公开(公告)号：US07307107B2

公开(公告)日：2007-12-11

申请号：US10522532

申请日：2003-07-17

申请人： Masao Imai ,  Mitsuo Nakamura ,  Hiroshi Naruse ,  Osamu Kohgo ,  Masahiro Enna ,  Atsuo Otsuji

发明人： Masao Imai ,  Mitsuo Nakamura ,  Hiroshi Naruse ,  Osamu Kohgo ,  Masahiro Enna ,  Atsuo Otsuji

IPC分类号： C08F2/46 ,  G02B1/10 ,  G03B21/60

CPC分类号： G02B1/041 ,  C08F22/105 ,  C08F222/1006 ,  C08L33/14 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2924/181 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/105 ,  Y10T428/1059 ,  Y10T428/1073 ,  Y10T428/1082 ,  C08L41/00 ,  H01L2924/00014 ,  H01L2924/00012

摘要： A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound is characterized by comprising (a) a bifunctional (meth)acrylic acid (thio)ester compound containing a sulfur atom in the molecule and (b) at least one of a (meth)acrylic acid ester compound represented by the general formula (1) or a bifunctional (meth)acrylic acid ester compound having a urethane linkage: wherein R1 and R2 are each independently a hydrogen atom or a methyl group; R3 and R4 are each independently an alkyl group, an aralkyl group, an aryl group or a halogen atom; m and n are each an integer of 0 to 2; X1 is an alkylidene group having 1 to 3 carbon atoms; and Y1 and Y2 are each independently a poly(oxyalkylene) group with the proviso that at least one of Y1 and Y2 is a poly(oxyalkylene) group having a hydroxy group.

摘要翻译： 一种包含可聚合化合物和光聚合引发剂的可光聚合组合物，其中所述可聚合化合物的特征在于包含（a）分子中含有硫原子的双官能（甲基）丙烯酸（硫代）酯化合物和（b）至少一种 由通式（1）表示的（甲基）丙烯酸酯化合物或具有氨基甲酸酯键的双官能（甲基）丙烯酸酯化合物：其中R 1和R 2 各自独立地为氢原子或甲基; R 3和R 4各自独立地为烷基，芳烷基，芳基或卤素原子; m和n分别为0〜2的整数。 X 1是具有1至3个碳原子的亚烷基; 和Y 1和Y 2 2各自独立地是聚（氧化烯）基团，条件是Y 1和Y 3中的至少一个 > 2 是具有羟基的聚（氧化烯）基团。

公开(公告)号：US20060003261A1

公开(公告)日：2006-01-05

申请号：US10522532

申请日：2003-07-17

申请人： Masao Imai ,  Mitsuo Nakamura ,  Hiroshi Naruse ,  Osamu Kohgo ,  Masahiro Enna ,  Atsuo Otsuji

发明人： Masao Imai ,  Mitsuo Nakamura ,  Hiroshi Naruse ,  Osamu Kohgo ,  Masahiro Enna ,  Atsuo Otsuji

IPC分类号： C08F2/46

CPC分类号： G02B1/041 ,  C08F22/105 ,  C08F222/1006 ,  C08L33/14 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2924/181 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/105 ,  Y10T428/1059 ,  Y10T428/1073 ,  Y10T428/1082 ,  C08L41/00 ,  H01L2924/00014 ,  H01L2924/00012

摘要： A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound is characterized by comprising (a) a bifunctional (meth)acrylic acid (thio)ester compound containing a sulfur atom in the molecule and (b) at least one of a (meth)acrylic acid ester compound represented by the general formula (1) or a bifunctional (meth)acrylic acid ester compound having a urethane linkage: wherein R1 and R2 are each independently a hydrogen atom or a methyl group; R3 and R4 are each independently an alkyl group, an aralkyl group, an aryl group or a halogen atom; m and n are each an integer of 0 to 2; X1 is an alkylidene group having 1 to 3 carbon atoms; and Y1 and Y2 are each independently a poly(oxyalkylene) group with the proviso that at least one of Y1 and Y2 is a poly(oxyalkylene) group having a hydroxy group.

