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    Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative
    1.
    发明授权
    Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative 有权
    含有3-杂环基取代的苯甲酰基衍生物的除草混合物

    公开(公告)号：US06479437B1

    公开(公告)日：2002-11-12

    申请号：US09701875

    申请日：2000-12-05

    申请人： Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler

    发明人： Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler

    IPC分类号： A01N4356

    CPC分类号： C05G3/02 ,  A01N43/78 ,  A01N43/80 ,  A01N2300/00

    摘要： A herbicidal mixture comprising a) a herbicidally active amount of a 3-heterocyclyl-substituted benzoyl derivative of the formula I  in which the variables have the following meanings: R1,R2 are hydrogen, halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy; R3 is hydrogen, halogen, C1-C6-alkyl; X is a heterocycle from amongst the group consisting of isoxazolyl, 4,5-dihydroisoxazolyl and thiazolyl, it being possible for the heterocycle to be optionally monosubstituted or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R5 is hydrogen or C1-C6-alkyl, R6 is C1-C6-alkyl, or their environmentally compatible salts; b) a nitrogenous fertilizer in a synergistically effective amount and c) an adjuvant in a synergistically effective amount.

    摘要翻译： 一种除草混合物，其包含a）除草活性量的式I的3-杂环基取代的苯甲酰基衍生物，其中所述变量具有以下含义：R 1，R 2是氢，卤素，C 1 -C 6 - 烷基，C 1 -C 6 - 烷硫基 ，C 1 -C 6烷基亚磺酰基，C 1 -C 6烷基磺酰基，C 1 -C 6卤代烷基，C 1 -C 6 - 烷氧基，C 1 -C 6卤代烷氧基; R 3是氢，卤素，C 1 -C 6烷基; X是 由异唑基，4,5-二氢异恶唑基和噻唑基组成的组，可以将杂环任选被卤素，C 1 -C 6 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基; R 5是氢或C 1 -C 6烷基，R 6是C 1 -C 6 - 烷基或其环境相容的盐; b）具有协同有效量的含氮肥料，和c）协同有效的佐剂 量。

    Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative and an adjuvant
    2.
    发明授权
    Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative and an adjuvant 有权
    含有3-杂环基取代的苯甲酰基衍生物和佐剂的除草混合物

    公开(公告)号：US06514910B1

    公开(公告)日：2003-02-04

    申请号：US09914873

    申请日：2001-09-05

    申请人： Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler ,  Herve Vantieghem

    发明人： Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler ,  Herve Vantieghem

    IPC分类号： A01N4378

    CPC分类号： A01N43/78 ,  A01N43/80 ,  A01N37/06 ,  A01N37/02 ,  A01N25/30 ,  A01N2300/00

    摘要： A herbicidal mixture, comprising a) a herbicidally effective amount of a benzoyl compound of formula I  where: R1, R2 are halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkyl-sulfinyl or C1-C6-alkylsulfonyl; R3 is hydrogen, halogen, C1-C6-alkyl; X is 4,5-dihydroisoxazolyl which is unsubstituted or mono- or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R4 is a pyrazole of the formula II  which is attached in the 4-position and where R5 is hydrogen, R6 is methyl, or an environmentally compatible salt thereof; b) an adjuvant comprising i) a C1-C5-alkyl C5-C22-alkanoate, ii) a C10-C20-carboxylic acid, iii) a partial phosphoric ester or a partial sulfuric ester of a monohydroxy-functional polyalkyl ether and iv) optionally an alkyl polyoxyalkylene polyether, wherein the compound of formula I and the adjuvat are present in synergistically effective amounts.

    摘要翻译： 一种除草混合物，其包含a）除草有效量的式I的苯甲酰基化合物，其中：R 1，R 2是卤素，C 1 -C 6烷基，C 1 -C 6烷硫基，C 1 -C 6烷基亚磺酰基或C 1 -C 6烷基磺酰基 R 3是氢，卤素，C 1 -C 6 - 烷基; X是未被取代或被卤素，C 1 -C 6烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷基，C 1 -C 6 - 烷氧基取代或被单取代或多取代的4,5-二氢异恶唑基 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基; R 4是连接在4-位的式II的吡唑，其中R 5是氢，R 6是甲基或其环境相容的盐; b）佐剂，其包含：i） C1-C5烷基C5-C22-链烷酸酯，ii）C10-C20羧酸，iii）部分磷酸酯或单羟基官能聚烷基醚的部分硫酸酯，和/或任选的烷基聚氧化烯聚醚，其中化合物 并且佐剂以协同有效量存在。

