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公开(公告)号：US20090023948A1
公开(公告)日：2009-01-22
申请号：US11908720
申请日：2006-03-15
IPC分类号： C07C69/52
CPC分类号： C07C67/08 , C07C67/12 , C07C315/04 , C07C69/653 , C07C317/18
摘要： The present invention discloses a method for producing a fluorine-containing alkyl (meth)acrylate represented by the following general formula (2): Rf—(CH2)k-[-A-(CH2)l—]m—OCOCR═CH2 (2) (wherein R is a hydrogen atom or a methyl group), characterized by reacting a fluorine-containing alcohol represented by the following general formula (1): Rf—(CH2)k-[-A-(CH2)l—]m—OH (1) (wherein Rf is a perfluoroalkyl group having 1 to 21 carbon atoms; A is S, SO or SO2; k is 0, 1 or 2; 1 is k, 2 or 3; m is 0 or 1; however, a case of k=0 and m=0 is excluded), (meth)acrylic acid, and a sulfonic acid halide in the presence of a base containing at least one kind of tertiary amine.
摘要翻译： 本发明公开了由以下通式（2）表示的（甲基）丙烯酸烷基酯（甲基）丙烯酸酯的制造方法：＆lt;线内式记载=“在线式”末端=“铅”→Rf - （CH 2）k - [ - A-（CH 2）1 - ] m -OCOCR-CH 2（2）<β在线式描述=“在线式”末端=“尾”→（其中R是 氢原子或甲基），其特征在于使由以下通式（1）表示的含氟醇反应：<？in-line-formula description =“In-Line Formulas”end =“lead”→Rf - （CH 2）k - [ - A-（CH 2）1 - ] m -OH（1）<？在线公式描述=“在线公式”end =“尾”→（其中Rf是全氟烷基 具有1至21个碳原子的基团; A是S，SO或SO 2; k是0,1或2; 1是k，2或3; m是0或1;然而，在k = 0和m = 0的情况下 不包括），（甲基）丙烯酸和磺酰卤，在含有至少一种叔胺的碱的存在下。
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公开(公告)号：US07700800B2
公开(公告)日：2010-04-20
申请号：US11908720
申请日：2006-03-15
IPC分类号： C07C69/52
CPC分类号： C07C67/08 , C07C67/12 , C07C315/04 , C07C69/653 , C07C317/18
摘要： The present invention discloses a method for producing a fluorine-containing alkyl (meth)acrylate represented by the following general formula (2): Rf—(CH2)k-[-A-(CH2)l—]m—OCOCR═CH2 (2) (wherein R is a hydrogen atom or a methyl group), characterized by reacting a fluorine-containing alcohol represented by the following general formula (1): Rf—(CH2)k-[-A-(CH2)l—]m—OH (1) (wherein Rf is a perfluoroalkyl group having 1 to 21 carbon atoms; A is S, SO or SO2; k is 0, 1 or 2; l is 1, 2 or 3; m is 0 or 1; however, a case of k=0 and m=0 is excluded), (meth)acrylic acid, and a sulfonic acid halide in the presence of a base containing at least one kind of tertiary amine.
摘要翻译： 本发明公开了由以下通式（2）表示的含氟烷基（甲基）丙烯酸酯的制备方法：Rf-（CH 2）k - [ - A-（CH 2）1 - ] m -OCOCR = CH 2 2）（其中R是氢原子或甲基），其特征在于使由以下通式（1）表示的含氟醇：Rf-（CH 2）k - [ - A-（CH 2） m-OH（1）（其中Rf是具有1至21个碳原子的全氟烷基; A是S，SO或SO 2; k是0,1或2; l是1,2或3; m是0或1; 然而，在含有至少一种叔胺的碱的存在下，不包括k = 0和m = 0的情况），（甲基）丙烯酸和磺酰卤。
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公开(公告)号：US20080280808A1
公开(公告)日：2008-11-13
申请号：US11547127
申请日：2005-03-24
IPC分类号： C11D3/37 , C08F214/18
CPC分类号： C08F214/18 , C08F220/28 , D21H17/36 , D21H17/37 , D21H17/63 , D21H21/14
摘要： A stain remover which comprises a copolymer made from as essential ingredients (a) a polymerizable monomer having a polyfluoroalkyl group with less than 8 carbon atoms and represented by the general formula H2C═CXCOO—Y-Rf and (b) a fluorine-free polymerizable monomer represented by the following general formula: H2C═CXCOO—(RO)n—X. The stain remover is effective in minimizing the amount of an organic solvent to be used. It imparts to a substrate the excellent property of removing stains therefrom and a satisfactory texture.
