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1.发明授权High refractive index glasses of limited specific gravity for distance and near vision spectacle lenses 失效用于距离和近视眼镜片的有限比重的高折射率眼镜
公开(公告)号：US4213787A
公开(公告)日：1980-07-22
申请号：US45613
申请日：1979-06-05
IPC分类号： C03C3/062 , C03C3/064 , C03C3/066 , C03C3/068 , C03C3/07 , C03C3/072 , C03C3/074 , E05B49/00 , G02C7/00 , G07C9/00 , C03C3/04 , C03C3/08 , C03C3/10
CPC分类号： C03C3/066 , C03C3/062 , C03C3/064 , C03C3/068 , C03C3/07 , C03C3/072 , C03C3/074 , Y10S501/90 , Y10S501/901
摘要： Optical glasses having high refractive indexes and low specific gravities are provided for use as both distant and near vision spectacle lenses. The glasses consist essentially of low molecular weight cationic oxides, alkali metal oxides and divalent oxides to promote the crystallization stability of the glass. They have good chemical resistance, chemical hardenability and a thermal expansion coefficient between 93 and 99.times.10.sup.-7 /.degree. C. in the range of 20.degree.-300.degree. C. Optical lenses can be continuously produced due to the high crystallization stability of the glasses and the resultant spectacle lenses have high dioptric values even with thinner edge or center thicknesses.
摘要翻译： 提供具有高折射率和低比重的光学眼镜用作远视眼镜和近视眼镜镜片。 玻璃基本上由低分子量阳离子氧化物，碱金属氧化物和二价氧化物组成，以促进玻璃的结晶稳定性。 它们具有良好的耐化学腐蚀性，化学硬化性和93〜99×10-7 /℃的热膨胀系数，在20〜300℃的范围内。由于玻璃的高结晶稳定性，可连续生产光学透镜， 即使具有较薄的边缘或中心厚度，所得眼镜镜片也具有高度的屈光度值。
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公开(公告)号：US4213786A
公开(公告)日：1980-07-22
申请号：US45612
申请日：1979-06-05
CPC分类号： C03C3/072 , C03C3/064 , C03C3/068 , Y10S501/90 , Y10S501/901
摘要： A glass having a high refractive index, preferably >1.77, and a low specific gravity, preferable .ltoreq.3.8, is provided for utilization as spectacle lenses. The glass consists essentially of 80 mol percent or more of light cationic oxides with the remainder being cationic oxides having a greater molecular weight. It has a high crystallization stability in a viscosity range >200 poises and an expansion coefficient .alpha..times.10.sup.7 between 20.degree.-300.degree. C. of .ltoreq.100. Sufficiently light in weight to be well-suited for use as spectacle lenses, the glass can be continuously produced, as it has no pronounced tendency toward crystallization. The resulting corrective optical lenses have relatively high dioptric values, even with small center and edge thicknesses.
摘要翻译： 提供折射率高，优选> 1.77，低比重，优选 200泊的粘度范围和20°-300℃之间的膨胀系数α×107的<100％之间具有高结晶稳定性。 足够轻的重量非常适合用作眼镜镜片，可以连续生产玻璃，因为它没有显着的结晶倾向。 所得到的校正光学透镜具有相对高的屈光度值，即使具有小的中心和边缘厚度。
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公开(公告)号：US4149896A
公开(公告)日：1979-04-17
申请号：US920086
申请日：1978-06-28
申请人： Marga Faulstich , Georg Gliemeroth
发明人： Marga Faulstich , Georg Gliemeroth
摘要： Glasses are provided which may be made phototropic and which have a thermal coefficient of linear expansion between about 43 and 58.times.10.sup.-7 /.degree. C. and an index of refraction n.sub.d over about 1.60. Such glasses can be employed as near portion glass material in spectacle lens manufacture; thus, such glasses can be fused with known phototropic for portion glass material, for example, of the borosilicate type, to make multifocal glasses useful in spectacle lenses and spectacles.
