀粉或糊精亲水成膜剂; 烷基苯磺酸盐盐; 含有低于约10％芳族化合物并且沸点在175°F至500°F范围内和闪点高于100°F的烃的组合物。 HLB为8〜15的氢，异辛基，壬基，癸基或十二烷基取代苯氧基聚（氧乙烯）乙醇表面活性剂; C12至C20醇; 单 - ，二 - 或三 - 乙醇胺; 有机或无机酸和水。 任选地含有缓冲盐和抑菌剂。

公开(公告)号：US5432046A

公开(公告)日：1995-07-11

申请号：US128913

申请日：1993-09-29

申请人： Stanley F. Wanat ,  Major S. Dhillon ,  Gerhard Sprintschnik ,  Allen W. Loveland ,  Dennis A. King

发明人： Stanley F. Wanat ,  Major S. Dhillon ,  Gerhard Sprintschnik ,  Allen W. Loveland ,  Dennis A. King

IPC分类号： G03F7/11 ,  B41C1/10 ,  B41N3/04 ,  G03F7/30 ,  G03F7/38

CPC分类号： B41N3/04

摘要： Provided herein is a brushgraining process to improve the quality of lithographic printing plate substrate surfaces. In the process, the surface is brushed in an aqueous slurry comprising a mixture of particulates of alumina and quartz in a weight ratio range 95:5 to 5:95, with the particulates being in the size range of 1-20 microns. Such a process surprisingly lessens the number of scratches produced on the substrate surface than when compared to using alumina alone or quartz alone or a mixture of alumina and quartz with particle sizes higher than the range disclosed.

摘要翻译： 本文提供了一种用于提高平版印刷版基板表面的质量的刷涂工艺。 在该方法中，表面被刷洗在包含氧化铝和石英颗粒的混合物的水性浆液中，其重量比范围为95:5至5:95，颗粒的尺寸范围为1-20微米。 与仅使用单独的氧化铝或单独的石英或比所公开的范围高的粒度的氧化铝和石英的混合物相比，这种方法令人惊奇地减少了在基材表面上产生的划痕的数量。

公开(公告)号：US5120772A

公开(公告)日：1992-06-09

申请号：US874743

申请日：1986-06-16

申请人： John E. Walls ,  Carlos Tellechea ,  Major S. Dhillon

发明人： John E. Walls ,  Carlos Tellechea ,  Major S. Dhillon

IPC分类号： C08F2/46 ,  G03F7/033

CPC分类号： G03F7/033

摘要： This invention relates to a radiation polymerizable composition for use in a phtographic element such as a lithographic printing plate comprising in admixturea) a binder resin having the general formula--A--B--C-- wherein a plurality of each of components A, B and C occur in ordered or random sequence in the resin and wherein A is present in said resin at about 5% to about 20% by weight and comprises groups of the formula ##STR1## B is present in said resin at about 4% to about 30% by weight and comprises groups of the formula ##STR2## and C is present in said resin at about 50% to about 91% by weight and comprises acetal groups consisting of groups of the formulae ##STR3## where R is lower alkyl or hydrogen, and wherein said group I is present in component C from about 75% to about 85%, group II is present in component C from about 3% to about 5%; and group III is present in component C from about 10% to about 22%;b) a photoinitiator; andc) a photopolymerizable mixture ofi) a polyfunctional acrylic monomer having two or more unsaturated groups;ii) a monofunctional acrylic monomer having 1 unsaturated group.

摘要翻译： 本发明涉及一种用于诸如平版印刷版的成像元件的放射线聚合组合物，其包含a）具有通式-ABC的粘合剂树脂，其中多个组分A，B和C各自有序地发生 或随机序列，其中A以约5重量％至约20重量％存在于所述树脂中，并且包含下式的基团B以约4重量％至约30重量％存在于所述树脂中，并且 包含式（IMAGE）的基团，并且C以约50％至约91％（重量）的量存在于所述树脂中，并且包含由下式的组分组成的缩醛基：II）和III ），其中R是低级烷基或氢，并且其中组I中存在的组I为约75％至约85％，组II中存在组II的约3％至约5％; 组分C中组III存在约10％至约22％; b）光引发剂; 和c）i）具有两个或更多个不饱和基团的多官能丙烯酸单体的可光聚合混合物; ii）具有1个不饱和基团的单官能丙烯酸类单体。

