公开(公告)号：US09826739B2

公开(公告)日：2017-11-28

申请号：US12376320

申请日：2007-08-03

Applicant: Michael Krapp ,  Rainer Berghaus ,  Matthias Bratz ,  Elmar Kibler ,  Herve R. Vantieghem

Inventor： Michael Krapp ,  Rainer Berghaus ,  Matthias Bratz ,  Elmar Kibler ,  Herve R. Vantieghem

IPC: A01N43/80 ,  A01N43/56 ,  A01N43/10 ,  A01N25/02 ,  A01N25/30

CPC classification number: A01N43/56 ,  A01N25/02 ,  A01N25/30 ,  A01N43/10 ,  A01N43/80 ,  A01N2300/00

Abstract: The present invention relates to active compound concentrates having herbicidal action, comprising a) from 10 to 100 g/l of at least one 4-benzoyl-substituted pyrazole compound of the formula I in which R1, R3 independently of one another are hydrogen, halogen, methyl, halomethyl, methoxy, halomethoxy, methylthio, methylsulfinyl or methylsulfonyl; R2 is a 5-membered heterocyclic radical which is unsubstituted or carries 1, 2, 3 or 4 substituents selected from the group consisting of halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy and C1-C4-alkylthio; R4 is hydrogen, halogen or methyl; R5 is C1-C6-alkyl, C3-C6-cycloalkyl or C3-C6-cycloalkylmethyl; and R6 is hydrogen or C1-C4-alkyl; or one of its agriculturally useful salts, b) from 200 to 700 g/l of 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide, and c) from 10 to 200 g/l of at least one surfactant S selected from a mixture of at least one anionic surfactant and at least one nonionic surfactant, where the components a), b) and c) are present dissolved in a mixture of organic solvents consisting to at least 95% by weight, based on the solvent mixture, of d1) at least one aprotic polar organic solvent having a miscibility with water at 25° C. and 1 bar of at least 50 g/l, and d2) at least one organic solvent having a solubility in water at 25° C. and 1 bar of less than 5 g/l.

公开(公告)号：US20100173777A1

公开(公告)日：2010-07-08

申请号：US12663781

申请日：2008-06-11

Applicant: Eike Hupe ,  Thomas Seitz ,  Matthias Witschel ,  Dschun Song ,  William Karl Moberg ,  Liliana Parra Rapado ,  Frank Stelzer ,  Andrea Vescovi ,  Trevor William Newton ,  Robert Reinhard ,  Bernd Sievernich ,  Klaus Grossmann ,  Thomas Ehrhardt ,  Michael Rack ,  Elmar Kibler

Inventor： Eike Hupe ,  Thomas Seitz ,  Matthias Witschel ,  Dschun Song ,  William Karl Moberg ,  Liliana Parra Rapado ,  Frank Stelzer ,  Andrea Vescovi ,  Trevor William Newton ,  Robert Reinhard ,  Bernd Sievernich ,  Klaus Grossmann ,  Thomas Ehrhardt ,  Michael Rack ,  Elmar Kibler

IPC: A01N43/60 ,  C07D241/04 ,  A01P13/00

CPC classification number: C07D241/08 ,  A01N43/60

Abstract: The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. R1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R12, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R12 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4-alkynyl; R5 is hydrogen, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkynyl or a group C(═O)R51 in which R51 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; R6 is C1-C4-alkyl, C1-C4-hydroxyalkyl or C1-C4-haloalkyl; R7, R8 independently of one another are hydrogen, OH, C1-C4-alkoxy, C1-C4-haloalkyloxy, C1-C4-alkyl or C1-C4-haloalkyl; R9, R10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy and C1-C4-haloalkoxy; and R11 is hydrogen or C1-C4-alkyl; and the agriculturally useful salts of these compounds.

