公开(公告)号：US06388028B2

公开(公告)日：2002-05-14

申请号：US08878681

申请日：1997-06-19

申请人： Mario Sacchetti ,  Illaro Cuffiani ,  Gianni Pennini

发明人： Mario Sacchetti ,  Illaro Cuffiani ,  Gianni Pennini

IPC分类号： C08F464

CPC分类号： C08F10/00 ,  C08F4/6543

摘要： The present invention relates to spherical solid catalyst components for the polymerization of olefins, comprising a titanium compound, supported on a magnesium halide, containing more than one Ti-halogen link and optionally containing groups different from halogen in an amount lower than 0.5 mole per mole of Ti. Spherical solid compounds of the invention are characterized by having a surface area, measured by the BET method, of lower than 70 m2/g, a total porosity, measured by the mercurium method, higher than 0.5 cm3/g and a pore radius such that at least 50% have values higher than 800 Å.

摘要翻译： 本发明涉及用于烯烃聚合的球形固体催化剂组分，其包含负载在卤化镁上的钛化合物，其含有多于一个的Ti-卤素连接并且任选地含有少于0.5摩尔/摩尔量的不同于卤素的基团 的Ti。 本发明的球形固体化合物的特征在于具有通过BET法测量的表面积低于70m 2 / g，通过汞法测量的总孔隙率高于0.5cm 3 / g，孔半径使得 至少有50％的值高于800？

公开(公告)号：US5585317A

公开(公告)日：1996-12-17

申请号：US500032

申请日：1995-07-10

申请人： Mario Sacchetti ,  Gianni Pennini ,  Illaro Cuffiani

发明人： Mario Sacchetti ,  Gianni Pennini ,  Illaro Cuffiani

IPC分类号： C08F4/02 ,  C08F4/60 ,  C08F4/654 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  B01J31/00

CPC分类号： C08F10/00

摘要： The present invention relates to spherical solid components of catalysts for the polymerization of olefins comprising, supported on a magnesium dihalide in active form, a titanium compound containing at least one Ti-halogen bond and one OR group, said OR group being bonded to Ti in an amount such that the OR/Ti molar ratio is greater than or equal to 0.5; optionally the component also comprises an electron donor compound. The spherical solid components of the invention are characterized by having a porosity comprised between 0.35 and 0.7 cm.sup.3 /g and by a pore size distribution such that at least 50% of the porosity is due to pores having an average radius greater than 800 .ANG..

摘要翻译： 本发明涉及用于烯烃聚合的催化剂的球形固体组分，其包括负载在活性形式的二卤化镁上，含有至少一个Ti-卤素键的钛化合物和一个OR基团，所述OR基团与Ti键合 使OR / Ti摩尔比大于或等于0.5的量; 任选地，组分还包含电子给体化合物。 本发明的球形固体组分的特征在于具有0.35-0.7cm 3 / g的孔隙率和孔径分布，使得至少50％的孔隙率是由于平均半径大于800的孔。

公开(公告)号：US5578541A

公开(公告)日：1996-11-26

申请号：US10750

申请日：1993-01-29

申请人： Mario Sacchetti ,  Illaro Cuffiani ,  Gianni Pennini

发明人： Mario Sacchetti ,  Illaro Cuffiani ,  Gianni Pennini

IPC分类号： C08F2/00 ,  C08F2/34 ,  C08F4/60 ,  C08F4/654 ,  C08F4/658 ,  C08F10/00 ,  C08F10/02 ,  B01J31/00

CPC分类号： C08F10/00

摘要： The present invention relates to spherical solid components of catalysts for the polymerization of olefins comprising, supported on a magnesium dihalide in active form, a titanium compound containing at least one Ti-halogen bond, and optionally an electron donor compound. The spherical solid components of the invention are characterized by porosity values higher than 1 cm.sup.3 /g and a pore size distribution such that at least 30% of their pores have an average radius greater than 10000 .ANG..

