公开(公告)号：US07388104B2

公开(公告)日：2008-06-17

申请号：US10523518

申请日：2003-08-05

申请人： Ikuo Yamamoto ,  Kayo Kusumi ,  Takuya Yoshioka ,  Fumihiko Yamaguchi

发明人： Ikuo Yamamoto ,  Kayo Kusumi ,  Takuya Yoshioka ,  Fumihiko Yamaguchi

IPC分类号： C07C271/00 ,  D06M15/19

CPC分类号： C07D251/34 ,  C07C275/14 ,  C07D251/12 ,  D06M13/428 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12

摘要： A fluorine-containing urethane compound of the general formula: [Rf-A1-(X1(OH))—(Y1)a—OC(═O)NH—]mI[—NHC(═O)O—Y2]n[—NHC(═O)O—((ClCH2—)X2O)b—R1]k   (1) wherein I is a group remaining after an isocyanate group is removed from a polyisocyanate compound, Rf is a perfluoroalkyl group having 2 to 21 carbon atoms, A1 is a direct bond or a divalent organic group having 1 to 21 carbon atoms, X1 and X2 are trivalent linear or branched aliphatic group having 2 to 5 carbon atoms, Y1 is a divalent organic group having 0 to 5 carbon atoms and 0 to 2 nitrogen atoms (provided that at least one carbon atom or nitrogen atom is present) and at least one hydrogen atom, Y2 is a monovalent organic group optionally having a hydroxyl group, and R1 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, can impart high water- and oil-repellency.

摘要翻译： 具有以下通式的含氟氨基甲酸酯化合物：<？in-line-formula description =“In-line formula”end =“lead”？> [Rf-A 1 - （X ^{“end =”tail“？>其中I是在从异氰酸酯化合物除去异氰酸酯基后残留的基团，Rf是具有2至21个碳原子的全氟烷基，A 1是直接键 或具有1至21个碳原子的二价有机基团，X 1和X 2是具有2至5个碳原子的三价直链或支链脂族基团，Y 1 是具有0至5个碳原子和0至2个氮原子的二价有机基团（条件是存在至少一个碳原子或氮原子）和至少一个氢原子，Y 2 O >是一种单价有机基团o 具有羟基，R 1是氢原子或具有1-10个碳原子的烷基，可以赋予高斥水斥油性。}

公开(公告)号：US20060091351A1

公开(公告)日：2006-05-04

申请号：US10523518

申请日：2003-08-05

申请人： Ikuo Yamamoto ,  Kayo Kusumi ,  Takuya Yoshioka ,  Fumihiko Yamaguchi

发明人： Ikuo Yamamoto ,  Kayo Kusumi ,  Takuya Yoshioka ,  Fumihiko Yamaguchi

IPC分类号： D06M15/263 ,  C07C271/20

CPC分类号： C07D251/34 ,  C07C275/14 ,  C07D251/12 ,  D06M13/428 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12

摘要： A fluorine-containing urethane compound of the general formula: [Rf-A1-(X1(OH))—(Y1)a—OC(═O)NH—]m I [—NHC(═O)O—Y2]n[—NHC(═O)O—((ClCH2—)X2O)b—R1]k   (1) wherein I is a group remaining after an isocyanate group is removed from a polyisocyanate compound, Rf is a perfluoroalkyl group having 2 to 21 carbon atoms, A1 is a direct bond or a divalent organic group having 1 to 21 carbon atoms, X1 and X2 are trivalent linear or branched aliphatic group having 2 to 5 carbon atoms, Y1 is a divalent organic group having 0 to 5 carbon atoms and 0 to 2 nitrogen atoms (provided that at least one carbon atom or nitrogen atom is present) and at least one hydrogen atom, Y2 is a monovalent organic group optionally having a hydroxyl group, and R1 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms, can impart high water- and oil-repellency.

