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公开(公告)号：US07307107B2
公开(公告)日：2007-12-11
申请号：US10522532
申请日：2003-07-17
申请人： Masao Imai , Mitsuo Nakamura , Hiroshi Naruse , Osamu Kohgo , Masahiro Enna , Atsuo Otsuji
发明人： Masao Imai , Mitsuo Nakamura , Hiroshi Naruse , Osamu Kohgo , Masahiro Enna , Atsuo Otsuji
CPC分类号： G02B1/041 , C08F22/105 , C08F222/1006 , C08L33/14 , H01L2224/48091 , H01L2224/48247 , H01L2224/73265 , H01L2924/181 , Y10T428/10 , Y10T428/1036 , Y10T428/105 , Y10T428/1059 , Y10T428/1073 , Y10T428/1082 , C08L41/00 , H01L2924/00014 , H01L2924/00012
摘要： A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound is characterized by comprising (a) a bifunctional (meth)acrylic acid (thio)ester compound containing a sulfur atom in the molecule and (b) at least one of a (meth)acrylic acid ester compound represented by the general formula (1) or a bifunctional (meth)acrylic acid ester compound having a urethane linkage: wherein R1 and R2 are each independently a hydrogen atom or a methyl group; R3 and R4 are each independently an alkyl group, an aralkyl group, an aryl group or a halogen atom; m and n are each an integer of 0 to 2; X1 is an alkylidene group having 1 to 3 carbon atoms; and Y1 and Y2 are each independently a poly(oxyalkylene) group with the proviso that at least one of Y1 and Y2 is a poly(oxyalkylene) group having a hydroxy group.
摘要翻译： 一种包含可聚合化合物和光聚合引发剂的可光聚合组合物，其中所述可聚合化合物的特征在于包含（a）分子中含有硫原子的双官能（甲基）丙烯酸（硫代）酯化合物和（b）至少一种 由通式（1）表示的（甲基）丙烯酸酯化合物或具有氨基甲酸酯键的双官能（甲基）丙烯酸酯化合物：其中R 1和R 2 各自独立地为氢原子或甲基; R 3和R 4各自独立地为烷基，芳烷基，芳基或卤素原子; m和n分别为0〜2的整数。 X 1是具有1至3个碳原子的亚烷基; 和Y 1和Y 2 2各自独立地是聚（氧化烯）基团，条件是Y 1和Y 3中的至少一个 > 2 是具有羟基的聚（氧化烯）基团。
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公开(公告)号：US06835844B2
公开(公告)日：2004-12-28
申请号：US10332742
申请日：2003-01-13
申请人： Mitsuo Nakamura , Masao Imai , Atsuo Otsuji
发明人： Mitsuo Nakamura , Masao Imai , Atsuo Otsuji
IPC分类号： C07D33902
CPC分类号： C07D409/14 , C07D339/06 , C07D411/14 , C08F22/105 , C08F22/24 , G02B1/04 , G02B1/041 , C08L33/14 , C08L35/02
摘要： The present invention provides an acrylic ester compound represented by formula (1), a polymerizable composition containing the acrylic ester compound, and a cured product and an optical component obtained by polymerizing the polymerizable composition: (wherein “a” is an integer of 0 to 4; R1 is a directly bonded single bond, an alkylene group, an aralkylene group or arylene group which may have a substituent, or a —Y3—S—R4—S—Y4— group (R4 is an alkylene group, an aralkylene group or an arylene group; and Y3 and Y4 are each an alkylene group); R2 and R3 are each a hydrogen atom or an alkyl group; X1 and X2 are each an oxygen atom or a sulfur atom; and Y1 and Y2 are each an alkylene group which may contain an oxygen atom or a sulfur atom).
摘要翻译： 本发明提供由式（1）表示的丙烯酸酯化合物，含有丙烯酸酯化合物的聚合性组合物和通过使聚合性组合物聚合而得到的固化物和光学部件（其中，“a”为0〜 4; R1是直接键合的单键，可以具有取代基的亚烷基，亚芳基或亚芳基，或-Y 3 -S-R 4 -S-Y 4 - 基（R 4是亚烷基，亚芳基 或亚芳基; Y 3和Y 4各自为亚烷基）; R 2和R 3各自为氢原子或烷基; X 1和X 2各自为氧原子或硫原子，Y 1和Y 2各自为亚烷基 可以含有氧原子或硫原子的基团）。
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3.发明授权公开(公告)号：US08637633B2
公开(公告)日：2014-01-28
申请号：US13611773
申请日：2012-09-12
申请人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
发明人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
IPC分类号： C08G75/04
摘要： A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n−p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), a thiol compound and an episulfide compound.
