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1.发明授权
公开(公告)号：US5024984A
公开(公告)日：1991-06-18
申请号：US382479
申请日：1989-07-19
申请人： Mark P. Kaminsky , Mark S. Kleefisch , George A. Huff , Don M. Washecheck , Aileen E. Alvarado-Swaisgood , Mark K. Barr
发明人： Mark P. Kaminsky , Mark S. Kleefisch , George A. Huff , Don M. Washecheck , Aileen E. Alvarado-Swaisgood , Mark K. Barr
CPC分类号： B01J23/14 , C07C2/84 , C07C2523/02 , C07C2523/10 , C07C2523/14
摘要： An oxidative coupling catalyst composition for converting methane to a higher hydrocarbon comprising a mixed oxide of: a) a Group IIIB metal selected from the group consisting of yttrium, scandium and lanthanum; b) a Group IIA metal selected from the group consisting of barium, calcium and strontium; and c) a Group IVA metal selected from the group consisting of tin, lead and germanium and wherein the cationic species are present in the approximate ratio of 1:0.5-3:2-4, respectively, and an improved process employing same.
摘要翻译： 一种用于将甲烷转化为高级烃的氧化偶联催化剂组合物，其包含以下混合氧化物：a）选自钇，钪和镧的IIIB族金属; b）选自钡，钙和锶的IIA族金属; 和c）选自锡，铅和锗的IVA族金属，并且其中阳离子种类分别以1:0.5-3:2-4的大致比例存在，以及使用其的改进方法。
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公开(公告)号：US5687565A
公开(公告)日：1997-11-18
申请号：US564479
申请日：1995-11-29
申请人： Frank S. Modica , Mark K. Barr , George A. Huff , Roger H. Cayton , Bruce D. Alexander , Richard A. Kretchmer
发明人： Frank S. Modica , Mark K. Barr , George A. Huff , Roger H. Cayton , Bruce D. Alexander , Richard A. Kretchmer
CPC分类号： F01N3/085 , B01D53/9472 , B01D53/9486 , F01N13/009 , F01N3/02 , F01N3/0205 , F01N3/0814 , F01N3/0835 , F01N3/0871 , F01N3/2006 , F01N3/2889 , B01D2251/102 , B01D2255/102 , B01D2255/207 , B01D53/945 , F01N2240/02 , F01N2250/12 , F02B1/04 , Y02T10/22 , Y02T10/26
摘要： Exhaust gas emissions from an internal combustion engine are controlled through the use of a heat exchanger, a sulfur oxide absorbent, and a catalytic converter. The exhaust gas is contacted with the sulfur oxide absorbent before it is passed to the catalytic converter, and the heat exchanger is used to extract heat from the exhaust gas before the exhaust gas is contacted with the sulfur oxide absorbent. The heat extracted from the exhaust gas by the heat exchanger is then used to heat the catalytic converter. In a preferred embodiment, the exhaust gas is also contacted with a hydrocarbon adsorbent which: (1) adsorbs organic compounds, such as hydrocarbons, from the exhaust gas at the low temperatures which are typical of an engine cold-start, and (2) desorbs them at the higher temperatures which are reached after sustained engine operation.