公开(公告)号：US4652604A

公开(公告)日：1987-03-24

申请号：US762091

申请日：1985-08-02

申请人： John E. Walls ,  Carlos Tellechea ,  Major S. Dhillon

发明人： John E. Walls ,  Carlos Tellechea ,  Major S. Dhillon

IPC分类号： C08F2/50 ,  C08F4/20 ,  G03F7/033

CPC分类号： G03F7/033

摘要： This invention relates to a radiation polymerizable composition for use in a photographic element such as a lithographic printing plate comprising in admixture(a) a binder resin having the general formula--A--B--C-- wherein a plurality of each of components A, B and C occur in ordered or random sequence in the resin and wherein A is present in said resin at about 5% to about 20% by weight and comprises groups of the formula ##STR1## B is present in said resin at about 4% to about 30% by weight and comprises groups of the formula ##STR2## and C is present in said resin at about 50% to about 91% by weight and comprises acetal groups consisting of groups of the formulae ##STR3## where R is lower alkyl or hydrogen, and wherein said group I is present in component C from about 75% to about 85%, group II is present in component C from about 3% to about 5%; and group III is present in component C from about 10% to about 22%.(b) a photoinitiator;(c) a diazonium salt; and(d) a photopolymerizable mixture of(i) an acrylic monomer having two or more unsaturated groups; and(ii) an oligomer which is prepared by reacting one molar equivalent of a substantially linear polymeric compound having an active hydrogen group at each end thereof with a least two molar equivalents of a diisocyanate compound so as to form a prepolymer having an isocyanate group at each end thereof; and subsequently reacting said prepolymer with at least two equivalents of an ethylenically unsaturated compound having an active hydrogen group to provide said prepolymer with unsaturation at each end thereof.

摘要翻译： 本发明涉及用于照相材料如平版印刷版的可辐射聚合组合物，其包含（a）具有通式-ABC的粘合剂树脂，其中多个组分A，B和C各自出现在 树脂中有序或无规顺序，其中A以约5％至约20％重量存在于所述树脂中，并且包含下式的基团B以约4％至约30％重量存在于所述树脂中 并且包含式（IMAGE）的基团，并且C以约50％至约91％（重量）的量存在于所述树脂中，并且包含由式（I）的基团组成的缩醛基，其中R是低级烷基或氢，并且其中所述 组I中组I的含量为约75％至约85％，组分C中组II为约3％至约5％; 组分C中组III存在约10％至约22％。 （b）光引发剂; （c）重氮盐; 和（d）（i）具有两个或更多个不饱和基团的丙烯酸类单体的光聚合混合物; 和（ii）低聚物，其通过使一摩尔当量的在其各端具有活性氢基团的基本上线性的聚合物与至少两摩尔当量的二异氰酸酯化合物反应制备，以便形成具有异氰酸酯基的预聚物 其每端; 随后使所述预聚物与至少两当量的具有活性氢基团的烯键式不饱和化合物反应，以使所述预聚物在其每一末端具有不饱和键。

公开(公告)号：US5728503A

公开(公告)日：1998-03-17

申请号：US566759

申请日：1995-12-04

申请人： Major S. Dhillon ,  Gerhard Sprintschnik ,  Jose G. Gonzales

发明人： Major S. Dhillon ,  Gerhard Sprintschnik ,  Jose G. Gonzales

IPC分类号： G03F7/021 ,  B41N1/08 ,  B41N3/03 ,  C23F1/36 ,  C23F3/02 ,  C23G1/22 ,  C25D11/08 ,  C25F3/04 ,  G03F7/00 ,  G03F7/09

CPC分类号： B41N3/034 ,  C25F3/04 ,  Y10T428/12736 ,  Y10T428/12764 ,  Y10T428/12993 ,  Y10T428/266

摘要： The present invention relates to supports for lithographic printing plates and to a process for producing the same. In particular, the invention relates to aluminum plates having an electrochemically grained and anodized surface which is has a smooth, shiny surface and hence greater image contrast when a lithographic image is formed thereon. The surface has a substantially uniform surface topography comprising peaks and valleys and surface roughness parameters wherein Ra ranges from about 0.10 to about 0.50 microns, Rz ranges from about 0.00 to about 5.00 microns, Rt ranges from about 0.00 to about 6.00 microns and Rp ranges from about 0.00 to about 4.00 microns. The surface preferably has tristimulus color coordinate values wherein L ranges from about 35.00 to about 75.00, a ranges from about -4.00 to about +4.00 and b ranges from about -4.00 to about +4.00.