摘要翻译： 提供了可以制成光变色并且具有在约43和58×10 -7 /℃之间的线性膨胀的热系数并且折射率nd大于约1.60的玻璃。 这种玻璃可以用作眼镜镜片制造中的近玻璃材料; 因此，这种玻璃可以与用于部分玻璃材料（例如，硼硅酸盐类型）的已知的光致变色物融合，以使多焦点眼镜可用于眼镜镜片和眼镜。
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公开(公告)号：US3999996A
公开(公告)日：1976-12-28
申请号：US680750
申请日：1976-04-27
申请人： Marga Faulstich , Georg Gliemeroth
发明人： Marga Faulstich , Georg Gliemeroth
CPC分类号： C03C4/06 , C03C3/074 , G02B5/23 , G02C7/06 , Y10S501/903
摘要： Glass as near-portion material for fusion with known phototropic far-portion glasses for multifocal spectacle lenses has a linear thermal expansion coefficient between 45 and 58 .times. 10.sup.-.sup.7 /.degree. C, a refractive index of n.sub.d .gtoreq.1.60, a speed of crystallization of less than 0.5 .mu./min., and the following composition:______________________________________ SiO.sub.2 10.0 - 20.0 % by weight B.sub.2 O.sub.3 15.0 - 23.0 % by weight PbO >26.0 - 30.0 % by weight ZnO 3.0 - 5.0 % by weight La.sub.2 O.sub.3 6.0 - 10.0 % by weight Al.sub.2 O.sub.3 12.0 - 17.0 % by weight ZrO.sub.2 0.5 - 3.0 % by weight TiO.sub.2 0.2 - 3.0 % by weight K.sub.2 O 0.1 - 2.0 % by weight Na.sub.2 O 0.1 - 2.0 % by weight Li.sub.2 O 0.1 - 4.0 % by weight ______________________________________ With the provision that:______________________________________ sum of SiO.sub.2 + B.sub.2 O.sub.3 is 30.0 - 40.0 % by weight sum of the alkali oxides is 0.2 - 3.0 % by weight sum of Al.sub.2 O.sub.3 + La.sub.2 O.sub.3 is 19.0 - 27.0 % by weight sum of the alkaline earth oxides is 3.0 - 8.0 % by weight, MgO being less than 5 % by weight and BaO being 3 - 8 % by weight sum of ZnO + ZrO.sub.2 + TiO.sub.2 is 3.0 - 6.0 % by weight sum of the oxides of Bi, Ta, Nb, W is 0 - 5.0 % by weight. ______________________________________
摘要翻译： 玻璃作为用于与多焦点眼镜片的已知光致变色远端眼镜融合的近部分材料具有45至58×10 -7 /℃之间的线性热膨胀系数，nd> / = 1.60的折射率，a 结晶速度小于0.5微米/分钟，组成如下：} SiO 2 10.0〜20.0重量％} B 2 O 3 15.0〜23.0重量％} PbO> 26.0〜30.0重量％} ZnO 3.0〜5.0重量％ } La 2 O 3 6.0〜10.0重量％} Al 2 O 3 12.0〜17.0重量％} ZrO 2 0.5〜3.0重量％·TiO 2 0.2〜3.0重量％·K 2 O 0.1〜2.0重量％·Na 2 O 0.1〜2.0重量％·Li 2 O 0.1〜4.0重量％}，其中：SiO 2 + B 2 O 3的重量比为30.0〜40.0重量％}碱金属氧化物的总量为0.2〜3.0重量％} Al 2 O 3 + La 2 O 3的和为19.0〜27.0质量％ 碱土金属氧化物的重量和总量为3.0〜8.0重量％，MgO}小于} 5重量％}，BaO}为3〜8重量％} ZnO + ZrO 2 + TiO 2的总和为3.0〜 6.0％（重量）} Bi，Ta，Nb，W的氧化物为0-5.0重量％。 }
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5.发明授权
公开(公告)号：US4225459A
公开(公告)日：1980-09-30
申请号：US897482
申请日：1978-04-18
申请人： Marga Faulstich , Walter Jahn , Georg Krolla , Norbert Neuroth
发明人： Marga Faulstich , Walter Jahn , Georg Krolla , Norbert Neuroth
CPC分类号： C03C4/0071 , C03C3/247 , Y10S501/903
摘要： Glass composition ranges are described which permit the introduction of laser activators into fluorphosphate glass with exceptionally high fluorine content while forming glasses of high crystallization stability and permitting the realization of large melt volumes. The high fluorine content imparts to the glasses an exceptionally low nonlinear refractive index n.sub.2 down to O,4 .times.10.sup.-13 esu.