摘要翻译： 一种去污剂，其包含由作为必要成分制备的共聚物（a）具有少于8个碳原子的多氟烷基并由通式H 2 C-CXCOO-Y-Rf表示的可聚合单体 和（b）由以下通式表示的无氟可聚合单体：H 2 C-CXCOO-（RO）n -X。 去污剂在最小化所用有机溶剂的量方面是有效的。 它赋予基材从其中除去污渍和令人满意的质感的优异性能。
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公开(公告)号：US07147669B2
公开(公告)日：2006-12-12
申请号：US10127501
申请日：2002-04-23
申请人： Fumihiko Yamaguchi , Ikuo Yamamoto , Kayo Kusumi
发明人： Fumihiko Yamaguchi , Ikuo Yamamoto , Kayo Kusumi
IPC分类号： D06M15/256 , D06M15/564 , C09D127/12
CPC分类号： D06M15/277 , D06M13/46 , D06M2200/11 , D06M2200/12 , Y10T428/23986 , Y10T442/2172
摘要： Excellent water repellency and Oil repellency are imparted to a textile by a method including (1) preparing a treatment liquid comprising a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent comprises at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains a cationic emulsifier and/or a salt.
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公开(公告)号：US20050234205A1
公开(公告)日：2005-10-20
申请号：US10516544
申请日：2003-06-12
IPC分类号： C08F220/22 , D21H17/37 , C08F12/20
CPC分类号： C08F220/22 , D21H17/37
摘要： A paper treatment agent which contains a copolymer essentially comprising a repeating unit derived from a polyfluoroalkyl group-containing (meth)acrylate, a repeating unit derived from a pyrrolidone monomer, a nitrogen-containing repeating unit such as —[CH2C(CH3)[COOCH2CH2CH2N+(CH3)3.Cl]]—, and an anionic functional group-containing repeating unit such as —[CH2C(CH3)COOH]— has a relatively low viscosity, and the action of the treatment agent hardly lowers even when a cationic paper strength-enhancing agent is used in combination therewith.
摘要翻译： 一种纸处理剂，其含有基本上包含衍生自含多氟烷基的（甲基）丙烯酸酯的重复单元，衍生自吡咯烷酮单体的重复单元，含氮重复单元如 - [CH 2] C（CH 3）3 CO 2 CH 2 CH 2 CH 2 N + （CH 3/3）3 Cl]] - 和含阴离子官能团的重复单元如 - [CH 2C≡C （CH 3 3 COOH） - 具有较低的粘度，即使与阳离子纸强度增强剂组合使用也不会降低处理剂的作用。
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公开(公告)号：US06472019B1
公开(公告)日：2002-10-29
申请号：US10094624
申请日：2002-03-12
申请人： Fumihiko Yamaguchi , Ikuo Yamamoto , Kayo Kusumi
发明人： Fumihiko Yamaguchi , Ikuo Yamamoto , Kayo Kusumi
IPC分类号： B05D302
CPC分类号： D06M15/277 , D06M13/262 , D06M15/248 , D06M15/263 , D06M15/3562 , D06M15/412 , D06M15/576 , D06M2200/11 , D06M2200/12
摘要： Excellent water repellency, Oil repellency, stain block property and yellowing-resistance are imparted to a textile by a method of preparing a treated textile has the steps of (1) preparing a treatment liquid containing a water- and oil-repellent agent and a stain blocking agent, (2) bringing a pH of the treatment liquid to at most 7, (3) applying the treatment liquid to the textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile. The treatment liquid contains a sulfated fatty acid compound.
