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    Nitrogen-heterocyclic compound and process for production thereof
    1.
    发明授权
    Nitrogen-heterocyclic compound and process for production thereof 失效
    氮杂环化合物及其制备方法

    公开(公告)号：US06346621B1

    公开(公告)日：2002-02-12

    申请号：US09523292

    申请日：2000-03-10

    申请人： Makoto Watanabe ,  Toshihide Yamamoto ,  Masakazu Nishiyama

    发明人： Makoto Watanabe ,  Toshihide Yamamoto ,  Masakazu Nishiyama

    IPC分类号： C07D24102

    CPC分类号： C07D491/04 ,  C07D209/08 ,  C07D403/04

    摘要： A nitrogen-heterocyclic compound is provided which is represented by General Formula (1): where R1 and R2 are independently hydrogen, an alkyl group, an aryl group, or a heteroaryl group; R3 is hydrogen or an aryl group; R4 is a substituted amino group, an alkoxy group, a nitro group, or halogen; m is an integer from 0 to 2; and n is 0 or 1. A process for producing the above compound is also provided. This compound is useful as a source material of medicines, pesticides, electronic materials, and intermediates for other substituted nitrogen-heterocyclic compounds.

    摘要翻译： 提供由通式（1）表示的氮杂环化合物：其中R 1和R 2独立地是氢，烷基，芳基或杂芳基; R3是氢或芳基; R4是取代氨基，烷氧基，硝基或卤素; m为0〜2的整数; 并且n为0或1.还提供了制备上述化合物的方法。 该化合物可用作药物，农药，电子材料和其它取代的氮杂环化合物的中间体的来源。

    Terphenylene derivative, tetrahaloterphenyl derivative, and processes for producing both
    3.
    发明授权
    Terphenylene derivative, tetrahaloterphenyl derivative, and processes for producing both 有权
    三苯并噻吩衍生物，四卤代苯基衍生物，以及二者的制造方法

    公开(公告)号：US07985885B2

    公开(公告)日：2011-07-26

    申请号：US11910759

    申请日：2006-03-28

    申请人： Makoto Watanabe ,  Tomokazu Ohashi ,  Toshihide Yamamoto

    发明人： Makoto Watanabe ,  Tomokazu Ohashi ,  Toshihide Yamamoto

    IPC分类号： C07C13/465 ,  C07C22/00

    CPC分类号： C07C211/56 ,  C07C1/28 ,  C07C13/62 ,  C07C22/08 ,  C07C25/22 ,  C07C25/24 ,  C07C211/61 ,  C07C2602/10 ,  C07C2603/52 ,  C07C2603/54 ,  C07F7/081 ,  H01L51/0055 ,  H01L51/0056 ,  H01L51/0058 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0094

    摘要： An object of the present invention relates to provision of a terphenylene derivative having excellent oxidation resistance and capable of forming a semiconductor active phase by a coating process and an oxidation-resistant organic semiconductor material using the same, as well as an organic thin film.The invention relates to production of a terphenylene derivative represented by the formula (1) by tetralithiating a tetrahaloterphenyl derivative with a lithiating agent and subsequently treating the resulting compound with a copper compound:[ka 1] wherein R1 to R14 are the same or different and each represents a hydrogen atom, a fluorine atom, a chlorine atom, an aryl group having 4 to 30 carbon atoms, an alkynyl group having 3 to 20 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, an alkyl group having 1 to 20 carbon atoms or a halogenated alkyl group having 1 to 20 carbon atoms, or a diarylamino group having 8 to carbon atoms; and l, m, and n each represents an integer of 0 or 1.

    摘要翻译： 本发明的目的在于提供具有优异抗氧化性并能够通过涂布方法形成半导体活性相的三亚苯衍生物和使用其的耐氧化有机半导体材料以及有机薄膜。 本发明涉及通过将四卤代苯基衍生物与锂化剂四氢萘酯化并随后用铜化合物处理所得化合物来制备由式（1）表示的三亚苯衍生物：[ka 1]其中R 1至R 14相同或不同， 各自表示氢原子，氟原子，氯原子，碳原子数4〜30的芳基，碳原子数3〜20的炔基，碳原子数2〜30的烯基，烷基，具有1〜 20个碳原子或具有1至20个碳原子的卤代烷基或具有8个碳原子的二芳基氨基; 并且l，m和n各自表示0或1的整数。

    TERPHENYLENE DERIVATIVE, TETRAHALOTERPHENYL DERIVATIVE, AND PROCESSES FOR PRODUCING BOTH
    4.
    发明申请
    TERPHENYLENE DERIVATIVE, TETRAHALOTERPHENYL DERIVATIVE, AND PROCESSES FOR PRODUCING BOTH 有权
    二苯并噻吩衍生物，四氢苯并噻唑衍生物及其制备方法