摘要翻译： 描述了玻璃组成范围，其允许将激光活化剂引入具有非常高的氟含量的氟磷酸盐玻璃中，同时形成高结晶稳定性的玻璃并且允许实现大的熔体体积。 高氟含量赋予玻璃非常低的非线性折射率n2，降至O 4×10-13埃苏。
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公开(公告)号：US3970466A
公开(公告)日：1976-07-20
申请号：US597092
申请日：1975-07-18
申请人： Marga Faulstich
发明人： Marga Faulstich
CPC分类号： C03C3/068 , Y10S501/903
摘要： Optical glass, nd = 1.650 .+-. 2 .times. 10.sup..sup.-3 and vd = 55.5 .+-. 1.0, having a high chemical stability and a sufficiently low tendency toward crystallization that it can be manufactured in a continuous tank melting process into gobs, pressed components, and other formed articles as a mass-produced glass, said glass consisting essentially of, in percent by weight: SiO.sub.2 33.0 .+-. 0.5 B.sub.2 O.sub.3 11.6 .+-. 0.5 BaO 36.6 .+-. 1.0 La.sub.2 O.sub.3 14.0 .+-. 2.5 ZrO.sub.2 4.0 .+-. 2.5 As.sub.2 O.sub.3 0 - 0.5. or Sb.sub.2 O.sub.3
摘要翻译： 光学玻璃，nd = 1.650 +/- 2×10 -3，vd = 55.5 +/- 1.0，具有高化学稳定性和足够低的结晶倾向，可以在连续槽熔化过程中制成料滴 ，压制组分和其它成型制品作为批量生产的玻璃，所述玻璃基本上由以重量百分数组成：} SiO 2 33.0 +/- 0.5} B 2 O 3 11.6 +/- 0.5} BaO 36.6 +/- 1.0} La 2 O 3 14.0 +/- 2.5} ZrO 2 4.0 +/- 2.5} As 2 O 3} 0-0.5。 }或Sb2O3}
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7.发明授权Optical glass having n.sub.D =1.63.+-.(1.5.times.10.sup.-2), v.sub.D =59.5.+-.1.0 with a high chemical stability and a low tendency to crystallization 失效nD = 1.63 +/-（1.5×10 -2），vD = 59.5 +/- 1.0，具有高化学稳定性和低结晶倾向的光学玻璃
公开(公告)号：US4343908A
公开(公告)日：1982-08-10
申请号：US221110
申请日：1980-12-29
申请人： Marga Faulstich , Volmar Geiler
发明人： Marga Faulstich , Volmar Geiler
CPC分类号： C03C3/068 , Y10S501/903
摘要： An optical glass having n.sub.D =1.63.+-.(1.5.times.10.sup.-2), v.sub.D =59.5.+-.1.0, a high chemical stability and a low tendency to crystallization is provided, consisting essentially of (in percent. by weight):______________________________________ SiO.sub.2 23-27 B.sub.2 O.sub.3 24-30 SrO 18-31 La.sub.2 O.sub.3 10-16 Al.sub.2 O.sub.3 2-4 BaO 0-10 CaO 0-5 ZnO 0-6 Y.sub.2 O.sub.3 0-5 ZrO.sub.2 0-2 Li.sub.2 O, Na.sub.2 O and/or K.sub.2 O 0-1.5 As.sub.2 O.sub.3 and/or Sb.sub.2 O.sub.3 0-1 F and/or Cl 0-1, ______________________________________ wherein the sum of SiO.sub.2 +B.sub.2 O.sub.3 is 50-53, the weight ratio SiO.sub.2 :B.sub.2 O.sub.3 is 0.8-1.0, the sum SrO+BaO is 26-31, and the sum ZnO+La.sub.2 O.sub.3 is 12-17.
