Polymer and Polymerization Method
    1.
    发明申请
    Polymer and Polymerization Method 有权
    聚合物和聚合方法

    公开(公告)号:US20120046440A1

    公开(公告)日:2012-02-23

    申请号:US13264143

    申请日:2010-04-15

    IPC分类号: C08G75/06 C08G73/06 C08G75/00

    摘要: A method for forming a polymer comprising the polymerization of a plurality of monomers, wherein at least one of the plurality of monomers is one or both of: a charge transporting unit and a hydrocarbon monomer in which at least one carbon atom has been substituted by an atom or group with a greater quantity of unshared valence electrons than the carbon atom it has been substituted for, and wherein at least one of the plurality of monomers comprises an end-capping compound at one end of said monomer, the end-capping compound preventing polymerization at the end, wherein the end-capping compound is not charge transporting and comprises at least two rings. The end capping compound preferably consists of or includes a structural unit having the formula: (Ar)n—X, wherein Ar in each occurrence independently represents an aryl or heteroaryl group; X represents a leaving group comprising a boron derivative group or halogen; and n is 2 or more.

    摘要翻译: 一种形成聚合物的方法,其包括多个单体的聚合,其中所述多个单体中的至少一个单体是以下之一或两者:电荷输送单元和烃单体,其中至少一个碳原子被 原子或基团,其具有比其已被取代的碳原子更大量的非共价价电子,并且其中所述多个单体中的至少一个单体包含在所述单体一端的封端化合物,所述封端化合物预防 末端聚合,其中封端化合物不是电荷输送并且包含至少两个环。 封端化合物优选包含或包括具有下式的结构单元:(Ar)n -X,其中Ar各自独立地表示芳基或杂芳基; X表示包含硼衍生物基团或卤素的离去基团; n为2以上。

    (Partially) conjugated polymer, process for its preparation and use in electroluminescent devices
    2.
    发明授权
    (Partially) conjugated polymer, process for its preparation and use in electroluminescent devices 有权
    (部分)共轭聚合物,其制备和用于电致发光器件的方法

    公开(公告)号:US07898163B2

    公开(公告)日:2011-03-01

    申请号:US11585753

    申请日:2006-10-24

    IPC分类号: H01J1/62

    摘要: A polymer for use in an optical device comprising one or more regions, where each region comprises (i) a first structural unit having general formula I: where m=1 or 2 and which contains at least one substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, heteroaryl, and heteroaryloxy groups, each of which may be further substituted; and (ii) a second structural unit Ar selected from the group consisting of heteroaryl, triarylamine and 2,7-fluorenyl; such that where m=1 each region comprises a unit having general formula II: wherein, the substituent has a molecular weight of less than 300.

    摘要翻译: 一种用于包括一个或多个区域的光学器件的聚合物,其中每个区域包括(i)具有通式I的第一结构单元:其中m = 1或2,并且其包含至少一个选自烷基 ,烷氧基,芳基,芳氧基,杂芳基和杂芳氧基,其中每一个可以进一步被取代; 和(ii)选自杂芳基,三芳基胺和2,7-芴基的第二结构单元Ar; 使得当m = 1时,每个区域包含具有通式II的单元:其中,取代基的分子量小于300。

    (Partially) conjugated polymer process for its preparation and use in electroluminescent devices
    3.
    发明授权
    (Partially) conjugated polymer process for its preparation and use in electroluminescent devices 有权
    (部分)共轭聚合物方法,用于其在电致发光器件中的制备和应用

    公开(公告)号:US07125952B2

    公开(公告)日:2006-10-24

    申请号:US10468719

    申请日:2002-02-20

    IPC分类号: C08G61/00 C08G61/10

    摘要: A polymer for use in an optical device comprising one or more regions, where each region comprises (i) a first structural unit having general formula I: where m=1 or 2 and which contains at least one substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, heteroaryl, and heteroaryloxy groups, each of which may be further substituted; and (ii) a second structural unit Ar selected from the group consisting of heteroaryl, triarylamine and 2,7-fluorenyl; such that where m=1 each region comprises a unit having general formula II: first structural unit—Ar  (II) wherein, the substituent has a molecular weight of less than 300.

    摘要翻译: 一种用于包括一个或多个区域的光学器件的聚合物,其中每个区域包括(i)具有通式I的第一结构单元:其中m = 1或2,并且其包含至少一个选自烷基 ,烷氧基,芳基,芳氧基,杂芳基和杂芳氧基,其中每一个可以进一步被取代; 和(ii)选自杂芳基,三芳基胺和2,7-芴基的第二结构单元Ar; 使得当m = 1时,每个区域包括具有通式II的单元:<?in-line-formula description =“In-line Formulas”end =“lead”?> 第一个结构 单位-Ar (II)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中,取代基的分子量小于300 。

    Triarylamine containing monomers for optoelectronic devices
    7.
    发明授权
    Triarylamine containing monomers for optoelectronic devices 有权
    含三芳基胺的单体用于光电器件