    公开(公告)号：US20090023957A1

    公开(公告)日：2009-01-22

    申请号：US11910759

    申请日：2006-03-28

    申请人： Makoto Watanabe ,  Tomokazu Ohashi ,  Toshihide Yamamoto

    发明人： Makoto Watanabe ,  Tomokazu Ohashi ,  Toshihide Yamamoto

    IPC分类号： C07C25/22 ,  C07C13/62 ,  C07C211/61 ,  C07C17/263 ,  C07C1/28

    CPC分类号： C07C211/56 ,  C07C1/28 ,  C07C13/62 ,  C07C22/08 ,  C07C25/22 ,  C07C25/24 ,  C07C211/61 ,  C07C2602/10 ,  C07C2603/52 ,  C07C2603/54 ,  C07F7/081 ,  H01L51/0055 ,  H01L51/0056 ,  H01L51/0058 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0071 ,  H01L51/0094

    摘要： An object of the present invention relates to provision of a terphenylene derivative having excellent oxidation resistance and capable of forming a semiconductor active phase by a coating process and an oxidation-resistant organic semiconductor material using the sane, as well as an organic thin film.The invention relates to production of a terphenylene derivative represented by the formula (1) by tetralithiating a tetrahaloterphenyl derivative with a lithiating agent and subsequently treating the resulting compound with a copper compound: wherein R1 to R14 are the same or different and each represents a hydrogen atom, a fluorine atom, a chlorine atom, an aryl group having 4 to 30 carbon atoms, an alkynyl group having 3 to 20 carbon atoms, an alkenyl group having 2 to 30 carbon atoms, an alkyl group having 1 to 20 carbon atoms or a halogenated alkyl group having 1 to 20 carbon atoms, or a diarylamino group having 8 to carbon atoms; and l, m, and n each represents an integer of 0 or 1.

    摘要翻译： 本发明的目的在于提供具有优异的耐氧化性并能够通过涂布工艺形成半导体活性相的三亚苯衍生物和使用该系统的耐氧化有机半导体材料以及有机薄膜。 本发明涉及通过将四卤代苯基衍生物与锂化剂四氢萘酯化并随后用铜化合物处理所得化合物来制备由式（1）表示的三亚苯衍生物：其中R1至R14相同或不同，并且各自表示氢 原子，氟原子，氯原子，碳原子数为4〜30的芳基，碳原子数3〜20的炔基，碳原子数2〜30的烯基，碳原子数1〜20的烷基， 碳原子数1〜20的卤代烷基或碳原子数为8的二芳基氨基; 并且l，m和n各自表示0或1的整数。

    Sulfur-containing cyclic olefin resin and its production method
    7.
    发明授权
    Sulfur-containing cyclic olefin resin and its production method 失效
    含硫环烯烃树脂及其制备方法

    公开(公告)号：US07709583B2

    公开(公告)日：2010-05-04

    申请号：US11914806

    申请日：2006-05-15

    申请人： Takashi Okada ,  Toshihide Yamamoto ,  Hiroshi Yamakawa

    发明人： Takashi Okada ,  Toshihide Yamamoto ,  Hiroshi Yamakawa

    IPC分类号： C08G75/00

    CPC分类号： C08G61/12 ,  C07D339/00 ,  C08G61/122 ,  G11B7/2538

    摘要： A sulfur-containing cyclic olefin resin comprising a unit represented by the following general formula (1) and having a weight average molecular weight of from 1,000 to 1,000,000. (Here, R1 to R6 each independently represents a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms, an aralkyl group having from 1 to 20 carbon atoms, an aromatic group having from 1 to 20 carbon atoms, a cyano group, an alkoxy group having from 1 to 10 carbon atoms or a heterocyclic compound, further R3 to R6 may be a halogen atom, R3 and R4, and R5 and R6 may form a ring containing carbon, oxygen, sulfur or nitrogen, R7 and R8′ each independently represents a hydrogen atom or a methyl group, . . . represents a single bond or a double bond, and l and m each is 0 or 1.)