    Synergistically acting herbicidal mixtures
    4.
    发明申请
    Synergistically acting herbicidal mixtures 有权
    协同作用的除草混合物

    公开(公告)号：US20050239653A1

    公开(公告)日：2005-10-27

    申请号：US11079431

    申请日：2005-03-14

    申请人： Bernd Sievernich ,  Max Landes ,  Elmar Kibler ,  Wolfgang Deyn ,  Helmut Walter ,  Martina Otten ,  Karl-Otto Westphalen ,  Herve Vantieghem

    发明人： Bernd Sievernich ,  Max Landes ,  Elmar Kibler ,  Wolfgang Deyn ,  Helmut Walter ,  Martina Otten ,  Karl-Otto Westphalen ,  Herve Vantieghem

    IPC分类号： A01N43/40 ,  A01N43/72 ,  A01N43/78 ,  A01N43/80 ,  A01N57/00 ,  A01N61/00

    CPC分类号： A01N43/78 ,  A01N43/80 ,  A01N61/00 ,  A01N57/20 ,  A01N47/36 ,  A01N47/30 ,  A01N47/12 ,  A01N47/06 ,  A01N43/90 ,  A01N43/88 ,  A01N43/82 ,  A01N43/76 ,  A01N43/707 ,  A01N43/70 ,  A01N43/653 ,  A01N43/58 ,  A01N43/54 ,  A01N43/50 ,  A01N43/42 ,  A01N43/40 ,  A01N43/18 ,  A01N39/04 ,  A01N41/10 ,  A01N37/48 ,  A01N37/46 ,  A01N37/40 ,  A01N37/26 ,  A01N37/22 ,  A01N37/18 ,  A01N37/12 ,  A01N2300/00

    摘要： A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are hydrogen, halogen, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a heterocyclic radical selected from the group: thiazol-2-yl, thiazol-4-yl, thiazol-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl, it being possible for these to be unsubstituted or mono- or polysubstituted by halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or alkylthio; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) a synergistically effective amount of at least one herbicidal compound from the group of the acetyl-CoA carboxylase inhibitors (ACC), acetolactate synthase inhibitors (ALS), amides, auxin herbicides, auxin transport inhibitors, carotenoid biosynthesis inhibitors, enolpyruvylshikimate-3-phosphate synthase inhibitors (ESPS), glutamine synthetase inhibitors, lipid biosynthesis inhibitors, mitosis inhibitors, protophorphyrinogen [sic ] IX oxidase inhibitors, photosynthesis inhibitors, synergists, growth substances, cell wall biosynthesis inhibitors and a variety of other herbicides. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.

    摘要翻译： 一种协同除草混合物，其包含A）至少一种式I的3-杂环基取代的苯甲酰基衍生物，其中变量具有以下含义：R 1，R 3， 氢，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基亚磺酰基或烷基磺酰基; R 2是选自以下的杂环基：噻唑-2-基，噻唑-4-基，噻唑-5-基，异恶唑-3-基，异恶唑-4-基，异恶唑-4-基， 5,5-二氢异恶唑-3-基，4,5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基，这些可能是未被取代的或被卤素单取代或多取代， 烷基，烷氧基，卤代烷基，卤代烷氧基或烷硫基; R 4是氢，卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 乙酰辅酶A羧化酶抑制剂（ACC），乙酰乳酸合酶抑制剂（ALS），酰胺，生长素除草剂，生长素转运抑制剂，类胡萝卜素生物合成抑制剂，烯醇丙酮酸莽草酸-3（3）的协同有效量的至少一种除草化合物 磷酸合成酶抑制剂（ESPS），谷氨酰胺合成酶抑制剂，脂质生物合成抑制剂，有丝分裂抑制剂，原卟啉原IX氧化酶抑制剂，光合作用抑制剂，增效剂，生长物质，细胞壁生物合成抑制剂和各种其它除草剂。 包含这些混合物的组合物，这些组合物的制备方法以及它们用于控制不期望的植物的用途。

    Non-aqueous active ingredient concentrates having an herbicidal effect
    7.
    发明授权
    Non-aqueous active ingredient concentrates having an herbicidal effect 有权

    公开(公告)号：US09826739B2

    公开(公告)日：2017-11-28

    申请号：US12376320

    申请日：2007-08-03

    申请人： Michael Krapp ,  Rainer Berghaus ,  Matthias Bratz ,  Elmar Kibler ,  Herve R. Vantieghem

    发明人： Michael Krapp ,  Rainer Berghaus ,  Matthias Bratz ,  Elmar Kibler ,  Herve R. Vantieghem