摘要翻译： 一种包含可聚合化合物和光聚合引发剂的可光聚合组合物，其中所述可聚合化合物的特征在于包含（a）分子中含有硫原子的双官能（甲基）丙烯酸（硫代）酯化合物和（b）至少一种 由通式（1）表示的（甲基）丙烯酸酯化合物或具有氨基甲酸酯键的双官能（甲基）丙烯酸酯化合物：其中R 1和R 2 各自独立地为氢原子或甲基; R 3和R 4各自独立地为烷基，芳烷基，芳基或卤素原子; m和n分别为0〜2的整数。 X 1是具有1至3个碳原子的亚烷基; 和Y 1和Y 2 2各自独立地是聚（氧化烯）基团，条件是Y 1和Y 3中的至少一个 > 2 是具有羟基的聚（氧化烯）基团。

公开(公告)号：US08637633B2

公开(公告)日：2014-01-28

申请号：US13611773

申请日：2012-09-12

申请人： Mitsuo Nakamura ,  Hiroshi Naruse ,  Atsuo Otsuji ,  Shinichi Usugi ,  Masao Imai ,  Hidetoshi Hayashi ,  Osamu Kohgo ,  Hideki Yamamoto ,  Seiichi Kobayashi

发明人： Mitsuo Nakamura ,  Hiroshi Naruse ,  Atsuo Otsuji ,  Shinichi Usugi ,  Masao Imai ,  Hidetoshi Hayashi ,  Osamu Kohgo ,  Hideki Yamamoto ,  Seiichi Kobayashi

IPC分类号： C08G75/04

CPC分类号： C08G75/06 ,  C08G75/04 ,  C08G75/08 ,  C08L81/02 ,  G02B1/04 ,  C08L81/00

摘要： A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n−p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), a thiol compound and an episulfide compound.

摘要翻译： 一种包含由以下通式（1）表示的化合物的可聚合组合物：（式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m 表示0或1以上的整数，p表示1〜n的整数，n表示金属原子M的化合价，Y表示各自独立地表示无机或有机残基，np为2以上时，Y可以 彼此键合形成含有金属原子M），硫醇化合物和环硫化合物的环。

公开(公告)号：US20130005934A1

公开(公告)日：2013-01-03

申请号：US13611773

申请日：2012-09-12

申请人： Mitsuo Nakamura ,  Hiroshi Naruse ,  Atsuo Otsuji ,  Shinichi Usugi ,  Masao Imai ,  Hidetoshi Hayashi ,  Osamu Kohgo ,  Hideki Yamamoto ,  Seiichi Kobayashi

发明人： Mitsuo Nakamura ,  Hiroshi Naruse ,  Atsuo Otsuji ,  Shinichi Usugi ,  Masao Imai ,  Hidetoshi Hayashi ,  Osamu Kohgo ,  Hideki Yamamoto ,  Seiichi Kobayashi

IPC分类号： C08G79/00

CPC分类号： C08G75/06 ,  C08G75/04 ,  C08G75/08 ,  C08L81/02 ,  G02B1/04 ,  C08L81/00

摘要： A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n−p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), a thiol compound and an episulfide compound.

摘要翻译： 一种包含由以下通式（1）表示的化合物的可聚合组合物：（式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m 表示0或1或更大的整数; p表示1至n的整数; n表示金属原子M的价数; Y各自独立地表示无机或有机残基，其中当n-p为2或更大时， Y可以彼此键合形成含有金属原子M），硫醇化合物和环硫化合物的环。

公开(公告)号：US20100298519A1

公开(公告)日：2010-11-25

申请号：US12294683

申请日：2007-03-29

申请人： Mitsuo Nakamura ,  Hiroshi Naruse ,  Atsuo Otsuji ,  Shinichi Usugi ,  Masao Imai ,  Hidetoshi Hayashi ,  Osamu Kohgo ,  Hideki Yamamoto ,  Seiichi Kobayashi

发明人： Mitsuo Nakamura ,  Hiroshi Naruse ,  Atsuo Otsuji ,  Shinichi Usugi ,  Masao Imai ,  Hidetoshi Hayashi ,  Osamu Kohgo ,  Hideki Yamamoto ,  Seiichi Kobayashi

IPC分类号： C08G79/00

CPC分类号： C08G75/06 ,  C08G75/08 ,  G02B1/04 ,  C08L81/00

摘要： A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n-p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), and a thiol compound.