    公开(公告)号:US07348428B2

    公开(公告)日:2008-03-25

    申请号:US10493637

    申请日:2002-10-18

    IPC分类号: C07F5/02

    摘要: Monomers having the formula X1—Ar1-[triarylamine]—Ar2-X2 wherein the triarylamine unit comprises at least one nitrogen atom in the backbone of the monomer and at least three substituted or unsubstituted aryl or heteroaryl groups and wherein X1 and X2 are the same or different polymerizable groups and wherein Ar1 and Ar2 are the same or different substituted or unsubstituted aryl or heteroaryl groups. Polymers and copolymers comprising such monomers are also described. The polymers have particular application in organic optoelectronic devices such as organic electroluminescent devices and organic photovoltaic devices.

    摘要翻译: 具有式X 1 -Ar 1 - [三芳基胺] -Ar 2 -X 2的单体其中三芳基胺 单元在单体的主链中包含至少一个氮原子和至少三个取代或未取代的芳基或杂芳基,并且其中X 1和X 2是相同或不同的 可聚合基团,其中Ar 1和Ar 2是相同或不同的取代或未取代的芳基或杂芳基。 还描述了包含这种单体的聚合物和共聚物。 聚合物在有机光电器件如有机电致发光器件和有机光电器件中具有特殊应用。

    Triarylamine containing monomers for optoelectronic devices
    8.
    发明申请
    Triarylamine containing monomers for optoelectronic devices 有权
    含三芳基胺的单体用于光电器件

    公开(公告)号:US20050070710A1

    公开(公告)日:2005-03-31

    申请号:US10493637

    申请日:2002-10-18

    摘要: Monomers having the formula X1—Ar1-[triarylamine]-Ar2—X2 wherein the triarylamine unit comprises at least one nitrogen atom in the backbone of the monomer and at least three substituted or unsubstituted aryl or heteroaryl groups and wherein X1 and X2 are the same or different polymerizable groups and wherein Ar1 and Ar2 are the same or different substituted or unsubstituted aryl or heteroaryl groups. Polymers and copolymers comprising such monomers are also described. The polymers have particular application in organic optoelectronic devices such as organic electroluminescent devices and organic photovoltaic devices.

    摘要翻译: 具有式X1-Ar1- [三芳基胺] -Ar2-X2的单体,其中三芳基胺单元在单体的主链中包含至少一个氮原子和至少三个取代或未取代的芳基或杂芳基,并且其中X 1和X 2相同 或不同的可聚合基团,其中Ar1和Ar2是相同或不同的取代或未取代的芳基或杂芳基。 还描述了包含这种单体的聚合物和共聚物。 聚合物在有机光电器件如有机电致发光器件和有机光电器件中具有特殊应用。

    Monomer, Polymerization Method, and Polymer
    10.
    发明申请
    Monomer, Polymerization Method, and Polymer 有权
    单体,聚合方法和聚合物

    公开(公告)号:US20120053315A1

    公开(公告)日:2012-03-01

    申请号:US13258910

    申请日:2010-04-15

    IPC分类号: C08G73/22 C07D265/38

    摘要: A monomer of formula (III): wherein X is a polymerisable group Ar, Ar1 and Ar2 each independently represent an optionally substituted aryl or heteroaryl group; R1 represents H or a substituent; and Z represents a direct bond or a divalent linking atom or group, wherein Ar1 and Ar2 are linked by a single bond or a divalent linking group selected from CR1R2, SiR1R2, PR1, NR1, O and S wherein R1 and R2 are independently selected from hydrogen; optionally substituted alkyl wherein one or more non-adjacent C atoms may be replaced with O, S, N, C═O and —COO—; alkoxy, aryl, arylalkyl, heteroaryl and heteroarylalkyl. Ar1 and Ar2 are preferably linked by an oxygen atom, and Ar1 and/or Ar2 may be fused to their respective adjacent Ar groups. Ar1 and its adjacent Ar group and/or Ar2 and its adjacent Ar group are optionally fused to form a fluorene unit.

    摘要翻译: 式(III)的单体:其中X是可聚合基团Ar,Ar 1和Ar 2各自独立地表示任选取代的芳基或杂芳基; R1表示H或取代基; Z表示直接键或二价连接原子或基团,其中Ar 1和Ar 2通过单键或选自CR 1 R 2,SiR 1 R 2,PR 1,NR 1,O和S的二价连接基团连接,其中R 1和R 2独立地选自 氢; 任选取代的烷基,其中一个或多个不相邻的C原子可被O,S,N,C = O和-COO-取代; 烷氧基,芳基,芳基烷基,杂芳基和杂芳基烷基。 Ar 1和Ar 2优选通过氧原子连接,并且Ar 1和/或Ar 2可以与它们各自相邻的Ar基团稠合。 Ar1及其相邻的Ar基团和/或Ar 2及其相邻的Ar基团任选地稠合形成芴单元。