摘要翻译： 通过使用热交换器，硫氧化物吸收剂和催化转化器来控制来自内燃机的废气排放。 废气在通过催化转化器之前与硫氧化物吸收剂接触，并且在废气与硫氧化物吸收剂接触之前，使用热交换器从废气中提取热量。 然后通过热交换器从排气中提取的热量用于加热催化转化器。 在优选的实施方案中，废气还与烃吸附剂接触，该烃吸附剂：（1）在发动机冷启动的典型的低温下从排气中吸附有机化合物，例如烃，和（2） 在持续发动机运行后达到的较高温度下解吸它们。
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公开(公告)号：US5916129A
公开(公告)日：1999-06-29
申请号：US890057
申请日：1997-07-09
申请人： Frank S. Modica , Mark K. Barr , George A. Huff , Roger H. Cayton , Bruce D. Alexander , Richard A. Kretchmer
发明人： Frank S. Modica , Mark K. Barr , George A. Huff , Roger H. Cayton , Bruce D. Alexander , Richard A. Kretchmer
CPC分类号： F01N3/085 , B01D53/9472 , B01D53/9486 , F01N13/009 , F01N3/02 , F01N3/0205 , F01N3/0814 , F01N3/0835 , F01N3/0871 , F01N3/2006 , F01N3/2889 , B01D2251/102 , B01D2255/102 , B01D2255/207 , B01D53/945 , F01N2240/02 , F01N2250/12 , F02B1/04 , Y02T10/22 , Y02T10/26
摘要： Exhaust gas emissions from an internal combustion engine are controlled through the use of a heat exchanger, a sulfur oxide absorbent, and two catalytic converter zones. The exhaust gas is passed sequentially through: (1) a first catalytic converter zone, (2) the sulfur oxide absorbent, and (3) a second catalytic converter zone. The heat exchanger is used to transfer heat from the first catalytic converter zone to the second catalytic converter zone.
摘要翻译： 通过使用热交换器，硫氧化物吸收剂和两个催化转化器区域来控制来自内燃机的废气排放。 废气依次通过：（1）第一催化转化器区，（2）硫氧化物吸收剂，和（3）第二催化转化器区。 热交换器用于将热量从第一催化转化器区传递到第二催化转化器区。
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公开(公告)号：US20080200696A1
公开(公告)日：2008-08-21
申请号：US11428851
申请日：2006-07-06
申请人： Jeffrey T. Miller , Bo Chen , Craig W. Colling , George A. Huff , Brian Henley , William John Koros , Raymond W. Chafin
发明人： Jeffrey T. Miller , Bo Chen , Craig W. Colling , George A. Huff , Brian Henley , William John Koros , Raymond W. Chafin
IPC分类号： C07D209/38
CPC分类号： C10G31/11 , B01D71/021
摘要： Processes are disclosed for production of value-added products from fluid admixtures of hydrocarbon compounds at least one of which is an aromatic hydrocarbon compound, by means of one or more devices using perm-selective polymeric membranes. More particularly, processes of the invention comprise separations using aromatic-selective polymeric materials comprising long-chain polymeric molecules in which recurring amide and imide linkages are part of the main polymer chain. Processes of the invention advantageously employ aromatic-selective membranes to separate an aromatic enriched stream from gaseous and/or liquid mixtures comprising one or more aromatic hydrocarbon compounds thereby producing a stream comprising the remaining compounds which may include alkenes and/or alkanes containing 3 or more carbon atoms, and/or alicyclic hydrocarbons. Processes of the invention are particularly useful for recovery of meta-xylene and para-xylene products from liquid mixtures even containing ethylbenzene as well as the three xylene isomers.
摘要翻译： 公开了用于通过使用烫发选择性聚合物膜的一种或多种装置从其中至少一种为芳族烃化合物的烃化合物的流体混合物生产增值产品的方法。 更具体地，本发明的方法包括使用包含长链聚合物分子的芳族选择性聚合物材料的分离，其中重复酰胺和酰亚胺键是主要聚合物链的一部分。 本发明的方法有利地采用芳香族选择性膜从包含一种或多种芳族烃化合物的气体和/或液体混合物中分离富含芳烃的物流，从而产生包含剩余化合物的物流，其可包括含有3个或更多个的烯烃和/或烷烃 碳原子和/或脂环烃。 本发明的方法特别可用于从含有乙苯的液体混合物以及三种二甲苯异构体中回收间二甲苯和对二甲苯产物。
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公开(公告)号：US6059962A
公开(公告)日：2000-05-09
申请号：US150451
申请日：1998-09-09
CPC分类号： C10G29/205
摘要： A product of reduced sulfur content is produced in a multiple stage process from a feedstock which is comprised of a mixture of hydrocarbons and includes sulfur-containing aromatic compounds as unwanted impurities. The first stage involves: (1) subjecting the feedstock to alkylation conditions which are effective to convert a portion of the impurities to higher boiling sulfur-containing products, and (2) separating the resulting products by fractional distillation into a lower boiling fraction and a higher boiling fraction. The lower boiling fraction is comprised of hydrocarbons and is of reduced sulfur content relative to the feedstock. The higher boiling fraction is comprised of hydrocarbons and contains unconverted sulfur-containing aromatic impurities and also the higher boiling sulfur-containing products. Each subsequent stage involves: (1) subjecting the higher boiling fraction from the preceding stage to alkylation conditions which are effective to convert at least a portion of its content of sulfur-containing aromatic compounds to higher boiling sulfur-containing products, and (2) separating the resulting products by fractional distillation into a lower boiling hydrocarbon fraction and a higher boiling fraction which contains higher boiling sulfur-containing alkylation products. The total hydrocarbon product of reduced sulfur content from the process is comprised of the lower boiling fractions from various stages.