摘要翻译： 一种包含由以下通式（1）表示的化合物的可聚合组合物：（式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m 表示0或1以上的整数，p表示1〜n的整数，n表示金属原子M的化合价，Y表示各自独立地表示无机或有机残基，np为2以上时，Y可以 彼此键合形成含有金属原子M的环）和硫醇化合物。

公开(公告)号：US20100063246A1

公开(公告)日：2010-03-11

申请号：US12305010

申请日：2007-06-21

申请人： Shinichi Usugi ,  Mitsuo Nakamura ,  Hiroshi Naruse ,  Atsuo Otsuji ,  Osamu Kohgo ,  Hidetoshi Hayashi ,  Seiichi Kobayashi

发明人： Shinichi Usugi ,  Mitsuo Nakamura ,  Hiroshi Naruse ,  Atsuo Otsuji ,  Osamu Kohgo ,  Hidetoshi Hayashi ,  Seiichi Kobayashi

IPC分类号： C08G75/06

CPC分类号： C08G75/08 ,  C08G75/06

摘要： Disclosed is a polymerizable composition containing a compound represented by the general formula (1) below and a bluing agent, wherein, in the general formula (1) below, M represents a metal atom; X1 and X2 each independently represent a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents 0 or an integer of not less than 1; p represents an integer of not less than 1 but not more than n; n represents the valence of the metal atom M; Ys independently represent an inorganic or organic residue, and when n−p is not less than 2, Ys may combine together to form a ring containing the metal atom M.

摘要翻译： 公开了含有下述通式（1）表示的化合物和上蓝剂的聚合性组合物，其中，在下述通式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m表示0或1以上的整数， p表示不小于1但不大于n的整数; n表示金属原子M的化合价; Ys独立地表示无机或有机残基，当n-p不小于2时，Y可以结合在一起形成含有金属原子M的环。

公开(公告)号：US20080027198A1

公开(公告)日：2008-01-31

申请号：US11667227

申请日：2005-11-16

申请人： Hiroshi Naruse ,  Atsuo Otsuji ,  Mitsuo Nakamura

发明人： Hiroshi Naruse ,  Atsuo Otsuji ,  Mitsuo Nakamura

IPC分类号： C08G75/04 ,  C07C321/00 ,  C08G79/00 ,  G02B1/04 ,  C08G18/38

CPC分类号： C08G18/3874 ,  C08G18/3855 ,  C08G18/3863 ,  C08G18/3876 ,  C08G18/7642 ,  C08G18/791 ,  C08G18/8125 ,  C08G75/00 ,  C08G75/04 ,  C08G75/045 ,  C08G79/00

摘要： A compound having two or more thiol groups and an atom selected from metal atoms in a molecule, a polythiol composition containing such a compound, a polymerizable composition containing such a polythiol composition, a resin obtained by polymerization of such a polymerizable composition, and an optical component obtained from such a resin are provided. The polymerizable composition can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7.

摘要翻译： 具有两个以上硫醇基和选自分子中的金属原子的原子的化合物，含有该化合物的多硫醇组合物，含有这种多硫醇组合物的聚合性组合物，通过聚合该聚合性组合物得到的树脂和光学 提供了由这种树脂获得的组分。 聚合性组合物可以是获得高于1.7的高折射率（nd）的树脂的原料，其具有高透明性，良好的耐热性和诸如塑料透镜等的光学部件所需的机械强度。

公开(公告)号：US06835844B2

公开(公告)日：2004-12-28

申请号：US10332742

申请日：2003-01-13

申请人： Mitsuo Nakamura ,  Masao Imai ,  Atsuo Otsuji

发明人： Mitsuo Nakamura ,  Masao Imai ,  Atsuo Otsuji

IPC分类号： C07D33902

CPC分类号： C07D409/14 ,  C07D339/06 ,  C07D411/14 ,  C08F22/105 ,  C08F22/24 ,  G02B1/04 ,  G02B1/041 ,  C08L33/14 ,  C08L35/02

摘要： The present invention provides an acrylic ester compound represented by formula (1), a polymerizable composition containing the acrylic ester compound, and a cured product and an optical component obtained by polymerizing the polymerizable composition: (wherein “a” is an integer of 0 to 4; R1 is a directly bonded single bond, an alkylene group, an aralkylene group or arylene group which may have a substituent, or a —Y3—S—R4—S—Y4— group (R4 is an alkylene group, an aralkylene group or an arylene group; and Y3 and Y4 are each an alkylene group); R2 and R3 are each a hydrogen atom or an alkyl group; X1 and X2 are each an oxygen atom or a sulfur atom; and Y1 and Y2 are each an alkylene group which may contain an oxygen atom or a sulfur atom).