摘要翻译： 具有以下通式的含氟氨基甲酸酯化合物：<？in-line-formula description =“In-line formula”end =“lead”？> [Rf-A 1 - （X ^{“end =”tail“？>其中I是在从异氰酸酯化合物除去异氰酸酯基后残留的基团，Rf是具有2至21个碳原子的全氟烷基，A 1是直接键 或具有1至21个碳原子的二价有机基团，X 1和X 2是具有2至5个碳原子的三价直链或支链脂族基团，Y 1 是具有0至5个碳原子和0至2个氮原子的二价有机基团（条件是存在至少一个碳原子或氮原子）和至少一个氢原子，Y 2 O >是一价有机g 任选具有羟基的醇，R 1是氢原子或具有1-10个碳原子的烷基，可以赋予高斥水斥油性。}

公开(公告)号：US06740357B2

公开(公告)日：2004-05-25

申请号：US10327190

申请日：2002-12-24

申请人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

发明人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

IPC分类号： B05D310

CPC分类号： D06N3/047 ,  D06M15/277 ,  D06M15/564 ,  D06M15/576 ,  D06M15/6433 ,  D06M15/6436 ,  D06M15/65 ,  D06M2200/11 ,  D06M2200/12 ,  D06N3/007 ,  D06N3/128 ,  D06N3/14

摘要： A method of preparing a treated textile, having steps of: (1) preparing a treatment liquid comprising a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent contains (A) a fluorine-containing compound which is a fluorine-containing polymer, and (B) a urethane compound and/or (C) a silicon-containing compound, can give a textile which is excellent in water repellency, oil repellency and soil releasability, when the textile is treated with the treatment liquid by an Exhaust process.

摘要翻译： 一种制备经处理的织物的方法，具有以下步骤：（1）制备包含拒水拒油剂的处理液，（2）将处理液的pH调节至至多7，（3）施加处理液 纺织品，（4）用蒸汽处理织物，（5）用水洗涤织物并使织物脱水，其中防水防油剂含有（A）含氟化合物， （B）氨基甲酸酯化合物和/或（C）含硅化合物可以得到当织物用处理液处理时具有优异的防水性，拒油性和污垢释放性的织物 排气过程。

公开(公告)号：US07147669B2

公开(公告)日：2006-12-12

申请号：US10127501

申请日：2002-04-23

申请人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

发明人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

IPC分类号： D06M15/256 ,  D06M15/564 ,  C09D127/12

CPC分类号： D06M15/277 ,  D06M13/46 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/23986 ,  Y10T442/2172

摘要： Excellent water repellency and Oil repellency are imparted to a textile by a method including (1) preparing a treatment liquid comprising a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent comprises at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains a cationic emulsifier and/or a salt.

公开(公告)号：US06472019B1

公开(公告)日：2002-10-29

申请号：US10094624

申请日：2002-03-12

申请人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

发明人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

IPC分类号： B05D302

CPC分类号： D06M15/277 ,  D06M13/262 ,  D06M15/248 ,  D06M15/263 ,  D06M15/3562 ,  D06M15/412 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12

摘要： Excellent water repellency, Oil repellency, stain block property and yellowing-resistance are imparted to a textile by a method of preparing a treated textile has the steps of (1) preparing a treatment liquid containing a water- and oil-repellent agent and a stain blocking agent, (2) bringing a pH of the treatment liquid to at most 7, (3) applying the treatment liquid to the textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile. The treatment liquid contains a sulfated fatty acid compound.

摘要翻译： （1）制备含有拒油拒油剂和染色剂的处理液的步骤具有优异的防水性，拒油性，防污性和防黄变性， （2）将处理液的pH调至7以下，（3）将处理液施加到织物上，（4）用蒸汽处理纺织品，（5）用水洗涤纺织品，脱水 纺织品。 处理液含有硫酸化脂肪酸化合物。

公开(公告)号：US07717963B2

公开(公告)日：2010-05-18

申请号：US11546301

申请日：2006-10-12

申请人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

发明人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

IPC分类号： D06M15/256 ,  C09D127/12

CPC分类号： D06M15/277 ,  D06M13/46 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/23986 ,  Y10T442/2172

摘要： Excellent water repellency and Oil repellency are imparted to a textile by a method including (1) preparing a treatment liquid comprising a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent comprises at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains a cationic emulsifier and/or a salt.