摘要翻译： 一种包含由以下通式（1）表示的化合物的可聚合组合物：（式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m 表示0或1以上的整数，p表示1〜n的整数，n表示金属原子M的化合价，Y表示各自独立地表示无机或有机残基，np为2以上时，Y可以 彼此键合形成含有金属原子M），硫醇化合物和环硫化合物的环。
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4.发明申请公开(公告)号：US20130005934A1
公开(公告)日：2013-01-03
申请号：US13611773
申请日：2012-09-12
申请人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
发明人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
IPC分类号： C08G79/00
摘要： A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n−p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), a thiol compound and an episulfide compound.
摘要翻译： 一种包含由以下通式（1）表示的化合物的可聚合组合物：（式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m 表示0或1或更大的整数; p表示1至n的整数; n表示金属原子M的价数; Y各自独立地表示无机或有机残基，其中当n-p为2或更大时， Y可以彼此键合形成含有金属原子M），硫醇化合物和环硫化合物的环。
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5.发明申请公开(公告)号：US20100298519A1
公开(公告)日：2010-11-25
申请号：US12294683
申请日：2007-03-29
申请人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
发明人： Mitsuo Nakamura , Hiroshi Naruse , Atsuo Otsuji , Shinichi Usugi , Masao Imai , Hidetoshi Hayashi , Osamu Kohgo , Hideki Yamamoto , Seiichi Kobayashi
IPC分类号： C08G79/00
摘要： A polymerizable composition including a compound represented by following General Formula (1): (in Formula (1), M represents a metal atom; X1 and X2 each independently represents a sulfur atom or an oxygen atom; R1 represents a divalent organic group; m represents an integer of 0 or 1 or greater; p represents an integer of 1 to n; n represents a valence of a metal atom M; and Y's each independently represents an inorganic or organic residue, where when n-p is 2 or greater, Y's may be bonded to each other to form a ring containing a metal atom M), and a thiol compound.
摘要翻译： 一种包含由以下通式（1）表示的化合物的可聚合组合物：（式（1）中，M表示金属原子; X1和X2各自独立地表示硫原子或氧原子; R1表示二价有机基团; m 表示0或1以上的整数，p表示1〜n的整数，n表示金属原子M的化合价，Y表示各自独立地表示无机或有机残基，np为2以上时，Y可以 彼此键合形成含有金属原子M的环）和硫醇化合物。
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公开(公告)号：US20060003261A1
公开(公告)日：2006-01-05
申请号：US10522532
申请日：2003-07-17
申请人： Masao Imai , Mitsuo Nakamura , Hiroshi Naruse , Osamu Kohgo , Masahiro Enna , Atsuo Otsuji
发明人： Masao Imai , Mitsuo Nakamura , Hiroshi Naruse , Osamu Kohgo , Masahiro Enna , Atsuo Otsuji
IPC分类号： C08F2/46
CPC分类号： G02B1/041 , C08F22/105 , C08F222/1006 , C08L33/14 , H01L2224/48091 , H01L2224/48247 , H01L2224/73265 , H01L2924/181 , Y10T428/10 , Y10T428/1036 , Y10T428/105 , Y10T428/1059 , Y10T428/1073 , Y10T428/1082 , C08L41/00 , H01L2924/00014 , H01L2924/00012
摘要： A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound is characterized by comprising (a) a bifunctional (meth)acrylic acid (thio)ester compound containing a sulfur atom in the molecule and (b) at least one of a (meth)acrylic acid ester compound represented by the general formula (1) or a bifunctional (meth)acrylic acid ester compound having a urethane linkage: wherein R1 and R2 are each independently a hydrogen atom or a methyl group; R3 and R4 are each independently an alkyl group, an aralkyl group, an aryl group or a halogen atom; m and n are each an integer of 0 to 2; X1 is an alkylidene group having 1 to 3 carbon atoms; and Y1 and Y2 are each independently a poly(oxyalkylene) group with the proviso that at least one of Y1 and Y2 is a poly(oxyalkylene) group having a hydroxy group.
