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1.发明授权
公开(公告)号：US5024984A
公开(公告)日：1991-06-18
申请号：US382479
申请日：1989-07-19
申请人： Mark P. Kaminsky , Mark S. Kleefisch , George A. Huff , Don M. Washecheck , Aileen E. Alvarado-Swaisgood , Mark K. Barr
发明人： Mark P. Kaminsky , Mark S. Kleefisch , George A. Huff , Don M. Washecheck , Aileen E. Alvarado-Swaisgood , Mark K. Barr
CPC分类号： B01J23/14 , C07C2/84 , C07C2523/02 , C07C2523/10 , C07C2523/14
摘要： An oxidative coupling catalyst composition for converting methane to a higher hydrocarbon comprising a mixed oxide of: a) a Group IIIB metal selected from the group consisting of yttrium, scandium and lanthanum; b) a Group IIA metal selected from the group consisting of barium, calcium and strontium; and c) a Group IVA metal selected from the group consisting of tin, lead and germanium and wherein the cationic species are present in the approximate ratio of 1:0.5-3:2-4, respectively, and an improved process employing same.
摘要翻译： 一种用于将甲烷转化为高级烃的氧化偶联催化剂组合物，其包含以下混合氧化物：a）选自钇，钪和镧的IIIB族金属; b）选自钡，钙和锶的IIA族金属; 和c）选自锡，铅和锗的IVA族金属，并且其中阳离子种类分别以1:0.5-3:2-4的大致比例存在，以及使用其的改进方法。
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2.发明授权
公开(公告)号：US4939311A
公开(公告)日：1990-07-03
申请号：US233063
申请日：1988-08-17
申请人： Don M. Washecheck , Aileen E. Alvarado-Swaisgood , Mark P. Kaminsky , Mark S. Kleefisch , George A. Huff, Jr.
发明人： Don M. Washecheck , Aileen E. Alvarado-Swaisgood , Mark P. Kaminsky , Mark S. Kleefisch , George A. Huff, Jr.
CPC分类号： B01J23/14 , C07C2/84 , C07C2523/02 , C07C2523/10 , C07C2523/14 , Y10S585/934
摘要： An oxidative coupling catalyst composition for converting methane to a higher hydrocarbon comprising a mixed oxide of: (a) a Group IIIB metal selected from the grouup consisting of yttrium, scandium and lanthanum; (b) a Group IIA metal selected from the group consisting of barium, calcium and strontium; and (c) a Group IVA metal selected from the group consisting of tin, lead and germanium and approximate ratio of 1:0.5-3:2-4, and an improved process employing same.
摘要翻译： 一种用于将甲烷转化为高级烃的氧化偶联催化剂组合物，其包含以下混合氧化物：（a）选自由钇，钪和镧组成的组的IIIB族金属; （b）选自钡，钙和锶的IIA族金属; 和（c）选自锡，铅和锗的ⅣA族金属和近似比例为1:0.5-3:2-4，以及使用其的改进方法。
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公开(公告)号：US5316995A
公开(公告)日：1994-05-31
申请号：US32666
申请日：1993-03-17
IPC分类号： C07C2/84 , B01J27/06 , B01J27/08 , B01J27/125 , B01J27/138
CPC分类号： C07C2/84 , C07C2523/02 , C07C2523/10 , C07C2523/14 , C07C2527/138 , Y10S585/943
摘要： A contact material composition of an intimately mixed halogen-containing mixed oxide of at least one cationic species of a naturally occurring Group IIIB element, at least one cationic species of a Group IIA metal of magnesium, calcium, strontium and barium and at least one cationic species of germanium and gallium, as well as methods for hydrocarbon conversion using such contact material compositions are provided.