摘要翻译： 减少硫含量的产物在多级工艺中由来自烃的混合物的原料产生，并且包括作为不需要的杂质的含硫芳族化合物。 第一阶段包括：（1）使原料经受有效将一部分杂质转化成高沸点含硫产物的烷基化条件，和（2）通过分馏将所得产物分离成较低沸点馏分和 较高的沸点。 低沸点馏分由烃组成，相对于原料硫含量降低。 较高沸点馏分由烃组成，含有未转化的含硫芳族杂质和较高沸点含硫产物。 每个后续阶段包括：（1）将来自前一阶段的较高沸点馏分经受烷基化条件，这些条件有效地将其含硫芳香族化合物的至少一部分转化成高沸点含硫产物，和（2） 通过分馏将所得产物分离成低沸点烃馏分和含较高沸点含硫烷基化产物的较高沸点馏分。 来自该方法的硫含量降低的总烃产物由来自不同阶段的低沸点馏分组成。
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公开(公告)号：US08211319B2
公开(公告)日：2012-07-03
申请号：US10663918
申请日：2003-09-16
CPC分类号： B01D9/00 , B01D17/048 , B01D29/114 , B01D29/52 , B01D2201/202 , C07C7/00
摘要： A process for separating solids from liquids in a filtration zone defined by a higher concentration zone and a lower concentration zone separated by a filter. The process includes the steps of directing a slurry feed comprising a liquid and solids into the higher concentration zone, directing a displacement fluid to the higher concentration zone and passing at least a portion of the liquid through a filter to the filtrate zone, producing a filtrate.
摘要翻译： 在由过滤器分离的较高浓度区域和较低浓度区限定的过滤区域中分离固体与液体的方法。 该方法包括以下步骤：将包含液体和固体的浆料进料引导到较高浓度区域，将置换流体引导到较高浓度区域并使至少一部分液体通过过滤器至滤液区域，产生滤液 。
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公开(公告)号：US06602405B2
公开(公告)日：2003-08-05
申请号：US09489371
申请日：2000-01-21
IPC分类号： C10G4502
CPC分类号： C10G69/12
摘要： A product of reduced sulfur content is produced from an olefin-containing hydrocarbon feedstock which includes sulfur-containing impurities. The feedstock is contacted with an olefin-modification catalyst in a reaction zone under conditions which are effective to produce an intermediate product which has a reduced amount of olefinic unsaturation relative to that of the feedstock as measured by bromine number. The intermediate product is then contacted with a hydrodesulfurization catalyst in the presence of hydrogen under conditions which are effective to convert at least a portion of its sulfur-containing impurities to hydrogen sulfide.
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公开(公告)号：US6111159A
公开(公告)日：2000-08-29
申请号：US203019
申请日：1998-12-01
CPC分类号： C07C2/18 , C07C2/70 , C10G50/00 , C07C2527/173
摘要： A method is provided for putting a fresh bed of solid phosphoric acid catalyst into service to catalyze a hydrocarbon conversion process. The method involves establishing hydrocarbon conversion conditions of temperature and pressure in the catalyst bed while it is immersed in a hydrocarbon liquid which is substantially free of water and compounds which can yield water upon contact with the catalyst. Thereafter, the catalyst bed is used to catalyze the conversion of a hydrocarbon feedstock which contains a minor amount of a hydrating agent which is effective to provide a desired level of catalyst hydration. The method permits the catalyst to be rapidly brought to an optimum level of activity for the specific hydrocarbon conversion process.