    IPC分类号： A01N43/80 ,  A01N43/56 ,  A01N43/10 ,  A01N25/02 ,  A01N25/30

    CPC分类号： A01N43/56 ,  A01N25/02 ,  A01N25/30 ,  A01N43/10 ,  A01N43/80 ,  A01N2300/00

    摘要： The present invention relates to active compound concentrates having herbicidal action, comprising a) from 10 to 100 g/l of at least one 4-benzoyl-substituted pyrazole compound of the formula I in which R1, R3 independently of one another are hydrogen, halogen, methyl, halomethyl, methoxy, halomethoxy, methylthio, methylsulfinyl or methylsulfonyl; R2 is a 5-membered heterocyclic radical which is unsubstituted or carries 1, 2, 3 or 4 substituents selected from the group consisting of halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy and C1-C4-alkylthio; R4 is hydrogen, halogen or methyl; R5 is C1-C6-alkyl, C3-C6-cycloalkyl or C3-C6-cycloalkylmethyl; and R6 is hydrogen or C1-C4-alkyl; or one of its agriculturally useful salts, b) from 200 to 700 g/l of 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide, and c) from 10 to 200 g/l of at least one surfactant S selected from a mixture of at least one anionic surfactant and at least one nonionic surfactant, where the components a), b) and c) are present dissolved in a mixture of organic solvents consisting to at least 95% by weight, based on the solvent mixture, of d1) at least one aprotic polar organic solvent having a miscibility with water at 25° C. and 1 bar of at least 50 g/l, and d2) at least one organic solvent having a solubility in water at 25° C. and 1 bar of less than 5 g/l.

    NON-AQUEOUS ACTIVE INGREDIENT CONCENTRATES HAVING AN HERBICIDAL EFFECT
    8.
    发明申请
    NON-AQUEOUS ACTIVE INGREDIENT CONCENTRATES HAVING AN HERBICIDAL EFFECT 有权
    具有除草效果的非水性活性成分浓度

    公开(公告)号：US20100227763A1

    公开(公告)日：2010-09-09

    申请号：US12376320

    申请日：2007-08-03

    申请人： Michael Krapp ,  Rainer Berghaus ,  Matthias Bratz ,  Elmar Kibler ,  Herve R. Vantieghem

    发明人： Michael Krapp ,  Rainer Berghaus ,  Matthias Bratz ,  Elmar Kibler ,  Herve R. Vantieghem

    IPC分类号： A01N43/56

    CPC分类号： A01N43/56 ,  A01N25/02 ,  A01N25/30 ,  A01N43/10 ,  A01N43/80 ,  A01N2300/00

    摘要： The present invention relates to active compound concentrates having herbicidal action, comprising a) from 10 to 100 g/l of at least one 4-benzoyl-substituted pyrazole compound of the formula I in which R1, R3 independently of one another are hydrogen, halogen, methyl, halomethyl, methoxy, halomethoxy, methylthio, methylsulfinyl or methylsulfonyl; R2 is a 5-membered heterocyclic radical which is unsubstituted or carries 1, 2, 3 or 4 substituents selected from the group consisting of halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy and C1-C4-alkylthio; R4 is hydrogen, halogen or methyl; R5 is C1-C6-alkyl, C3-C6-cycloalkyl or C3-C6-cycloalkylmethyl; and R6 is hydrogen or C1-C4-alkyl; or one of its agriculturally useful salts, b) from 200 to 700 g/l of 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide, and c) from 10 to 200 g/l of at least one surfactant S selected from a mixture of at least one anionic surfactant and at least one nonionic surfactant, where the components a), b) and c) are present dissolved in a mixture of organic solvents consisting to at least 95% by weight, based on the solvent mixture, of d1) at least one aprotic polar organic solvent having a miscibility with water at 25° C. and 1 bar of at least 50 g/l, and d2) at least one organic solvent having a solubility in water at 25° C. and 1 bar of less than 5 g/l.