摘要翻译： 一种包含可聚合化合物和光聚合引发剂的可光聚合组合物，其中所述可聚合化合物的特征在于包含（a）分子中含有硫原子的双官能（甲基）丙烯酸（硫代）酯化合物和（b）至少一种 由通式（1）表示的（甲基）丙烯酸酯化合物或具有氨基甲酸酯键的双官能（甲基）丙烯酸酯化合物：其中R 1和R 2 各自独立地为氢原子或甲基; R 3和R 4各自独立地为烷基，芳烷基，芳基或卤素原子; m和n分别为0〜2的整数。 X 1是具有1至3个碳原子的亚烷基; 和Y 1和Y 2 2各自独立地是聚（氧化烯）基团，条件是Y 1和Y 3中的至少一个 > 2 是具有羟基的聚（氧化烯）基团。
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公开(公告)号：US06794471B2
公开(公告)日：2004-09-21
申请号：US09960308
申请日：2001-09-24
申请人： Tadashi Ohkuma , Masao Imai , Mitsuo Nakamura , Atsuo Otsuji
发明人： Tadashi Ohkuma , Masao Imai , Mitsuo Nakamura , Atsuo Otsuji
IPC分类号： C08F2038
CPC分类号： C07D409/04 , C07D339/06 , C08F20/38 , G02B1/04 , C08L33/14
摘要： An acrylic ester compound represented by the general formula (1): wherein, R1 and R2 represent independently a hydrogen atom, an alkyl group which may have a substituent, an aromatic alkyl group which may have a substituent or an aromatic residue which may have a substituent, respectively; R3 represents a hydrogen atom or an alkyl group; A represents a divalent organic group; and X represents a sulfur atom or an oxygen atom; provided that when X is an oxygen atom, R1 represents an aromatic residue that may have a substituent, a polymerizable composition comprising the compound, and a cured article and optical components obtained by polymerizing the polymerizable composition.
摘要翻译： 由通式（1）表示的丙烯酸酯化合物：其中，R 1和R 2分别独立地表示氢原子，可以具有取代基的烷基，可以具有取代基的芳香族烷基或可具有取代基的芳香族残基 取代基; R3表示氢原子或烷基; A表示二价有机基团; X表示硫原子或氧原子; 条件是当X是氧原子时，R 1表示可以具有取代基的芳族残基，包含该化合物的可聚合组合物和固化物以及通过使可聚合组合物聚合而获得的光学组分。
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公开(公告)号：US20080027198A1
公开(公告)日：2008-01-31
申请号：US11667227
申请日：2005-11-16
申请人： Hiroshi Naruse , Atsuo Otsuji , Mitsuo Nakamura
发明人： Hiroshi Naruse , Atsuo Otsuji , Mitsuo Nakamura
IPC分类号： C08G75/04 , C07C321/00 , C08G79/00 , G02B1/04 , C08G18/38
CPC分类号： C08G18/3874 , C08G18/3855 , C08G18/3863 , C08G18/3876 , C08G18/7642 , C08G18/791 , C08G18/8125 , C08G75/00 , C08G75/04 , C08G75/045 , C08G79/00
摘要： A compound having two or more thiol groups and an atom selected from metal atoms in a molecule, a polythiol composition containing such a compound, a polymerizable composition containing such a polythiol composition, a resin obtained by polymerization of such a polymerizable composition, and an optical component obtained from such a resin are provided. The polymerizable composition can be a raw material for a resin having high transparency, good heat resistance and mechanical strength required for optical components such as plastic lenses and the like, while attaining a high refractive index (nd) exceeding 1.7.