    摘要翻译： 一种含硫环状烯烃树脂，其含有下述通式（1）表示的单元，重均分子量为1,000〜1,000,000。 （这里，R 1〜R 6各自独立地表示氢原子，碳原子数1〜20的烷基，碳原子数1〜20的芳烷基，碳原子数1〜20的芳香族基，氰基， 具有1至10个碳原子的烷氧基或杂环化合物，另外R 3至R 6可以是卤素原子，R 3和R 4，并且R 5和R 6可以形成含有碳，氧，硫或氮的环，R 7和R 8' 各自独立地表示氢原子或甲基，...表示单键或双键，l和m各自为0或1.）

    Combustion chamber structure for an engine
    9.
    发明授权
    Combustion chamber structure for an engine 失效
    发动机燃烧室结构

    公开(公告)号：US5335634A

    公开(公告)日：1994-08-09

    申请号：US883335

    申请日：1992-05-14

    申请人： Kazuhiko Hashimoto ,  Yoshihiko Imamura ,  Toshihide Yamamoto ,  Yoshihisa Noh

    发明人： Kazuhiko Hashimoto ,  Yoshihiko Imamura ,  Toshihide Yamamoto ,  Yoshihisa Noh

    IPC分类号： F02B1/04 ,  F02B23/08 ,  F02B31/00 ,  F02B31/08

    CPC分类号： F02B31/085 ,  F02B23/08 ,  F02B1/04 ,  F02B2031/006 ,  Y02T10/125 ,  Y02T10/146

    摘要： A combustion chamber for an engine is provided between a cylinder bore formed in a cylinder block, a generally conically-shaped wall formed in an under wall of a cylinder head, and a piston in the cylinder bore. The combustion chamber has a structure into which an intake port opens so as to introduce an intake air flow closer to a marginal portion than a central portion of the combustion chamber, thereby generating a swirl flow of intake air in the combustion chamber. The combustion chamber also includes a curved air flow guide wall formed in the generally conically-shaped wall which extends from near the intake port so as to approach the cylinder bore surface gradually, thereby generating what is termed a squish flow of intake air.

    摘要翻译： 用于发动机的燃烧室设置在形成在气缸体中的气缸孔，形成在气缸盖的下壁中的大致锥形的壁和气缸孔中的活塞之间。 燃烧室具有进气口打开的结构，以便引入比燃烧室的中心部分更靠近边缘部分的进气流，从而在燃烧室中产生进气的旋流。 燃烧室还包括形成在大致圆锥形壁上的弯曲气流引导壁，其从进气口附近延伸，以便逐渐接近缸孔表面，从而产生所谓的挤压的进气流。

    SULFUR-CONTAINING CYCLIC OLEFIN RESIN AND ITS PRODUCTION METHOD
    10.
    发明申请
    SULFUR-CONTAINING CYCLIC OLEFIN RESIN AND ITS PRODUCTION METHOD 失效
    含硫的环烯烃树脂及其生产方法

    公开(公告)号：US20090069503A1

    公开(公告)日：2009-03-12

    申请号：US11914806

    申请日：2006-05-15

    申请人： Takashi Okada ,  Toshihide Yamamoto ,  Hiroshi Yamakawa

    发明人： Takashi Okada ,  Toshihide Yamamoto ,  Hiroshi Yamakawa

    IPC分类号： C08F28/06 ,  C07D339/00

    CPC分类号： C08G61/12 ,  C07D339/00 ,  C08G61/122 ,  G11B7/2538

    摘要： An object of the present invention is to provide a novel sulfur-containing cyclic olefin resin having high transparency and high refractive index and being expected to utilization to optical materials such as various plastic lenses represented by a condensing lens, prism sheets, antireflective films, transparent coating materials such as an optical fiber coating material, optical films and the like, and its production method.The present invention relates to a sulfur-containing cyclic olefin resin comprising a unit represented by the following general formula (1) and having a weight average molecular weight of from 1,000 to 1,000,000. (Here, R1 to R6 each independently represents a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms, an aralkyl group having from 1 to 20 carbon atoms, an aromatic group having from 1 to 20 carbon atoms, a cyano group, an alkoxy group having from 1 to 10 carbon atoms or a heterocyclic compound, further R3 to R6 may be a halogen atom, R3 and R4, and R5 and R6 may form a ring containing carbon, oxygen, sulfur or nitrogen, R7 and R8′, each independently represents a hydrogen atom or a methyl group, . . . represents a single bond or a double bond, and 1 and m each is 0 or 1.)

    摘要翻译： 本发明的目的是提供一种具有高透明度和高折射率的新型含硫环状烯烃树脂，并且预期可用于诸如由聚光透镜，棱镜片，抗反射膜，透明膜 涂布材料如光纤涂层材料，光学膜等及其制造方法。 本发明涉及含有下述通式（1）所示的单元且重均分子量为1,000〜1,000,000的含硫环状烯烃树脂。 （这里，R 1〜R 6各自独立地表示氢原子，碳原子数1〜20的烷基，碳原子数1〜20的芳烷基，碳原子数1〜20的芳香族基，氰基， 具有1至10个碳原子的烷氧基或杂环化合物，另外R 3至R 6可以是卤素原子，R 3和R 4，并且R 5和R 6可以形成含有碳，氧，硫或氮的环，R 7和R 8' ，各自独立地表示氢原子或甲基，...表示单键或双键，1和m各自为0或1.）