摘要翻译： 本发明涉及用于烯烃聚合的催化剂的球形固体组分，其包含负载在活性形式的二卤化镁上，含有至少一个Ti-卤素键的钛化合物和任选的电子给体化合物。 本发明的球形固体组分的特征在于高于1cm 3 / g的孔隙度值和孔径分布，使得其孔的至少30％的平均半径大于10000Ag。

公开(公告)号：US5726261A

公开(公告)日：1998-03-10

申请号：US712425

申请日：1996-09-11

申请人： Mario Sacchetti ,  Gianni Pennini ,  Illaro Cuffiani

发明人： Mario Sacchetti ,  Gianni Pennini ,  Illaro Cuffiani

IPC分类号： C08F4/02 ,  C08F4/60 ,  C08F4/654 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16

CPC分类号： C08F10/00

摘要： The present invention relates to spherical solid components of catalysts for the polymerization of olefins comprising, supported on a magnesium dihalide in active form, a titanium compound containing at least one Ti-halogen bond and one OR group, said OR group being bonded to Ti in an amount such that the OR/Ti molar ratio is greater than or equal to 0.5; optionally the component also comprises an electron donor compound. The spherical solid components of the invention are characterized by having a porosity comprised between 0.35 and 0.7 cm.sup.3 /g and by a pore size distribution such that at least 50% of the porosity is due to pores having an average radius greater than 800 .ANG..

公开(公告)号：US4305840A

公开(公告)日：1981-12-15

申请号：US88162

申请日：1979-10-25

申请人： Umberto Zucchini ,  Gianni Pennini ,  Illaro Cuffiani

发明人： Umberto Zucchini ,  Gianni Pennini ,  Illaro Cuffiani

IPC分类号： C08F4/00 ,  C08F4/02 ,  C08F4/60 ,  C08F4/62 ,  C08F10/00 ,  C08F4/64

CPC分类号： C08F10/00 ,  C08F4/022

摘要： There are disclosed new catalyst-forming components and catalysts prepared therefrom which, used in the polymerization of olefins, result in high yields of polyolefins having a narrow molecular weight distribution and which do not require special purifying after-treatments for the removal of catalyst residues. More particularly, the new catalyst components and catalysts prepared from them are useful in the polymerization of ethylene or alpha-olefins CH.sub.2 .dbd.CHR, in which R is an alkyl or aryl radical of from 1 to 8 carbon atoms, or mixtures of ethylene with said alpha-olefins.

摘要翻译： 公开了新的催化剂形成组分和由其制备的催化剂，其用于烯烃聚合中，导致具有窄分子量分布的高产率聚烯烃，并且不需要特殊的净化后处理以除去催化剂残余物。 更具体地说，由它们制备的新催化剂组分和催化剂可用于乙烯或α-烯烃CH 2 = CHR的聚合，其中R是具有1至8个碳原子的烷基或芳基，或乙烯与所述 α-烯烃。

公开(公告)号：US4517307A

公开(公告)日：1985-05-14

申请号：US452152

申请日：1982-12-22

申请人： Illaro Cuffiani ,  Paolo Longi ,  Umberto Zucchini ,  Gianni Pennini

发明人： Illaro Cuffiani ,  Paolo Longi ,  Umberto Zucchini ,  Gianni Pennini

IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/651 ,  C08F4/654 ,  C08F4/658 ,  C08F10/00 ,  C08F10/02 ,  C08F4/64 ,  C08F4/68

CPC分类号： C08F10/02 ,  Y10S526/903 ,  Y10S526/904 ,  Y10S526/909

摘要： Components of catalysts for the polymerization of ethylene and of mixtures thereof with other olefins, in the form of emulsions or dispersions, in an inert liquid medium or in an inert gas phase of a liquid phase, comprising a compound of a metal of Groups IV to VI inclusive, of the Mendelyeev Periodic System, or a composition containing such a compound of the Mendelyeev Periodic System, which compound or composition is immiscible with aliphatic hydrocarbons, or which components are obtained from emulsions or dispersions, in an inert liquid medium or in gas phase, of a precursor of the catalyst component which, in the liquid state, is immiscible with the aliphatic hydrocarbons.An object of this invention is to provide new catalyst components for use in the polymerization of ethylene and of mixtures thereof with olefins and the catalysts obtained therefrom.More particularly, the invention provides new liquid catalytic components used in emulsion or dispersion in an inert liquid medium and the use of the catalysts deriving therefrom in the polymerization of ethylene and of mixtures thereof with alpha-olefins and/or with polyenes containing at least two double bonds.