摘要翻译： （1）制备含有拒油拒油剂和染色剂的处理液的步骤具有优异的防水性，拒油性，防污性和防黄变性， （2）将处理液的pH调至7以下，（3）将处理液施加到织物上，（4）用蒸汽处理纺织品，（5）用水洗涤纺织品，脱水 纺织品。 处理液含有硫酸化脂肪酸化合物。
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公开(公告)号：US07388104B2
公开(公告)日：2008-06-17
申请号：US10523518
申请日：2003-08-05
IPC分类号： C07C271/00 , D06M15/19
CPC分类号： C07D251/34 , C07C275/14 , C07D251/12 , D06M13/428 , D06M15/576 , D06M2200/11 , D06M2200/12
摘要： A fluorine-containing urethane compound of the general formula: [Rf-A1-(X1(OH))—(Y1)a—OC(═O)NH—]mI[—NHC(═O)O—Y2]n[—NHC(═O)O—((ClCH2—)X2O)b—R1]k (1) wherein I is a group remaining after an isocyanate group is removed from a polyisocyanate compound, Rf is a perfluoroalkyl group having 2 to 21 carbon atoms, A1 is a direct bond or a divalent organic group having 1 to 21 carbon atoms, X1 and X2 are trivalent linear or branched aliphatic group having 2 to 5 carbon atoms, Y1 is a divalent organic group having 0 to 5 carbon atoms and 0 to 2 nitrogen atoms (provided that at least one carbon atom or nitrogen atom is present) and at least one hydrogen atom, Y2 is a monovalent organic group optionally having a hydroxyl group, and R1 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, can impart high water- and oil-repellency.
摘要翻译： 具有以下通式的含氟氨基甲酸酯化合物：<？in-line-formula description =“In-line formula”end =“lead”？> [Rf-A 1 - （X “end =”tail“？>其中I是在从异氰酸酯化合物除去异氰酸酯基后残留的基团，Rf是具有2至21个碳原子的全氟烷基，A 1是直接键 或具有1至21个碳原子的二价有机基团，X 1和X 2是具有2至5个碳原子的三价直链或支链脂族基团，Y 1 是具有0至5个碳原子和0至2个氮原子的二价有机基团（条件是存在至少一个碳原子或氮原子）和至少一个氢原子，Y 2 O >是一种单价有机基团o 具有羟基，R 1是氢原子或具有1-10个碳原子的烷基，可以赋予高斥水斥油性。
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公开(公告)号：US06313357B1
公开(公告)日：2001-11-06
申请号：US09444401
申请日：1999-11-22
IPC分类号： C07C3134
CPC分类号： B01D61/362 , B01D61/364 , C07C29/76 , C07C29/82 , C07C31/38
摘要： In a method for recovering a fluoroalcohol from a mixture comprising a fluoroalcohol and water, (i) a method for recovering a fluoroalcohol by distilling the mixture comprising the fluoroalcohol and water to separate water as an azeotropic or azeotrope-like composition; and (ii) a method for recovering a fluoroalcohol, wherein water is separated by pervaporation.
摘要翻译： 在从包含氟代醇和水的混合物中回收氟代醇的方法中，（i）通过将包含氟代醇和水的混合物蒸馏以分离作为共沸或类共沸组合物的水来回收氟代醇的方法; 和（ii）回收氟代醇的方法，其中水通过渗透蒸发分离。
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公开(公告)号：US06303686B1
公开(公告)日：2001-10-16
申请号：US09147952
申请日：1999-05-19
IPC分类号： C08L2712
CPC分类号： C08L27/12 , C08L33/16 , C08L67/02 , C08L2666/04
摘要： The resin composition of the present invention comprises (a) a fluorine-free resin, (b) a fluorine-containing resin, and (c) a polyfluoroalkyl group-containing polymer, has excellent impact strength, and repels a flux.
摘要翻译： 本发明的树脂组合物包含（a）无氟树脂，（b）含氟树脂和（c）含多氟烷基的聚合物，具有优异的冲击强度，并排斥助熔剂。
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公开(公告)号：US06245953B1
公开(公告)日：2001-06-12
申请号：US09444402
申请日：1999-11-22
IPC分类号： C07C2976
摘要： In a method for recovering a fluorine-containing solvent from the mixture comprising the fluorine-containing solvent and dyes, (i) a method for recovering a fluorine-containing solvent by distillation; and (ii) a method for recovering a fluorine-containing solvent comprising the steps of adding to the mixture the second solvent which uniformly mixes with the fluorine-containing solvent but does not dissolve the dyes; separating a precipitate from the resulting mixture; and separating the second solvent.
摘要翻译： 在由含氟溶剂和染料的混合物中回收含氟溶剂的方法中，（i）通过蒸馏回收含氟溶剂的方法; 和（ii）回收含氟溶剂的方法，包括以下步骤：向混合物中加入与含氟溶剂均匀混合但不溶解染料的第二溶剂; 从所得混合物中分离出沉淀物; 并分离第二溶剂。
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