摘要翻译： 通过以下方法赋予纺织品优异的防水性和拒油性，该方法包括：（1）制备包含拒水拒油剂的处理液，（2）将处理液的pH调节至7以下，（3）施加 将处理液转移到织物上，（4）用蒸汽处理织物，（5）用水洗涤织物并使织物脱水，其中防水防油剂包含至少一种选自以下的含氟化合物： 由含氟聚合物和含氟低分子化合物组成的组，防水防油剂或处理液含有阳离子乳化剂和/或盐。

公开(公告)号：US20070028395A1

公开(公告)日：2007-02-08

申请号：US11546301

申请日：2006-10-12

申请人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

发明人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Kayo Kusumi

IPC分类号： C11D3/00

CPC分类号： D06M15/277 ,  D06M13/46 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/23986 ,  Y10T442/2172

摘要： Excellent water repellency and Oil repellency are imparted to a textile by a method including (1) preparing a treatment liquid comprising a water- and oil-repellent agent, (2) adjusting pH of the treatment liquid to at most 7, (3) applying the treatment liquid to a textile, (4) treating the textile with steam, and (5) washing the textile with water and dehydrating the textile, wherein the water- and oil-repellent agent comprises at least one fluorine-containing compound selected from the group consisting of a fluorine-containing polymer and a fluorine-containing low molecular weight compound, and the water- and oil-repellent agent or the treatment liquid contains a cationic emulsifier and/or a salt.

摘要翻译： 通过以下方法赋予纺织品优异的防水性和拒油性，该方法包括：（1）制备包含拒水拒油剂的处理液，（2）将处理液的pH调节至7以下，（3）施加 将处理液转移到织物上，（4）用蒸汽处理织物，（5）用水洗涤织物并使织物脱水，其中防水防油剂包含至少一种选自以下的含氟化合物： 由含氟聚合物和含氟低分子化合物组成的组，防水防油剂或处理液含有阳离子乳化剂和/或盐。

公开(公告)号：US06833082B2

公开(公告)日：2004-12-21

申请号：US10058376

申请日：2002-01-30

申请人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Teruyuki Fukuda ,  Kayo Kusumi

发明人： Fumihiko Yamaguchi ,  Ikuo Yamamoto ,  Teruyuki Fukuda ,  Kayo Kusumi

IPC分类号： D06M1555

CPC分类号： D06M15/263 ,  D06M11/56 ,  D06M11/66 ,  D06M13/188 ,  D06M13/2243 ,  D06M13/262 ,  D06M15/412 ,  D06M2200/25 ,  Y10T428/23986

摘要： Excellent stain block property, WAQE resistance and yellowing resistance are imparted to a textile by a method of preparing a treated textile has the steps of (1) preparing a treatment liquid comprising a stain blocking agent and a sulfated castor oil and having pH of at most 7, (2) applying the treatment liquid to the textile, (3) treating the textile with steam, and (4) washing the textile with water and dehydrating the textile.

摘要翻译： 通过制备经处理的织物的方法赋予纺织品优异的防污性，耐WAQE性和耐黄变性，具有以下步骤：（1）制备包含防污剂和硫酸化蓖麻油并具有最多pH值的处理液 7，（2）将处理液施加到纺织品上，（3）用蒸汽处理织物，（4）用水洗涤织物并使织物脱水。

公开(公告)号：US6019909A

公开(公告)日：2000-02-01

申请号：US492041

申请日：1995-07-21

申请人： Satoshi Ide ,  Katsuki Fujiwara ,  Masayuki Yamana ,  Yoshitaka Honda ,  Ikuo Yamamoto ,  Fumihiko Yamaguchi ,  Eiji Seki ,  Tatsuya Otsuka ,  Satoshi Ishida

发明人： Satoshi Ide ,  Katsuki Fujiwara ,  Masayuki Yamana ,  Yoshitaka Honda ,  Ikuo Yamamoto ,  Fumihiko Yamaguchi ,  Eiji Seki ,  Tatsuya Otsuka ,  Satoshi Ishida

IPC分类号： C07C41/06 ,  C07C43/12 ,  C07C43/13 ,  C07C43/17 ,  C07C43/178 ,  C07C43/225 ,  C07C43/317 ,  C08G65/00 ,  C08G65/22 ,  C08G65/26 ,  C09K5/04 ,  C10M105/54 ,  C10M105/72 ,  C10M105/74 ,  C10M107/38 ,  C10M107/46 ,  C10M171/00 ,  C10N40/14 ,  C10N40/30 ,  G11B5/71 ,  G11B5/725