摘要翻译： 用于乙烯聚合的催化剂及其与惰性液体介质或惰性气相中的乳液或分散体形式的其它烯烃的混合物的组分，其包含第IV族至第 VI，包括Mendelyeev定期系统的组合物，或含有这种化合物或组合物与脂肪烃不混溶的这种化合物的组合物，或哪些组分由乳液或分散体在惰性液体介质或气体中获得 在液态下与脂族烃不混溶的催化剂组分的前体相。 本发明的目的是提供用于乙烯及其与烯烃的混合物的聚合的新催化剂组分和由其获得的催化剂。 更具体地说，本发明提供了用于惰性液体介质中的乳液或分散体中的新的液体催化组分，以及由其衍生的催化剂在乙烯聚合中的用途及其与α-烯烃和/或与含有至少两个 双重债券。

公开(公告)号：US06300273B1

公开(公告)日：2001-10-09

申请号：US08873580

申请日：1997-06-12

申请人： Mario Sacchetti ,  Illaro Cuffiani

发明人： Mario Sacchetti ,  Illaro Cuffiani

IPC分类号： B01J3102

CPC分类号： C08F10/00 ,  C08F4/6494

摘要： The present invention relates to catalysts for the polymerization of ethylene and its mixtures with olefins CH2═CHRVIII, comprising the reaction product of a solid catalyst component containing Ti, Mg and halogen, an alkyl-Al compound and a particular electron donor compound selected from the compounds containing at least two oxygen atoms bonded to different carbon atoms and selected by standard tests of reactivity with triethyl-Al and MgCl2 compounds. The catalyst of the invention are used in processes for the (co)polymerization of ethylene to prepare (co)polymers having narrow molecular weight distribution (MWD).

摘要翻译： 本发明涉及用于聚合乙烯及其与烯烃CH 2 = CHRVIII的混合物的催化剂，其包含含有Ti，Mg和卤素的固体催化剂组分，烷基-Al化合物和特定的电子给体化合物的反应产物，其选自 含有至少两个键合到不同碳原子上的氧原子的化合物，并通过与三乙基-Al和MgCl 2化合物的反应性的标准试验选择。 本发明的催化剂用于（共）聚合乙烯以制备具有窄分子量分布（MWD）的（共）聚合物的方法。

公开(公告)号：US5219961A

公开(公告)日：1993-06-15

申请号：US808080

申请日：1991-12-11

申请人： Umberto Zucchini ,  Viviano Banzi ,  Illaro Cuffiani

发明人： Umberto Zucchini ,  Viviano Banzi ,  Illaro Cuffiani

IPC分类号： C08F10/00

CPC分类号： C08F10/00

摘要： Catalytic components for copolymerizing ethylene with alpha-olefins, or alpha-olefins with one another, and possibly with a diene as a termonomer, suitable for producing saturated and unsaturated elastomeric copolymers are disclosed. The catalytic components are compounds obtained by the reaction of:(1) a magnesium compound having the formula:R'.sub.y MgX.sub.n (OR).sub.2-n (wherein R, R'=alkyl, cycloalkyl, aryl; X=Cl, Br; n is from 0 to 1.8, y is from 0 to 1, and n+y=2), or(2) a Mg-alcohol adduct;with a titanium compound having the formula:Ti(OR).sub.Z X.sub.4-Z'wherein X and R are as defined above and Z is from 0 to 1, the compounds being charcterized by a Mg/Ti ratio of from 0.5 to 50 and an OR/Ti ratio of from 0.7 to 10. The copolymers produced using these catalytic components are endowed with improved tension-set characteristics in the vulcanized state.