摘要翻译： 具有nD = 1.63 +/-（1.5×10 -2），v D = 59.5 +/- 1.0的光学玻璃，提供高的化学稳定性和低的结晶倾向，基本上由（以重量百分比计）： SiO 2 23-27 -B 2 O 3 24-30 -SrO 18-31 -La 2 O 3 10-16 -Al 2 O 3 2-4 -BaO 0-10 -CaO 0-5 -ZnO 0-6-Y 2 O 3 0-5 -ZrO 2 0-2 - Li 2 O，Na 2 O和/或K 2 O 0-1.5 -As 2 O 3和/或Sb 2 O 3 0-1 -F和/或Cl 0-1，其中SiO 2 + B 2 O 3的总和为50-53，SiO 2 :B 2 O 3的重量比为0.8 -1.0，SrO + BaO之和为26-31，ZnO + La2O3为12-17。
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公开(公告)号：US4099834A
公开(公告)日：1978-07-11
申请号：US527152
申请日：1974-11-25
CPC分类号： C03C3/07 , C03C13/046 , C03C3/102
摘要： A glass when in the form of an optical fiber having an optical loss of not more than 150 dB/km, high transparency, a high numerical aperture, and a high flexural strength, said glass being especially suitable for optical fibers and consisting essentially of:SiO.sub.2 : 65 - 75 mol-%; (38 - 46% by weight);R.sub.2 o: 4 - 17 mol-%; (4 - 13% by weight);PbO: 16 - 25 mol-%; (42 - 55% by weight); wherein R.sub.2 O is Na.sub.2 O, K.sub.2 O or Cs.sub.2 O or mixtures thereof, preferably not more than 3.0 mol % Na.sub.2 O, and with the provision that the molar ratio of SiO.sub.2 : PbO is 2.5 - 4.0.
摘要翻译： 玻璃当具有光损耗不超过150dB / km，高透明度，高数值孔径和高弯曲强度的光纤形式时，特别适用于光纤并且由以下组成：
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公开(公告)号：US4076647A
公开(公告)日：1978-02-28
申请号：US598137
申请日：1975-07-22
申请人： Marga Faulstich , Franz Reitmayer
发明人： Marga Faulstich , Franz Reitmayer
CPC分类号： C03C3/16 , Y10S501/903
摘要： An optical glass with a path length independent of temperature comprises between 40 and 55% by weight P.sub.2 O.sub.5, between 40 and 54% by weight BaO and between 6 and 12% by weight Nb.sub.2 O.sub.5. Part of the BaO may be replaced by SrO or CaO. Minor amounts of SiO.sub.2 or B.sub.2 O.sub.3 may be included as may other metal oxides such as ZnO, Sb.sub.2 O.sub.3 and La.sub.2 O.sub.3.
摘要翻译： 具有独立于温度的路径长度的光学玻璃包含40至55重量％的P 2 O 5，40至54重量％的BaO和6至12重量％的Nb 2 O 5。 BaO的一部分可以被SrO或CaO代替。 可以包括少量的SiO 2或B 2 O 3，如其它金属氧化物如ZnO，Sb 2 O 3和La 2 O 3。
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公开(公告)号：US4022707A
公开(公告)日：1977-05-10
申请号：US632848
申请日：1975-11-17
IPC分类号： C03C3/17 , C03C3/247 , C03C4/00 , H01S3/08 , H01S3/17 , C09K11/42 , C03C3/16 , C03C3/28 , C09K11/46
CPC分类号： C03C3/247 , C03C3/17 , C03C4/0071 , H01S3/17 , H01S3/08072
摘要： A neodymium-doped phosphate laser glass composition having a low threshold for stimulated emission, a negative temperature coefficient of refractive index, high acid resistence and homogeneity even in large structures comprises P.sub.2 O.sub.5, Na.sub.2 O or K.sub.2 O, Al.sub.2 O.sub.3, Nd.sub.2 O.sub.3, and optionally, F or RO, wherein R is Mg, Ba, Ca, Sr or Zn.
摘要翻译： 即使在大结构中，具有低激发激发阈值，负温度系数，高耐酸性和均匀性的钕掺杂磷酸盐激光玻璃组合物包括P 2 O 5，Na 2 O或K 2 O，Al 2 O 3，Nd 2 O 3和任选的F或RO 其中R是Mg，Ba，Ca，Sr或Zn。
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