CPC分类号： C07C43/12 ,  C07C43/126 ,  C07C43/137 ,  C07C43/17 ,  C07C43/178 ,  C07C43/1786 ,  C07C43/225 ,  C07C43/317 ,  C08G65/007 ,  C08G65/226 ,  C08G65/2639 ,  C09K5/044 ,  C09K5/045 ,  C10M105/54 ,  C10M105/72 ,  C10M105/74 ,  C10M107/38 ,  C10M107/46 ,  C10M171/008 ,  G11B5/71 ,  G11B5/725 ,  C09K2205/22 ,  C09K2205/24 ,  C10M2211/022 ,  C10M2211/042 ,  C10M2211/06 ,  C10M2213/00 ,  C10M2213/04 ,  C10M2213/06 ,  C10M2219/082 ,  C10M2223/06 ,  C10M2223/061 ,  C10N2240/00 ,  C10N2240/20 ,  C10N2240/201 ,  C10N2240/202 ,  C10N2240/203 ,  C10N2240/204 ,  C10N2240/205 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66

摘要： A novel fluorinated hydrocarbon compound containing an oxygen or sulfur atom in its molecule, produced by the nucleophilic reaction of a fluorine compound with a hydrocarbon compound. This compound is useful as a lubricant for various applications and particularly excellent as an oil for refrigerators wherein hydrochlorofluorocarbon is used as the refrigerant and as a magnetic recording medium lubricant.

摘要翻译： PCT No.PCT / JP94 / 00084 Sec。 371日期1995年7月21日 102（e）日期1995年7月21日PCT 1991年1月21日PCT PCT。 第WO94 / 17023号公报 日期：1994年8月4日一种通过氟化合物与烃化合物的亲核反应产生的分子中含有氧或硫原子的新型氟化烃化合物。 该化合物可用作各种用途的润滑剂，特别优选用作其中使用氢氯氟烃作为制冷剂的冰箱和作为磁记录介质润滑剂的油。

公开(公告)号：US20090023948A1

公开(公告)日：2009-01-22

申请号：US11908720

申请日：2006-03-15

申请人： Masao Yamaguchi ,  Fumihiko Yamaguchi

发明人： Masao Yamaguchi ,  Fumihiko Yamaguchi

IPC分类号： C07C69/52

CPC分类号： C07C67/08 ,  C07C67/12 ,  C07C315/04 ,  C07C69/653 ,  C07C317/18

摘要： The present invention discloses a method for producing a fluorine-containing alkyl (meth)acrylate represented by the following general formula (2): Rf—(CH2)k-[-A-(CH2)l—]m—OCOCR═CH2  (2) (wherein R is a hydrogen atom or a methyl group), characterized by reacting a fluorine-containing alcohol represented by the following general formula (1): Rf—(CH2)k-[-A-(CH2)l—]m—OH  (1) (wherein Rf is a perfluoroalkyl group having 1 to 21 carbon atoms; A is S, SO or SO2; k is 0, 1 or 2; 1 is k, 2 or 3; m is 0 or 1; however, a case of k=0 and m=0 is excluded), (meth)acrylic acid, and a sulfonic acid halide in the presence of a base containing at least one kind of tertiary amine.

摘要翻译： 本发明公开了由以下通式（2）表示的（甲基）丙烯酸烷基酯（甲基）丙烯酸酯的制造方法：＆lt;线内式记载=“在线式”末端=“铅”→Rf - （CH 2）k - [ - A-（CH 2）1 - ] m -OCOCR-CH 2（2）<β在线式描述=“在线式”末端=“尾”→（其中R是 氢原子或甲基），其特征在于使由以下通式（1）表示的含氟醇反应：<？in-line-formula description =“In-Line Formulas”end =“lead”→Rf - （CH 2）k - [ - A-（CH 2）1 - ] m -OH（1）<？在线公式描述=“在线公式”end =“尾”→（其中Rf是全氟烷基 具有1至21个碳原子的基团; A是S，SO或SO 2; k是0,1或2; 1是k，2或3; m是0或1;然而，在k = 0和m = 0的情况下 不包括），（甲基）丙烯酸和磺酰卤，在含有至少一种叔胺的碱的存在下。