摘要翻译： 天然存在的IIIB族元素的至少一种阳离子物质的至少一种阳离子种类，镁，钙，锶和钡的IIA族金属的至少一种阳离子物质和至少一种阳离子 提供锗和镓的种类，以及使用这种接触材料组合物的烃转化方法。
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公开(公告)号：US5245109A
公开(公告)日：1993-09-14
申请号：US775226
申请日：1991-10-11
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2523/02 , C07C2523/10 , C07C2523/14 , C07C2527/138 , Y10S585/943
摘要： A contact material composition of an intimately mixed halogencontaining mixed oxide of at least one cationic species of a naturally occurring Group IIIB element, at least one cationic species of a Group IIA metal of magnesium, calcium, strontium and barium and at least one cationic species of germanium and gallium, as well as methods for hydrocarbon conversion using such contact material compositions are provided.
摘要翻译： 天然存在的IIIB族元素的至少一种阳离子种类的至少一种阳离子物质，镁，钙，锶和钡的IIA族金属的至少一种阳离子物质和至少一种阳离子种类的接触材料组合物 锗和镓，以及使用这种接触材料组合物的烃转化方法。
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公开(公告)号：US5328883A
公开(公告)日：1994-07-12
申请号：US13574
申请日：1993-02-04
申请人： Don M. Washecheck , Mark K. Barr , George A. Huff, Jr. , Mark P. Kaminsky , Mark S. Kleefisch , Victor K. Shum
发明人： Don M. Washecheck , Mark K. Barr , George A. Huff, Jr. , Mark P. Kaminsky , Mark S. Kleefisch , Victor K. Shum
CPC分类号： C07C2/84 , C07C2521/02 , Y10S585/943
摘要： A contact material composition containing an intimately mixed, mixed oxide of at least one cationic species of a naturally occurring Group IIIB element, at least one cationic species of a Group IIA metal of magnesium, calcium, strontium, and barium and a cationic species of aluminum, as well as methods for hydrocarbon conversion using such contact material compositions are provided.
摘要翻译： 包含天然存在的IIIB族元素的至少一种阳离子物质，镁，钙，锶和钡的IIA族金属的至少一种阳离子物质和阳离子物质的铝的接触材料组合物 ，以及使用这种接触材料组合物的烃转化方法。
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公开(公告)号：US5312795A
公开(公告)日：1994-05-17
申请号：US975280
申请日：1992-11-12
CPC分类号： B01J23/10 , C07C2/00 , C07C2/84 , C07C2521/06 , C07C2521/10 , C07C2523/02 , C07C2523/10 , Y10S585/943
摘要： A contact material composition containing an intimately mixed, mixed oxide of at least one cationic species of a naturally occurring Group IIIB element, at least one cationic species of a Group IIA metal of magnesium, calcium, strontium, and barium and at least one additional metal cationic species of zirconium and hafnium, as well as methods for hydrocarbon conversion using such contact material compositions are provided.
摘要翻译： 一种接触材料组合物，其含有天然存在的IIIB族元素的至少一种阳离子物质，镁，钙，锶和钡的IIA族金属的至少一种阳离子物质和至少一种另外的金属 提供了锆和铪的阳离子种类，以及使用这种接触材料组合物的烃转化方法。
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公开(公告)号：US5198596A
公开(公告)日：1993-03-30
申请号：US775227
申请日：1991-10-11
CPC分类号： B01J23/10 , C07C2/00 , C07C2/84 , C07C2521/06 , C07C2521/10 , C07C2523/02 , C07C2523/10 , Y10S585/943
摘要： A contact material composition containing an intimately mixed, mixed oxide of at least one cationic species of a naturally occurring Group 111B elment, at least one cationic species of a Group IIA metal of magnesium, calcium, strontium, and barium and at least one additional metal cationic species of zirconium and hafnium, as well as methods for hydrocarbon conversion using such contact material compositions are provided.
