公开(公告)号：US3984496A

公开(公告)日：1976-10-05

申请号：US521086

申请日：1974-11-05

申请人： Masayoshi Morimoto ,  Tetsutaro Sanjiki ,  Hideki Horiike ,  Takeo Oyamada

发明人： Masayoshi Morimoto ,  Tetsutaro Sanjiki ,  Hideki Horiike ,  Takeo Oyamada

IPC分类号： C08F255/02 ,  C08F255/04 ,  C08F255/06

CPC分类号： C08F255/02

摘要： A binary or ternary graft-copolymer excellent in both tensile strength and impact resistance is obtained by the process for producing a binary or ternary graft-copolymer consisting essentially of an ethylene-propylene rubber and an aromatic vinyl compound or of an ethylene-propylene rubber, an aromatic vinyl compound, and a vinyl cyanide compound, characterized by subjecting these materials to solution polymerization in a mixed solvent comprising an aliphatic hydrocarbon solvent capable of dissolving the ethylene-propylene rubber and a polar solvent capable of dissolving a poly-(aromatic vinyl compound) or a copolymer of the aromatic vinyl compound and the vinyl cyanide compound.

摘要翻译： 通过生产基本上由乙丙橡胶和芳族乙烯基化合物或乙丙橡胶组成的二元或三元接枝共聚物的方法，可获得拉伸强度和抗冲击性均优异的二元或三元接枝共聚物， 芳族乙烯基化合物和乙烯基氰化合物，其特征在于将这些材料在包含能够溶解乙丙橡胶的脂族烃溶剂和能够溶解聚（芳族乙烯基化合物）的极性溶剂的混合溶剂中进行溶液聚合 ）或芳香族乙烯基化合物与乙烯基氰化合物的共聚物。

公开(公告)号：US4089913A

公开(公告)日：1978-05-16

申请号：US662019

申请日：1976-02-27

申请人： Tamotsu Miki ,  Shizuo Narisawa ,  Ichiro Ichikawa ,  Hideki Horiike

发明人： Tamotsu Miki ,  Shizuo Narisawa ,  Ichiro Ichikawa ,  Hideki Horiike

IPC分类号： C08F297/04

CPC分类号： C08F297/04

摘要： In block-copolymerizing a vinyl aromatic compound and a conjugated diene in a hydrocarbon solvent using an organolithium compound as initiator, a transparent block copolymer resin characterized by having elastomeric random copolymer blocks may be produced by continuously adding a mixture of the vinyl aromatic compound and the conjugated diene. The block copolymer resin thus obtained is transparent, excellent in mechanical characteristics and may be used in the fields of sheetings, films, and various molded articles.

摘要翻译： 使用有机锂化合物作为引发剂在烃溶剂中使乙烯基芳族化合物和共轭二烯嵌段共聚，可以通过连续地加入乙烯基芳族化合物和 共轭二烯。 由此获得的嵌段共聚物树脂是透明的，机械性能优异，可用于片材，薄膜和各种模制品领域。

公开(公告)号：US4054616A

公开(公告)日：1977-10-18

申请号：US685129

申请日：1976-05-10

申请人： Tamotsu Miki ,  Shizuo Narisawa ,  Ichiro Ichikawa ,  Hideki Horiike

发明人： Tamotsu Miki ,  Shizuo Narisawa ,  Ichiro Ichikawa ,  Hideki Horiike

IPC分类号： C08F297/04 ,  C08L9/06

CPC分类号： C08F297/04

摘要： A block copolymer resin having at one or both ends a copolymer block of a vinyl aromatic compound and a conjugated diene is obtained by subjecting a vinyl aromatic compound and a conjugated diene to 2- or 3-stage block copolymerization in a hydrocarbon solvent in the presence of a definite amount of a Lewis base compound using an organolithium compound as an initiator. The block copolymer resin is high in transparency and excellent in mechanical properties, and is successfully usable in the fields of sheets, films and various molded articles.

摘要翻译： 在一端或两端具有乙烯基芳族化合物和共轭二烯的共聚物嵌段的嵌段共聚物树脂通过在烃溶剂中在乙烯基芳族化合物和共轭二烯存在下进行2-或3-阶段的嵌段共聚合获得 使用有机锂化合物作为引发剂的一定量的路易斯碱化合物。 嵌段共聚物树脂的透明性高，机械性能优异，成功地用于片材，薄膜和各种成型品领域。

公开(公告)号：US4220738A

公开(公告)日：1980-09-02

申请号：US890942

申请日：1978-03-28

申请人： Tamotsu Miki ,  Shizuo Narisawa ,  Hideki Horiike ,  Ichiro Ichikawa

发明人： Tamotsu Miki ,  Shizuo Narisawa ,  Hideki Horiike ,  Ichiro Ichikawa

IPC分类号： C08F297/04 ,  C08F293/00

CPC分类号： C08F297/04

摘要： By block-copolymerizing a mixture of an aromatic vinyl compound and a conjugated diene in two stages in an aliphatic hydrocarbon solvent, using an organomonolithium compound or an organodilithium compound as a polymerization initiator, a block copolymer is formed as a suspension polymer in a slurry state.The resulting block copolymer is very clear and excellent in mechanical properties, especially, strength, elongation and impact strength. It has a wide application in the field of general resins.

摘要翻译： 通过使用有机锂化合物或有机锂化合物作为聚合引发剂，将芳香族乙烯基化合物和共轭二烯的混合物分两个阶段进行脂肪族烃溶剂的嵌段共聚，形成作为悬浮聚合物的淤浆状态的嵌段共聚物 。 所得嵌段共聚物的机械性能，特别是强度，伸长率和冲击强度非常透明和优异。 它在普通树脂领域有广泛的应用。

公开(公告)号：US4122134A

公开(公告)日：1978-10-24

申请号：US827079

申请日：1977-08-23

申请人： Tamotsu Miki ,  Shizuo Narisawa ,  Ichiro Ichikawa ,  Hideki Horiike

发明人： Tamotsu Miki ,  Shizuo Narisawa ,  Ichiro Ichikawa ,  Hideki Horiike

IPC分类号： C08F297/04

CPC分类号： C08F297/04

摘要： By block-copolymerizing a vinyl aromatic compound and a conjugated diene in a hydrocarbon solvent with an organolithium compound as initiator, there is obtained a block copolymer which comprises in the molecule three blocks of homopolymerized vinyl aromatic compound, randomly copolymerized vinyl aromatic compound and conjugated diene, and homopolymerized diene, respectively. The resulting block copolymer is transparent and excellent in mechanical properties, and is suitable for use in the manufacture of sheeting, film, and various molded articles.

摘要翻译： 通过在有机锂化合物作为引发剂的烃溶剂中使乙烯基芳族化合物和共轭二烯嵌段共聚合得到嵌段共聚物，该共聚物在该分子中包含三个均聚乙烯基芳族化合物的嵌段，无规共聚的乙烯基芳族化合物和共轭二烯 ，和均聚二烯。 所得的嵌段共聚物是透明的，机械性能优异，适用于片材，薄膜和各种模塑制品的制造。