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公开(公告)号:USRE41136E1
公开(公告)日:2010-02-16
申请号:US10053690
申请日:2002-01-24
申请人: Masahiro Motoyuki , Koji Yamamoto , Ajit Vishwanath Sapre , John Paul McWilliams , Susan Patricia Donnelly
发明人: Masahiro Motoyuki , Koji Yamamoto , Ajit Vishwanath Sapre , John Paul McWilliams , Susan Patricia Donnelly
CPC分类号: C07C4/12 , C07C15/24 , C07C2521/04 , C07C2523/26 , C07C2523/75 , C07C2523/883 , C07C2529/06 , C08G63/189
摘要: The present invention relates to a process of preparing dialkylnaphthylenes and polyalkylenenaphthyleneates dialkylnaphthalenes and polyalkylenenaphthalates.
摘要翻译: 本发明涉及制备二烷基萘和聚亚烷基亚萘基二烷基萘和聚亚烷基亚萘基酯的方法。
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公开(公告)号:US5723711A
公开(公告)日:1998-03-03
申请号:US744828
申请日:1996-11-06
CPC分类号: C07C5/2737 , C07C2529/70
摘要: A process for producing 2-methylnaphthalene from a feedstock containing 1-methylnaphthalene by contacting the feedstock with a catalyst composition, in which the process comprising isomerization of 1-methylnaphthalene, wherein the catalyst composition comprising a synthetic zeolite characterized by an X-ray diffraction pattern including interplanar d-spacing as set forth in Table A of the specification.
摘要翻译: 通过使原料与催化剂组合物接触,由含有1-甲基萘的原料生产2-甲基萘的方法,其中所述方法包括1-甲基萘的异构化,其中所述催化剂组合物包含以X射线衍射图案为特征的合成沸石 包括说明书的表A所示的平面间距d。
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公开(公告)号:USRE39222E1
公开(公告)日:2006-08-01
申请号:US10076431
申请日:2002-02-19
申请人: Masahiro Motoyuki , Koji Yamamoto , Ajit Vishwanath Sapre , John Paul McWilliams , Susan Patricia Donnelly
发明人: Masahiro Motoyuki , Koji Yamamoto , Ajit Vishwanath Sapre , John Paul McWilliams , Susan Patricia Donnelly
IPC分类号: C07C1/00 , C07C4/12 , C07C5/22 , C07C2/68 , C08G63/181
CPC分类号: C07C4/12 , C07C15/24 , C07C2521/04 , C07C2523/26 , C07C2523/75 , C07C2523/883 , C07C2529/06 , C08G63/189
摘要: A process for producing 2,6-dialkylnaphthalene from a hydrocarbon feedstock that contains at least one component selected from the group consisting of dialkylnaphthalene isomers, monoalkylnaphthalene isomers, polyalkylnaphthalenes, and naphthalene, is provided that includes the following steps: I. separating the hydrocarbon feedstock and/or a dealkylation product fed from step III into a naphthalene fraction, a monoalkylnaphthalene fraction, a dialkylnaphthalene fraction and a remaining products fraction; II. separating and purifying 2,6-dialkylnaphthalene from the dialkylnaphthalene fraction of step I; III. dealkylating the hydrocarbon feedstock and/or the remaining products fraction of step I and feeding the dealkylation product to step I; and IV. alkylating the naphthalene and monoalkylnaphthalene fractions of step I; wherein the hydrocarbon feedstock is fed to step I or step III.