摘要翻译： 本发明涉及平版印刷版的支持体及其制造方法。 特别地，本发明涉及具有电化学颗粒和阳极氧化表面的铝板，其具有光滑的光泽表面，并且因此当在其上形成平版印刷图像时具有更大的图像对比度。 该表面具有包括峰和谷以及表面粗糙度参数的基本上均匀的表面形貌，其中Ra为约0.10至约0.50微米，Rz为约0.00至约5.00微米，Rt为约0.00至约6.00微米，Rp为 约0.00至约4.00微米。 表面优选具有三刺激色坐标值，其中L为约35.00至约75.00，a为约-4.00至约+4.00，b的范围为约-4.00至约+4.00。

公开(公告)号：US4707437A

公开(公告)日：1987-11-17

申请号：US924383

申请日：1986-10-29

申请人： John E. Walls ,  Carlos Tellechea ,  Major S. Dhillon

发明人： John E. Walls ,  Carlos Tellechea ,  Major S. Dhillon

IPC分类号： G03F7/033 ,  G03C1/76

CPC分类号： G03F7/033 ,  Y10T428/31667 ,  Y10T428/31692 ,  Y10T428/31797 ,  Y10T428/31855

摘要： This invention relates to a radiation polymerizable composition for use in a photographic element such as a lithographic printing plate comprising in admixture(a) a binder resin having the general formula--A--B--C-- wherein a plurality of each of components A, B and C occur in ordered or random sequence in the resin and wherein A is present in said resin at about 5% to about 20% by weight and comprises groups of the formula ##STR1## B is present in said resin at about 4% to about 30% by weight and comprises groups of the formula ##STR2## and C is present in said resin at about 50% to about 91% by weight and comprises acetal groups consisting of groups of the formulae ##STR3## where R is lower alkyl or hydrogen, and wherein said group I is present in component C from about 75% to about 85%, group II is present in component C from about 3% to about 5%; and group III is present in component C from about 10% to about 22%.(b) a photoinitiator;(c) a diazonium salt; and(d) a photopolymerizable mixture of(i) an acrylic monomer having two or more unsaturated groups; and(ii) an oligomer which is prepared by reacting one molar equivalent of a substantially linear polymeric compound having an active hydrogen group at each end thereof with at least two molar equivalents of a diisocyanate compound so as to form a prepolymer having an isocyanate group at each end thereof; and subsequently reacting said prepolymer with at least two equivalents of an ethylenically unsaturated compound having an active hydrogen group to provide said prepolymer with unsaturation at each end thereof.

摘要翻译： 本发明涉及用于照相材料如平版印刷版的可辐射聚合组合物，其包含（a）具有通式-ABC的粘合剂树脂，其中多个组分A，B和C各自出现在 树脂中有序或无序的序列，其中A以约5重量％至约20重量％存在于所述树脂中，并且包含下式的基团B以约4重量％至约30重量％存在于所述树脂中 并且包含式（IMAGE）的基团，并且C以约50％至约91％（重量）的量存在于所述树脂中，并且包含由式（I）的基团组成的缩醛基，其中R是低级烷基或氢，并且其中所述 组I中组I的含量为约75％至约85％，组分C中组II为约3％至约5％; 组分C中组III存在约10％至约22％。 （b）光引发剂; （c）重氮盐; 和（d）（i）具有两个或更多个不饱和基团的丙烯酸类单体的光聚合混合物; 和（ii）低聚物，其通过使一摩尔当量的在其各端具有活性氢基团的基本上线性的聚合物与至少两摩尔当量的二异氰酸酯化合物反应制备，以便形成具有异氰酸酯基团的预聚物 其每端; 随后使所述预聚物与至少两当量的具有活性氢基团的烯键式不饱和化合物反应，以使所述预聚物在其每一末端具有不饱和键。

公开(公告)号：US4554236A

公开(公告)日：1985-11-19

申请号：US543566

申请日：1983-10-19

申请人： Trisha Bentley ,  John E. Walls ,  Major S. Dhillon

发明人： Trisha Bentley ,  John E. Walls ,  Major S. Dhillon

IPC分类号： G03F7/016 ,  G03C1/60 ,  G03C1/94

CPC分类号： G03F7/0166

摘要： This invention relates to light sensitive water soluble diazonium compound condensation products stabilized against degradation caused by heat and/or prolonged storage employing selected amino acids as stabilizers. The invention also relates to presensitized reproduction materials comprising the amino acid stabilized water soluble diazonium compound condensation products.