    摘要翻译： 本发明涉及具有除草作用的活性化合物浓缩物，其包含a）10-100g / l至少一种式I的4-苯甲酰基取代的吡唑化合物，其中R 1，R 3彼此独立地为氢，卤素 ，甲基，卤代甲基，甲氧基，卤代甲氧基，甲硫基，甲基亚磺酰基或甲基磺酰基; R2是未取代的或携带1,2,3或4个选自卤素，C 1 -C 6烷基，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷基，C 1 -C 4的取代基的5元杂环基 - 卤代烷氧基和C 1 -C 4 - 烷硫基; R4是氢，卤素或甲基; R5是C1-C6-烷基，C3-C6-环烷基或C3-C6-环烷基甲基; 和R6是氢或C1-C4-烷基; 或其农业上有用的盐之一，b）200-700g / l的2-氯-N-（2,4-二甲基-3-噻吩基）-N-（2-甲氧基-1-甲基乙基）乙酰胺，和 c）10至200g / l的至少一种选自至少一种阴离子表面活性剂和至少一种非离子表面活性剂的混合物的表面活性剂S，其中组分a），b）和c）存在于 基于溶剂混合物，至少95重量％的有机溶剂为d1）至少一种与25℃的水混合的至少一种非质子极性有机溶剂和至少50g / l的1巴，d2 ）至少一种在25℃下在水中的溶解度和小于5g / l的1巴的有机溶剂。

    Piperazine Compounds Having Herbicidal Action
    9.
    发明申请
    Piperazine Compounds Having Herbicidal Action 审中-公开
    具有除草作用的哌嗪化合物

    公开(公告)号：US20100173777A1

    公开(公告)日：2010-07-08

    申请号：US12663781

    申请日：2008-06-11

    申请人： Eike Hupe ,  Thomas Seitz ,  Matthias Witschel ,  Dschun Song ,  William Karl Moberg ,  Liliana Parra Rapado ,  Frank Stelzer ,  Andrea Vescovi ,  Trevor William Newton ,  Robert Reinhard ,  Bernd Sievernich ,  Klaus Grossmann ,  Thomas Ehrhardt ,  Michael Rack ,  Elmar Kibler

    发明人： Eike Hupe ,  Thomas Seitz ,  Matthias Witschel ,  Dschun Song ,  William Karl Moberg ,  Liliana Parra Rapado ,  Frank Stelzer ,  Andrea Vescovi ,  Trevor William Newton ,  Robert Reinhard ,  Bernd Sievernich ,  Klaus Grossmann ,  Thomas Ehrhardt ,  Michael Rack ,  Elmar Kibler

    IPC分类号： A01N43/60 ,  C07D241/04 ,  A01P13/00

    CPC分类号： C07D241/08 ,  A01N43/60

    摘要： The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. R1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R12, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R12 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4-alkynyl; R5 is hydrogen, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkynyl or a group C(═O)R51 in which R51 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; R6 is C1-C4-alkyl, C1-C4-hydroxyalkyl or C1-C4-haloalkyl; R7, R8 independently of one another are hydrogen, OH, C1-C4-alkoxy, C1-C4-haloalkyloxy, C1-C4-alkyl or C1-C4-haloalkyl; R9, R10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy and C1-C4-haloalkoxy; and R11 is hydrogen or C1-C4-alkyl; and the agriculturally useful salts of these compounds.

    摘要翻译： 本发明涉及下面定义的通式I的哌嗪化合物及其作为除草剂的用途。 此外，本发明涉及用于作物保护的组合物和用于防治不想要的植物的方法。 R 1选自卤素，氰基，硝基，Z-C（= O）-R 12，苯基和具有1,2,3或4个杂原子的5或6元杂环基，所述杂原子选自 的O，N和S作为环原子，其中苯基和杂环基是未取代的或可以具有1,2,3或4个取代基R 1a; Z是共价键或CH2基; R12是氢，C1-C6-烷基，C3-C6-环烷基，C2-C6-烯基，C5-C6-环烯基，C2-C6-炔基等; R2是氢，卤素，硝基，氰基，C1-C4-烷基，C1-C4卤代烷基，C2-C4-烯基，C1-C4-烷氧基，C1-C4-卤代烷氧基，苄基或基团S（O） 其中R 21为C 1 -C 4烷基或C 1 -C 4卤代烷基，n为0,1或2; R3是氢或卤素; R4是C1-C4-烷基，C3-C4-烯基或C3-C4-炔基; R 5为氢，C 1 -C 4 - 烷基，C 3 -C 4 - 烯基，C 3 -C 4 - 炔基或C（= O）R 51，其中R 51为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基， C 4 - 烷氧基或C 1 -C 4 - 卤代烷氧基; R 6是C 1 -C 4烷基，C 1 -C 4羟基烷基或C 1 -C 4卤代烷基; R 7，R 8彼此独立地是氢，OH，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4 - 烷基或C 1 -C 4卤代烷基; R 9，R 10彼此独立地选自氢，卤素，CN，NO 2，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 2 -C 4 - 烯基，C 1 -C 4 - 烷氧基和C 1 -C 4 - 卤代烷氧基 和R 11是氢或C 1 -C 4 - 烷基; 和这些化合物的农业上有用的盐。