摘要翻译： 具有两个以上硫醇基和选自分子中的金属原子的原子的化合物，含有该化合物的多硫醇组合物，含有这种多硫醇组合物的聚合性组合物，通过聚合该聚合性组合物得到的树脂和光学 提供了由这种树脂获得的组分。 聚合性组合物可以是获得高于1.7的高折射率（nd）的树脂的原料，其具有高透明性，良好的耐热性和诸如塑料透镜等的光学部件所需的机械强度。
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公开(公告)号：US06570025B1
公开(公告)日：2003-05-27
申请号：US10048002
申请日：2002-01-25
申请人： Kenichi Fujii , Atsuo Otsuji , Masao Imai , Kenichi Sugimoto , Tadashi Okuma , Rihoko Suzuki , Keisuke Takuma
发明人： Kenichi Fujii , Atsuo Otsuji , Masao Imai , Kenichi Sugimoto , Tadashi Okuma , Rihoko Suzuki , Keisuke Takuma
IPC分类号： C07D33906
CPC分类号： C07D339/06 , C07D339/00 , C07D339/08 , C08F20/38
摘要： This invention provides sulfur-containing (meth)acrylic ester compounds each of which is represented by the following formula (1); wherein R1 and R2 each independently represent a hydrogen atom or an alkyl group or may be fused together to form a ring, R3 represents a hydrogen atom or a methyl group, X1 represents an oxygen atom or a sulfur atom, m stands for an integer of from 0 to 3, and n stands for an integer of from 1 to 4, polymerizable compositions comprising the sulfur-containing (meth)acrylic acids, and cured products and optical parts obtained by polymerizing the polymerizable compositions. The sulfur-containing (meth)acrylic ester compounds according to the present invention are very useful, as monomers for photocurable, polymerizable compositions, in applications such as optical materials and dental materials. The optical parts obtained by curing the polymerizable compositions are excellent in optical properties, thermal properties and mechanical properties and are also good in productivity.
摘要翻译： 本发明提供了各自由下式（1）表示的含硫（甲基）丙烯酸酯化合物，其中R 1和R 2各自独立地表示氢原子或烷基，或者可以一起稠合形成环，R 3 表示氢原子或甲基，X1表示氧原子或硫原子，m表示0〜3的整数，n表示1〜4的整数，包含含硫（ 甲基）丙烯酸，以及通过聚合可聚合组合物获得的固化产物和光学部件。 作为本发明的含硫（甲基）丙烯酸酯化合物，作为光固化性聚合性组合物的单体，在光学材料和牙科用材料等应用中是非常有用的。 通过固化可聚合组合物获得的光学部件的光学性能，热性能和机械性能优异，并且生产率也良好。
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公开(公告)号：US06320020B1
公开(公告)日：2001-11-20
申请号：US09389317
申请日：1999-09-03
申请人： Keisuke Takuma , Kenichi Sugimoto , Atsuo Otsuji , Rihoko Suzuki , Kenichi Fujii , Masao Imai
发明人： Keisuke Takuma , Kenichi Sugimoto , Atsuo Otsuji , Rihoko Suzuki , Kenichi Fujii , Masao Imai
IPC分类号： C08G7560
摘要： A sulfur-containing (thio)ether (co)polymer comprising repetitive structural units represented by general formulas 1 and 2, and an optical element using the (co)polymer: where A and B are bivalent organic group; R1 and R2 are hydrogen or alkyl; X1 to X4 are oxygen or sulfur; Y1 and Y2 are halogen, hydroxy, —OR3 or —SR4, in which R3 is sulfur-containing alkyl, aryl, heterocycle or acyl optionally having a substituent other than SH; and R4 is alkyl, aryl, heterocycle or acyl; provided that —OR3 and/or —SR4 constitute 10 to 100% of the total of Y1+Y2. The (co)polymer exhibits good optical, mechanical and thermal properties and a higher refractive index, and may be prepared in a good productivity. The sulfur-containing (thio)ether (co)polymer is useful for manufacturing a variety of optical elements.
摘要翻译： 包含由通式1和2表示的重复结构单元的含硫（硫）醚（共）聚合物和使用（共）聚合物的光学元件：其中A和B是二价有机基团; R1和R2是氢或烷基; X1至X4为氧或硫; Y1和Y2是卤素，羟基，-OR3或-SR4，其中R3是任选具有除SH以外的取代基的含硫烷基，芳基，杂环或酰基; 和R4是烷基，芳基，杂环或酰基; 条件是-OR3和/或-SR4构成Y1 + Y2总数的10〜100％。 （共）聚合物显示出良好的光学，机械和热性能以及更高的折射率，并且可以以良好的生产率制备。 含硫（硫）醚（共）聚合物可用于制造各种光学元件。
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