摘要:
The invention relates to a process for purifying an ionic liquid, which comprises the steps (a) partial crystallization of the ionic liquid from its melt and (b) separation of the crystals from the residual melt.
摘要:
The invention relates to a process for purifying an ionic liquid, which comprises the steps (a) partial crystallization of the ionic liquid from its melt and (b) separation of the crystals from the residual melt.
摘要:
The invention relates to a method of operating a liquid ring compressor having an impeller installed eccentrically in a compressor body, with gas being supplied to the liquid ring compressor on a suction side and gas being discharged from the liquid ring compressor on a pressure side. A liquid ring is generated in the liquid ring compressor on the inside of the compressor body by rotation of the impeller. Chambers are formed between blades of the impeller and the liquid ring and gas is drawn into these. The gas is compressed in the chambers which become smaller from the suction side to the pressure side as a result of the rotation of the eccentrically mounted impeller. The compressed gas is ejected on the pressure side. An ionic liquid is used as service liquid for generation of the liquid ring.
摘要:
The invention relates to a method of operating a liquid ring compressor having an impeller installed eccentrically in a compressor body, with gas being supplied to the liquid ring compressor on a suction side and gas being discharged from the liquid ring compressor on a pressure side. A liquid ring is generated in the liquid ring compressor on the inside of the compressor body by rotation of the impeller. Chambers are formed between blades of the impeller and the liquid ring and gas is drawn into these. The gas is compressed in the chambers which become smaller from the suction side to the pressure side as a result of the rotation of the eccentrically mounted impeller. The compressed gas is ejected on the pressure side. An ionic liquid is used as service liquid for generation of the liquid ring.
摘要:
A process for preparing chlorine by catalytic gas-phase oxidation of hydrogen chloride over a fixed catalyst bed is disclosed that includes: making available a feed gas stream I with hydrogen chloride and an oxygen-containing feed gas stream II, feeding the feed gas stream I, the feed gas stream II, and, if desired, a recycled stream Ia with hydrogen chloride, an oxygen-containing recycle stream IIa, and a recycled stream III into an oxidation zone and oxidizing hydrogen chloride to chlorine in the presence of a catalyst present in a fixed bed to give product gas stream IV having chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor, and taking the recycled stream III from the product gas stream IV, without further treatment, and recirculating it to the oxidation zone, leaving a product gas stream IVa.
摘要:
The invention relates to a process for carrying out exothermic chemical equilibrium reactions in a fluidized-bed reactor, wherein there is a temperature distribution in the fluidized bed of the fluidized-bed reactor and the temperature difference between the lowest temperature and the highest temperature is at least 10 K. The invention further relates to a fluidized-bed reactor for carrying out chemical reactions in a fluidized bed (5), wherein at least one heat exchanger (12, 28) is located in the fluidized bed (5) to control the temperature distribution.
摘要:
A process for preparing formaldehyde by gas-phase oxidation of methanol vapor by means of a gas stream comprising molecular oxygen in the presence of a fixed-bed catalyst comprising iron and molybdenum, wherein the process is carried out in a reactor (1) having heat-exchange plates (2) which are arranged in the longitudinal direction of the reactor (1) and have a spacing between them and through which a heat transfer medium flows, inlet and outlet facilities (3, 4) for the heat transfer medium to the heat-exchange plates (2) and also gaps (5) between heat-exchange plates (2) in which the fixed-bed catalyst is present and into which the methanol vapor and the gas stream comprising molecular oxygen are passed, is described.
摘要:
The invention relates to a process for preparing chlorine by catalytic gas-phase oxidation of hydrogen chloride, which comprises the steps: a) providing a feed gas stream I comprising hydrogen chloride and a feed gas stream II comprising oxygen; b) in a first oxidation stage, feeding the feed gas stream I, the feed gas stream II, if desired a recycle stream la comprising hydrogen chloride and if desired an oxygen-containing recycle stream IIa into a first oxidation zone and bringing them into contact with a first oxidation catalyst so that a first partial amount of the hydrogen chloride is oxidized to chlorine and a gas stream III comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; c) in a second oxidation stage, feeding the gas stream III into a second oxidation zone and bringing it into contact with at least one further oxidation catalyst so that a second partial amount of the hydrogen chloride is oxidized to chlorine and a product gas stream IV comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; d) isolating chloride, if desired the recycle stream Ia and if desired the recycle stream IIa from the product gas stream IV, wherein the first oxidization catalyst in the first oxidation zone is present in a fluidized bed and the further oxidation catalyst or catalysts in the second oxidation zone is/are present in a fixed bed.
摘要:
The present invention relates to a process for the continuous preparation of chlorine by reaction of hydrogen chloride with oxygen in the presence of a heterogeneous catalyst, in which the conversion of hydrogen chloride in a single pass through the reactor is restricted to from 15 to 90%.