摘要翻译： 一种接触材料组合物，其包含至少一种阳离子种类的天然存在的第111B族组分的至少一种阳离子物质，镁，钙，锶和钡的IIA族金属的至少一种阳离子物质和至少一种另外的金属 提供了锆和铪的阳离子种类，以及使用这种接触材料组合物的烃转化方法。
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公开(公告)号：US5196634A
公开(公告)日：1993-03-23
申请号：US775209
申请日：1991-10-11
申请人： Don M. Washecheck , Mark K. Barr , George A. Huff, Jr. , Mark P. Kaminsky , Mark S. Kleefisch , Victor K. Shum
发明人： Don M. Washecheck , Mark K. Barr , George A. Huff, Jr. , Mark P. Kaminsky , Mark S. Kleefisch , Victor K. Shum
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2521/02 , Y10S585/943
摘要： A contact material composition containing an intimately mixed, mixed oxide of at least one cationic species of a naturally occurring Group IIIB element, at least one cationic species of a Group IIA metal of magnesium, calcium, strontium, and barium and a cationic species of aluminum, as well as methods for hydrocarbon conversion using such contact material compositions are provided.
摘要翻译： 包含天然存在的IIIB族元素的至少一种阳离子物质，镁，钙，锶和钡的IIA族金属的至少一种阳离子物质和阳离子物质的铝的接触材料组合物 ，以及使用这种接触材料组合物的烃转化方法。
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公开(公告)号：US4971940A
公开(公告)日：1990-11-20
申请号：US382477
申请日：1989-07-19
CPC分类号： B01J23/14 , C07C2/84 , C07C2523/02 , C07C2523/10 , C07C2523/14
摘要： A tin-containing composition is provided, the composition having a tin Auger line transition wherein the ratio of the area of the M.sub.5 N.sub.4,5 N.sub.4,5 transition peak at 424.5 eV.+-.leV, having a 6 eV FWHM, to the area of M.sub.4 N.sub.4,5 N.sub.4,5 transition peak at 430.5 eV.+-.1eV is at least 10 to 1. Additional such tin-containing compositions, including catalyst compositions are also provided as are methods for converting feedstock alkanes containing from 1 to 4 carbon atoms to higher molecular weight hydrocarbons using such catalyst compositions.
摘要翻译： 提供含锡组合物，该组合物具有锡俄歇线转变，其中具有6eV FWHM的424.5eV +/- leV的M5N4,5N4,5转变峰的面积与M4N4的面积的比率， 在430.5eV +/- 1eV下的5N4.5转变峰至少为10:1。还提供了另外的这种含锡组合物，包括催化剂组合物，如将含有1至4个碳原子的原料烷烃转化为较高分子量烃的方法 使用这种催化剂组合物。
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公开(公告)号：US5059740A
公开(公告)日：1991-10-22
申请号：US555768
申请日：1990-06-25
CPC分类号： B01J23/14 , C07C2/84 , C07C2523/02 , C07C2523/10 , C07C2523/14 , Y10S585/934
摘要： A tin-containing composition is provided, the composition having a tin Auger line transition wherein the ratio of the area of the M.sub.5 N.sub.4,5 N.sub.4,5 transition peak at 424.5 eV.+-.1 eV, having a 6 eV FWHM, to the area of M.sub.4 N.sub.4,5 N.sub.4,5 transition peak at 430.5 eV.+-.1 eV is at least 10 to 1. Additional such tin-containing compositions, including catalyst compositions are also provided as are methods for converting feedstock alkanes containing from 1 to 4 carbon atoms to higher molecular weight hydrocarbons using such catalyst compositions.
摘要翻译： 提供含锡组合物，组合物具有锡俄歇线转变，其中具有6eV FWHM的具有6eV FWHM的M5N4,5N4,5转变峰的面积与M4N4的面积的比值为424.5eV +/- 1eV 在430.5eV +/- 1eV下的5N4.5转变峰为至少10:1。还提供另外的这种含锡组合物，包括催化剂组合物，其方法是将含有1至4个碳原子的原料烷烃转化为更高分子量 使用这种催化剂组合物的重量烃。
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