摘要翻译： 提供了一种将新鲜的固体磷酸催化剂床用于催化烃转化过程的方法。 该方法包括在浸入基本上不含水的烃液体中和在与催化剂接触时可产生水的化合物时，在催化剂床中建立温度和压力的烃转化条件。 此后，催化剂床用于催化含有少量水合剂的烃原料的转化，其有效提供所需水平的催化剂水合。 该方法允许催化剂快速地达到特定烃转化过程的最佳活性水平。
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9.发明授权Oxidative coupling process for converting methane and/or natural gas to more transportable products 失效将甲烷和/或天然气转化为更多可运输产品的氧化偶合方法
公开(公告)号：US5015799A
公开(公告)日：1991-05-14
申请号：US376307
申请日：1989-07-06
申请人： Robert H. Walker , Paul A. Willems , George A. Huff , Lewis E. Grimes , David F. Tatterson , Robert L. Mehlberg
发明人： Robert H. Walker , Paul A. Willems , George A. Huff , Lewis E. Grimes , David F. Tatterson , Robert L. Mehlberg
IPC分类号： C07C2/82
CPC分类号： C07C2/82 , Y10S585/943
摘要： A method for converting methane to higher molecular weight hydrocarbons wherein hot oxidative coupling reactor effluent is briefly contacted with a C.sub.2 to C.sub.20 alkane quench material to remove part of the heat contained in the raw reactor effluent, and is then further quenched by thermal quenching means to achieve a temperature which discourages retrograde reactions.
摘要翻译： 一种将甲烷转化为较高分子量烃的方法，其中热氧偶联反应器流出物与C2至C20烷烃淬火材料短暂接触以除去生反应器流出物中所含的一部分热量，然后通过热淬火装置进一步淬火 达到避免逆行反应的温度。
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公开(公告)号：US20080223785A1
公开(公告)日：2008-09-18
申请号：US11685461
申请日：2007-03-13
IPC分类号： B01D61/00
CPC分类号： B01D71/44 , B01D53/228 , B01D61/00 , B01D67/0093 , B01D71/40 , B01D71/82 , B01D2257/708 , B01D2323/36 , B01D2325/14 , B01D2325/16
摘要： Compositions and processes are disclosed for economical separation of fluid mixtures. Broadly, the present invention discloses ionic polymer compositions that are useful for perm-selective membrane separations. More particularly, ionic polymers of the invention comprise a plurality of repeating structural units having as a constituent part thereof organic ionic moieties consisting of nitrogen containing anions and/or cations. In the form of non-porous membranes, ionic polymers of the invention facilitate recovery of purified organic and inorganic products from fluid mixtures by means of perm-selective membrane separations. The present invention also provides methods for forming the ionic polymers, for example by treating selected nitrogen-containing organic polymers with acids, or treating a polymeric material comprising a plurality of carboxylate groups with an amine. Ionic polymer compositions of the invention are particularly useful for simultaneous recovery of a permeate product of an increased concentration, and a desired non-permeate stream, from a fluid mixture containing at least two compounds of different boiling point temperatures.
摘要翻译： 公开了用于经济分离流体混合物的组合物和方法。 广泛地，本发明公开了可用于烫发选择性膜分离的离子聚合物组合物。 更具体地，本发明的离子聚合物包含多个重复结构单元，其具有由含有阴离子和/或阳离子的氮组成的有机离子部分的组成部分。 以无孔膜的形式，本发明的离子聚合物便于通过选择性膜分离从流体混合物中回收纯化的有机和无机产物。 本发明还提供了形成离子聚合物的方法，例如通过用酸处理选定的含氮有机聚合物，或用胺处理包含多个羧酸酯基团的聚合物材料。 本发明的离子聚合物组合物特别可用于从含有至少两种不同沸点温度的化合物的流体混合物中同时回收浓度增加的渗透产物和期望的非渗透物流。
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