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公开(公告)号:US6011190A
公开(公告)日:2000-01-04
申请号:US887052
申请日:1997-07-02
IPC分类号: B01J29/04 , C07B61/00 , C07C2/66 , C07C6/12 , C07C15/24 , C07C1/01 , C07C2/64 , C07C2/68 , C07C5/22
CPC分类号: C07C15/24 , C07C2/66 , C07C6/126 , C07C2529/70
摘要: 2,6-Dialkylnaphthalene is prepared from a feedstock comprising naphthalene and an alkylating agent, by a process comprising the steps:(I) transalkylating isomers of dialkylnaphthalene and naphthalene to produce monoalkylnaphthalene and isomers of dialkylnaphthalene;(II) separating the product obtained in step (I) into naphthalene, monoalkylnaphthalene, dialkylnaphthalene and other components;(III) alkylating the monoalkylnaphthalene fraction from step (II) with an alkylating agent to produce dialkylnaphthalene; and(IV) separating 2,6-dialkylnaphthalene from the dialkylnaphthalene fraction in step (II),wherein at least step (I) or step (III) is conducted in the presence of a catalyst having a composition comprising a synthetic zeolite having an X-ray diffraction pattern with an interplanar d-spacing (.ANG.)______________________________________ 12.36 .+-. 0.4 11.03 .+-. 0.2 8.83 .+-. 0.14 6.18 .+-. 0.12 6.00 .+-. 0.10 4.06 .+-. 0.07 3.91 .+-. 0.07 3.42 .+-. 0.06. ______________________________________
摘要翻译: 2,6-二烷基萘由包含萘和烷基化剂的原料制备,通过包括以下步骤的方法制备:(I)将烷基萘和萘的异构体转烷基化以产生单烷基萘和二烷基萘的异构体; (II)将步骤(I)中获得的产物分离成萘,单烷基萘,二烷基萘等组分; (III)用烷基化剂烷基化来自步骤(II)的单烷基萘馏分以制备二烷基萘; 和(IV)在步骤(II)中从二烷基萘馏分中分离2,6-二烷基萘,其中至少步骤(I)或步骤(III)在具有包含具有X 具有面间d间距(ANGSTROM)的-ray衍射图 - 12.36 +/- 0.4-11.03 +/- 0.2-8.83 +/- 0.14-6.18 +/- 0.12- 6.00 +/- 0.10-4.06 +/- 0.07- 3.91 +/- 0.07 - 3.42 +/- 0.06。 -
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公开(公告)号:US5844064A
公开(公告)日:1998-12-01
申请号:US974231
申请日:1997-11-19
IPC分类号: B01J29/06 , C07B61/00 , C07C5/27 , C07C6/12 , C07C15/24 , C08G63/189 , C08G63/02 , C08G63/00
CPC分类号: C08G63/189 , C07C15/24 , C07C6/126 , C07C2529/70
摘要: A process for producing alkylnaphthalene from a feedstock comprising isomers of dialkylnaphthalene and naphthalene by contacting the feedstock with a catalyst composition, in which the process comprising transalkylation between isomers of dialkylnaphthalene and naphthalene to produce monoalkylnaphthalene, and isomerization of dialkylnaphthalene, wherein the catalyst composition comprising a synthetic zeolite characterized by an X-ray diffraction pattern including interplanar d-spacing as set forth in Table A of the specification.
摘要翻译: 通过使原料与催化剂组合物接触,由原料包含二烷基萘和萘的异构体制备烷基萘的方法,其中该方法包括二烷基萘和萘的异构体之间的烷基转移以产生单烷基萘,和二烷基萘的异构化,其中催化剂组合物包含 其特征在于包括本说明书的表A所示的平面d间距的X射线衍射图案。
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公开(公告)号:US5744670A
公开(公告)日:1998-04-28
申请号:US661114
申请日:1996-06-10
IPC分类号: B01J29/06 , C07B61/00 , C07C5/27 , C07C6/12 , C07C15/24 , C08G63/189 , C07C2/00 , C07C2/66 , C07C5/22
CPC分类号: C08G63/189 , C07C15/24 , C07C6/126 , C07C2529/70
摘要: A process for producing alkylnaphthalene from a feedstock comprising isomers of dialkylnaphthalene and naphthalene by contacting the feedstock with a catalyst composition, in which the process comprising transalkylation between isomers of dialkylnaphthalene and naphthalene to produce monoalkylnaphthalene, and isomerization of dialkylnaphthalene, wherein the catalyst composition comprising a synthetic zeolite characterized by an X-ray diffraction pattern including interplanar d-spacing as set forth in Table A of the specification.
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公开(公告)号:US06617482B1
公开(公告)日:2003-09-09
申请号:US09639555
申请日:2000-08-16
申请人: Chaya Rao Venkat , Yun-Yang Huang , Thomas Francis Degnan, Jr. , John Paul McWilliams , Ronald A. Weiss
发明人: Chaya Rao Venkat , Yun-Yang Huang , Thomas Francis Degnan, Jr. , John Paul McWilliams , Ronald A. Weiss
IPC分类号: C07C266
CPC分类号: C07C15/02 , C07C7/13 , C07C2529/70 , C07C15/00
摘要: A process is described for removing polar compounds from an aromatic feedstock which contains polar compounds and which is then used in an alkylation process. The process comprises contacting the feedstock in an adsorption zone at a temperature of less than or equal to 130° C. with an adsorbent selective for the adsorption of said polar compounds and comprising a molecular sieve having pores and/or surface cavities with cross-sectional dimensions greater than 5.6 Angstroms. A treated feedstock substantially free of said polar compounds is withdrawn from the adsorption zone and fed to an alkylation zone for contact under liquid phase alkylation conditions with an alkylating agent in the presence of an alkylation catalyst.
摘要翻译: 描述了从含有极性化合物的芳族原料中除去极性化合物的方法,然后将其用于烷基化方法。 该方法包括使原料在小于或等于130℃的吸附区中与选择性吸附所述极性化合物的吸附剂接触,并且包含具有孔和/或表面空腔的分子筛,其横截面 尺寸大于5.6埃。 基本上不含所述极性化合物的经处理的原料从吸附区排出,并在烷基化催化剂存在下,用烷基化剂在液相烷基化条件下进料至烷基化区进行接触。
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