摘要翻译： 本发明提供由式（1）表示的丙烯酸酯化合物，含有丙烯酸酯化合物的聚合性组合物和通过使聚合性组合物聚合而得到的固化物和光学部件（其中，“a”为0〜 4; R1是直接键合的单键，可以具有取代基的亚烷基，亚芳基或亚芳基，或-Y 3 -S-R 4 -S-Y 4 - 基（R 4是亚烷基，亚芳基 或亚芳基; Y 3和Y 4各自为亚烷基）; R 2和R 3各自为氢原子或烷基; X 1和X 2各自为氧原子或硫原子，Y 1和Y 2各自为亚烷基 可以含有氧原子或硫原子的基团）。

公开(公告)号：US20070191615A1

公开(公告)日：2007-08-16

申请号：US10594497

申请日：2005-03-31

申请人： Atsuo Otsuji ,  Hiroshi Naruse ,  Mitsuo Nakamura

发明人： Atsuo Otsuji ,  Hiroshi Naruse ,  Mitsuo Nakamura

IPC分类号： C07D327/00

CPC分类号： C08G75/06 ,  G02B1/04

摘要： The present invention is to provide a polymerizable compound which can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7, and an optical component composed of such a resin. Disclosed is a compound represented by the general formula (3), wherein, in the formula, M represents a metal atom; X1 and X2 each independently represent a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or more; p represents an integer of from 1 to n; q represents an integer of from 1 to (n-p); n represents a valence of a metal atom M; Yq each independently represent an inorganic or organic residue; and when q is 2 or more, Yq may be bonded to one another for forming a ring structure with the intermediary of a metal atom M.

摘要翻译： 本发明提供一种聚合性化合物，其可以成为具有高透明度，高耐热性和塑料透镜等的光学部件所需的机械强度的树脂的原料，同时获得高折射率（nd） 1.7，以及由这种树脂构成的光学部件。 公开了由通式（3）表示的化合物，其中在式中，M表示金属原子; X 1和X 2各自独立地表示硫原子或氧原子; R 1表示二价有机基团; m表示0或1以上的整数， p表示1〜n的整数， q表示1〜（n-p）的整数。 n表示金属原子M的化合价; Yq各自独立地表示无机或有机残基; 当q为2以上时，可以将Yq彼此结合形成具有金属原子M的中间环状结构。

公开(公告)号：US07772348B2

公开(公告)日：2010-08-10

申请号：US11667227

申请日：2005-11-16

申请人： Hiroshi Naruse ,  Atsuo Otsuji ,  Mitsuo Nakamura

发明人： Hiroshi Naruse ,  Atsuo Otsuji ,  Mitsuo Nakamura

IPC分类号： C08G79/00 ,  C07F15/00 ,  C07F7/00 ,  C07F1/00

CPC分类号： C08G18/3874 ,  C08G18/3855 ,  C08G18/3863 ,  C08G18/3876 ,  C08G18/7642 ,  C08G18/791 ,  C08G18/8125 ,  C08G75/00 ,  C08G75/04 ,  C08G75/045 ,  C08G79/00

摘要： A compound having two or more thiol groups and an atom selected from metal atoms in a molecule, a polythiol composition containing such a compound, a polymerizable composition containing such a polythiol composition, a resin obtained by polymerization of such a polymerizable composition, and an optical component obtained from such a resin are provided. The polymerizable composition can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7.

摘要翻译： 具有两个以上硫醇基和选自分子中的金属原子的原子的化合物，含有该化合物的多硫醇组合物，含有这种多硫醇组合物的聚合性组合物，通过聚合该聚合性组合物得到的树脂和光学 提供了由这种树脂获得的组分。 聚合性组合物可以是获得高于1.7的高折射率（nd）的树脂的原料，其具有高透明性，良好的耐热性和诸如塑料透镜等的光学部件所需的机械强度。