摘要翻译： 公开了用于使乙烯与α-烯烃或彼此之间的α-烯烃共聚的催化组分，以及可能用作产生饱和和不饱和弹性体共聚物的二烯作为单体的二烯烃。 催化组分是通过以下反应获得的化合物：（1）具有下式的镁化合物：R'yMgXn（OR）2-n（其中R，R'=烷基，环烷基，芳基; X = Cl，Br; n 为0〜1.8，y为0〜1，n + y = 2），（2）Mg-醇加成物; 与具有下式的钛化合物：Ti（OR）ZX4-Z'，其中X和R如上定义，Z为0至1，该化合物被Mg / Ti比为0.5至50表示，OR / Ti比为0.7〜10。使用这些催化剂组分制备的共聚物在硫化状态下具有改进的张力设定特性。

公开(公告)号：US5084540A

公开(公告)日：1992-01-28

申请号：US616767

申请日：1990-11-20

申请人： Enrico Albizzati ,  Umberto Zucchini ,  Arrigo Soverini ,  Illaro Cuffiani

发明人： Enrico Albizzati ,  Umberto Zucchini ,  Arrigo Soverini ,  Illaro Cuffiani

IPC分类号： C08F2/00 ,  C08F2/34 ,  C08F4/00 ,  C08F4/60 ,  C08F10/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/16

CPC分类号： C08F210/16

摘要： Crystalline copolymers of ethylene and alpha-olefins CH.sub.2 .dbd.CHR in which R is an alkyl group having 2 to 8 carbon atoms, containing 0.5 to 3% by moles of polymerized alpha-olefin and having a density lower than 0.945 g/cc are obtained by polymerizing, in the gas phase, mixtures of ethylene and the alpha-olefins in contact with catalysts prepared from (1) Ti compounds supported on Mg halides and (2) organometallic compounds, which are active in the polymerization of ethylene but exhibit little, if any, activity in the homo- or copolymerization of the alpha-olefins.

摘要翻译： 乙烯和α-烯烃CH 2 = CHR的结晶共聚物，其中R为具有2-8个碳原子的烷基，含有0.5-3％（摩尔）聚合的α-烯烃，密度低于0.945g / cc，通过 在气相中聚合乙烯和α-烯烃的混合物与由（1）负载在卤化镁上的Ti化合物和（2）有机金属化合物制备的催化剂接触，所述有机金属化合物在乙烯的聚合中是有活性的，但是如果 任何在α-烯烃的均聚或共聚中的活性。

公开(公告)号：US4390454A

公开(公告)日：1983-06-28

申请号：US285961

申请日：1981-07-23

申请人： Illaro Cuffiani ,  Paolo Galli ,  Umberto Zucchini

发明人： Illaro Cuffiani ,  Paolo Galli ,  Umberto Zucchini

IPC分类号： C08F4/64 ,  C12N9/18 ,  C12P33/00 ,  C12R1/025

CPC分类号： C12R1/025 ,  C12N9/18 ,  Y10S435/824

摘要： There are disclosed components of catalysts for polymerizing ethylene and mixtures of ethylene with alpha-olefins comprising the reaction product of (A) a magnesium compound, such as Mg-chloride, Mg-alcoholate or a Grignard compound, with (B) a titanium, vanadium or zirconium compound having at least two metal-oxygen bonds, such as a tetra-alcoholate, and with (C) a halogenated compound of metals of B, such as Ti tetrachloride.According to an aspect of the invention, the reaction product (A)+(B), before being reacted with (C), is treated with a silicum compound having a halogenating and/or reducing action.The catalysts according to the invention are suitable for obtaining ethylene polymers having a broad distribution of molecular weights.

摘要翻译： 公开了用于聚合乙烯的催化剂的组分和乙烯与α-烯烃的混合物的组分，其包括（A）镁化合物如Mg-氯化物，Mg-醇化物或格氏化合物与（B）钛的反应产物， 具有至少两个金属 - 氧键的钒或锆化合物，例如四醇化物，和（C）B的金属卤化化合物如四氯化钛。 根据本发明的一个方面，在与（C）反应之前，将反应产物（A）+（B）用具有卤化和/或还原作用的硅酸盐化合物处理。 根据本发明的催化剂适用于获得分子量分布广泛的乙烯聚合物。