摘要翻译： 本发明涉及使用所选择的氨基酸作为稳定剂的由热和/或长期储存稳定的防止降解的光敏水溶性重氮化合物缩合产物。 本发明还涉及包含氨基酸稳定化的水溶性重氮化合物缩合产物的致敏复制材料。

公开(公告)号：US4448873A

公开(公告)日：1984-05-15

申请号：US359460

申请日：1982-03-18

申请人： John E. Walls ,  Major S. Dhillon

发明人： John E. Walls ,  Major S. Dhillon

IPC分类号： G03F1/54 ,  G03F7/016 ,  G03C1/60 ,  G03C1/78

CPC分类号： G03F1/54 ,  G03F7/0166

摘要： A photographic element comprising a transparent support and a coating on the support comprising a diazonium composition having a light absorbency of about 45% or less, and a colorant composition, said coating having a light transmission of not more than about 0.1%.

摘要翻译： 一种照相元件，包括透明载体和载体上的涂层，其包含具有约45％或更小的光吸收率的重氮组合物和着色剂组合物，所述涂层具有不大于约0.1％的透光率。

公开(公告)号：US06451491B1

公开(公告)日：2002-09-17

申请号：US09688471

申请日：2000-10-16

申请人： Major S. Dhillon ,  Stanley F. Wanat ,  Gerhard Sprintschnik

发明人： Major S. Dhillon ,  Stanley F. Wanat ,  Gerhard Sprintschnik

IPC分类号： G03F7021

CPC分类号： G03F7/105 ,  G03F7/004

摘要： A color ant dispersion having a pigment, a solvent composition of a C1-C8 aliphatic alcohol, a mono- or di-C1-C8 alkylene glycol C1-C8 alkyl ether, or a cyclic ketone; and an aqueous alkaline soluble or swellable polymeric compound which is the reaction product of a hydroxy containing polymer and an anhydride in the presence of a catalytic amount of a tertiary amine catalyst. The pigment and the polymeric compound are present in a high relative weight ratio of from about 0.75:1.25 to about 1.25:0.75. An admixture of the dispersion, a light sensitive component diazonium compound or photopolymerizable composition and an aqueous alkaline soluble or swellable polymeric binder, when coated and dried onto a substrate, forms a photographic element, which when imagewise exposed and developed has an exceptionally high contrast between image and removed non-image areas.

摘要翻译： 具有颜料的颜色分散体，C1-C8脂族醇，单或二C1-C8亚烷基二醇C1-C8烷基醚或环酮的溶剂组合物; 以及在催化量的叔胺催化剂存在下，含羟基聚合物和酸酐的反应产物的水溶性碱溶性或可溶胀聚合物。 颜料和聚合化合物以约0.75:2.25至约1.25:0.75的高相对重量比存在。 当涂布和干燥到基底上时，分散体，光敏组分重氮化合物或可光聚合组合物和水性碱溶性或可溶胀聚合物粘合剂的混合物形成照相元件，当成像曝光和显影时具有非常高的对比度 图像和删除的非图像区域。

公开(公告)号：US4729935A

公开(公告)日：1988-03-08

申请号：US789236

申请日：1985-10-18

申请人： John E. Walls ,  Major S. Dhillon

发明人： John E. Walls ,  Major S. Dhillon

IPC分类号： G03F1/54 ,  G03F7/016 ,  G03F1/00 ,  G03C1/78 ,  G03F7/08

CPC分类号： G03F1/54 ,  G03F7/0166

摘要： A process for the production of photographic images utilizing a photographic element comprising a transparent support and a coating on the support comprising a diazonium composition having a light absorbency of about 45% or less, and a colorant composition, said coating having a light transmission of not more than about 0.1%.

摘要翻译： 一种使用包含透明支持​​体的照相元件和载体上的涂层制造照相图像的方法，其包含具有约45％或更小的光吸收率的重氮组合物和着色剂组合物，所述涂层具有不透光的透光性 超过约0.1％。