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    PROCESS FOR PREPARING COPPER-COMPRISING METAL ORGANIC FRAMEWORKS
    1.
    发明申请
    PROCESS FOR PREPARING COPPER-COMPRISING METAL ORGANIC FRAMEWORKS 审中-公开
    制备包含金属有机骨架的方法

    公开(公告)号：US20090306420A1

    公开(公告)日：2009-12-10

    申请号：US12375218

    申请日：2007-07-13

    申请人： Markus Schubert ,  Faruk Oezkirim ,  Christoph Kiener ,  Ulrich Mueller ,  Markus Tonigold

    发明人： Markus Schubert ,  Faruk Oezkirim ,  Christoph Kiener ,  Ulrich Mueller ,  Markus Tonigold

    IPC分类号： C07F1/08

    CPC分类号： C07F1/005

    摘要： The present invention relates to a process for preparing a porous metal organic framework comprising a first and at least one second at least bidentate organic compound coordinated to at least one copper ion, which comprises the steps (a) reaction of a reaction mixture in the liquid phase comprising at least one copper compound and the first at least bidentate organic compound to form an intermediate complex comprising the at least one copper ion and the first at least bidentate organic compound, with the first at least bidentate organic compound being derived from a dicarboxylic acid and having a skeleton which is a hydrocarbon, and (b) reaction of the intermediate complex with the at least second at least bidentate organic compound, with the at least second at least bidentate organic compound being an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S, wherein the reaction mixture in step (a) comprises less than a 3-fold excess of formic acid based on the copper of the copper compound used.

    摘要翻译： 本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种铜离子配位的第一和至少一种第二至少二齿有机化合物，其包括以下步骤：（a）将反应混合物在液体 包含至少一种铜化合物和第一至少二齿有机化合物以形成包含至少一种铜离子和第一至少二齿有机化合物的中间体络合物，第一至少二齿有机化合物衍生自二羧酸 并且具有作为烃的骨架，和（b）中间体络合物与至少第二至少二齿有机化合物的反应，至少第二至少二齿有机化合物是任选取代的单环，双环或多环饱和或 不饱和烃，其中至少两个环碳原子被杂原子所取代 由N，O和S组成，其中步骤（a）中的反应混合物包含基于所使用的铜化合物的铜少于3倍过量的甲酸。

    Mesoporous metal-organic framework
    4.
    发明授权
    Mesoporous metal-organic framework 有权
    介孔金属 - 有机骨架

    公开(公告)号：US07842827B2

    公开(公告)日：2010-11-30

    申请号：US11996976

    申请日：2006-08-16

    申请人： Markus Schubert ,  Ulrich Mueller ,  Hendrick Mattenheimer ,  Markus Tonigold

    发明人： Markus Schubert ,  Ulrich Mueller ,  Hendrick Mattenheimer ,  Markus Tonigold

    IPC分类号： C07F5/06 ,  B01J33/00

    CPC分类号： C07F5/069 ,  C01B3/001 ,  C01B3/0015 ,  C01B3/0026 ,  C07C51/418 ,  Y02E60/327 ,  Y02E60/328 ,  C07C63/307

    摘要： The present invention relates to a porous metal-organic framework comprising AlIII and at least one at least bidentate compound, wherein the at least one at least bidentate organic compound is a six-membered aromatic hydrocarbon ring A in which one or more ring carbons may be replaced by nitrogen and which has three substituents X and optionally one or more substituents selected from the group consisting of R, NRR′, OR, SR, F, Cl and Br, where R, R′ are each, independently of one another, hydrogen, methyl which may optionally be substituted by one or more fluorine atoms or ethyl which may optionally be substituted by one or more fluorine atoms and each X is, independently of the others, C(═O)O−, C(═S)O−, C(═O)S−, C(═S)S− or a protonated form thereof. The invention further provides a process for preparing it and provides for the use of the new porous metal-organic framework.

    摘要翻译： 本发明涉及包含AlIII和至少一种至少二齿化合物的多孔金属 - 有机骨架，其中所述至少一种至少二齿的有机化合物是其中一个或多个环碳可以是六元芳烃环A 被氮取代，并且具有三个取代基X和任选的一个或多个选自R，NRR'，OR，SR，F，Cl和Br的取代基，其中R，R'彼此独立地为氢 可以任选被一个或多个氟原子取代的甲基或可任意被一个或多个氟原子取代的乙基，并且每个X独立地为C（= O）O-，C（= S）O - ，C（= O）S-，C（= S）S-或其质子化形式。 本发明还提供了一种制备该方法并提供了新的多孔金属 - 有机骨架的用途。

    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS
    10.
    发明申请
    PROCESS FOR THE SEPARATION OF UNBRANCHED HYDROCARBONS FROM THEIR BRANCHED ISOMERS 失效
    从分散式异构体中分离出未结合的烃类的方法

    公开(公告)号：US20100197990A1

    公开(公告)日：2010-08-05

    申请号：US12668436

    申请日：2008-06-30

    申请人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener ,  Ingo Richter ,  William Dolan ,  Frank Poplow

    发明人： Markus Schubert ,  Ulrich Mueller ,  Christoph Kiener ,  Ingo Richter ,  William Dolan ,  Frank Poplow

    IPC分类号： C07C7/12

    CPC分类号： C07C7/12 ,  B01J20/22 ,  B01J20/226 ,  B01J2220/56 ,  C07C7/135 ,  C10G25/003 ,  C07C9/00

    摘要： The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of—contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.

    摘要翻译： 本发明涉及从含有非支链烃和非支链烃的至少一种支链异构体的流体混合物中分离至少一种未分支的C 4 -C 20烃的方法，其包括使流体混合物与 吸附剂，其包含多孔金属有机骨架材料，该材料包含与至少一种金属离子配位结合的至少一种至少二齿有机化合物，以获得非支化烃被吸附，其中至少一种至少二齿有机化合物是单环， 衍生自选自吡咯，α-吡啶酮和γ-吡啶酮的至少一种杂环的双环或多环系统，并且具有至少两个环氮并且是未取代的或带有一个或多个独立地选自以下的取代基： 的卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，Ophenyl和OCi-6-alk 其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自卤素，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH， 苯基和OC 1-6烷基。 本发明还涉及所述多孔金属 - 有机骨架材料在从其支化异构体中分离未分支烃的方法中的用途。