Abstract translation: 本发明涉及下面定义的通式I的哌嗪化合物及其作为除草剂的用途。 此外，本发明涉及用于作物保护的组合物和用于防治不想要的植物的方法。 R 1选自卤素，氰基，硝基，Z-C（= O）-R 12，苯基和具有1,2,3或4个杂原子的5或6元杂环基，所述杂原子选自 的O，N和S作为环原子，其中苯基和杂环基是未取代的或可以具有1,2,3或4个取代基R 1a; Z是共价键或CH2基; R12是氢，C1-C6-烷基，C3-C6-环烷基，C2-C6-烯基，C5-C6-环烯基，C2-C6-炔基等; R2是氢，卤素，硝基，氰基，C1-C4-烷基，C1-C4卤代烷基，C2-C4-烯基，C1-C4-烷氧基，C1-C4-卤代烷氧基，苄基或基团S（O） 其中R 21为C 1 -C 4烷基或C 1 -C 4卤代烷基，n为0,1或2; R3是氢或卤素; R4是C1-C4-烷基，C3-C4-烯基或C3-C4-炔基; R 5为氢，C 1 -C 4 - 烷基，C 3 -C 4 - 烯基，C 3 -C 4 - 炔基或C（= O）R 51，其中R 51为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基， C 4 - 烷氧基或C 1 -C 4 - 卤代烷氧基; R 6是C 1 -C 4烷基，C 1 -C 4羟基烷基或C 1 -C 4卤代烷基; R 7，R 8彼此独立地是氢，OH，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4 - 烷基或C 1 -C 4卤代烷基; R 9，R 10彼此独立地选自氢，卤素，CN，NO 2，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 2 -C 4 - 烯基，C 1 -C 4 - 烷氧基和C 1 -C 4 - 卤代烷氧基 和R 11是氢或C 1 -C 4 - 烷基; 和这些化合物的农业上有用的盐。

公开(公告)号：US06534444B1

公开(公告)日：2003-03-18

申请号：US09719429

申请日：2000-12-12

Applicant: Bernd Sievernich ,  Max Landes ,  Elmar Kibler ,  Wolfgang von Deyn ,  Helmut Walter ,  Martina Otten ,  Karl-Otto Westphalen ,  Herve Vantieghem

Inventor： Bernd Sievernich ,  Max Landes ,  Elmar Kibler ,  Wolfgang von Deyn ,  Helmut Walter ,  Martina Otten ,  Karl-Otto Westphalen ,  Herve Vantieghem

IPC: A01N4356

CPC classification number: A01N43/78 ,  A01N43/80 ,  A01N61/00 ,  A01N57/20 ,  A01N47/36 ,  A01N47/30 ,  A01N47/12 ,  A01N47/06 ,  A01N43/90 ,  A01N43/88 ,  A01N43/82 ,  A01N43/76 ,  A01N43/707 ,  A01N43/70 ,  A01N43/653 ,  A01N43/58 ,  A01N43/54 ,  A01N43/50 ,  A01N43/42 ,  A01N43/40 ,  A01N43/18 ,  A01N39/04 ,  A01N41/10 ,  A01N37/48 ,  A01N37/46 ,  A01N37/40 ,  A01N37/26 ,  A01N37/22 ,  A01N37/18 ,  A01N37/12 ,  A01N2300/00

Abstract: A synergistic herbicidal mixture comprising A) at least one benzoyl compound of formula I  or a salt thereof wherein R1, R3 are hydrogen, halogen, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is optionally substituted thiazol-2-yl, thiazol-4-yl, thiazol-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl or 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; and, B) a synergistically effective amount of at least one further herbicidal compound as defined in the specification, compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.

Abstract translation: 一种协同除草混合物，其包含A）至少一种式I的苯甲酰基化合物或其盐，其中R 1，R 3是氢，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基亚磺酰基或烷基磺酰基; R 2是任选取代的噻唑-2-基， 噻唑-4-基，噻唑-5-基，异恶唑-3-基，异恶唑-4-基，异恶唑-5-基，4,5-二氢异恶唑-3-基，4,5-二氢异恶唑-4-基或 4,5-二氢异恶唑-5-基; R 4是氢，卤素或烷基; R 5是烷基; R 6是氢或烷基; 和B）协同有效量的至少一种本说明书中定义的除草化合物，包含这些混合物的组合物，制备这些组合物的方法及其用于防治不需要的植物的用途。

公开(公告)号：US06514910B1

公开(公告)日：2003-02-04

申请号：US09914873

申请日：2001-09-05

Applicant: Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler ,  Herve Vantieghem

Inventor： Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler ,  Herve Vantieghem

IPC: A01N4378

CPC classification number: A01N43/78 ,  A01N43/80 ,  A01N37/06 ,  A01N37/02 ,  A01N25/30 ,  A01N2300/00

Abstract: A herbicidal mixture, comprising a) a herbicidally effective amount of a benzoyl compound of formula I  where: R1, R2 are halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkyl-sulfinyl or C1-C6-alkylsulfonyl; R3 is hydrogen, halogen, C1-C6-alkyl; X is 4,5-dihydroisoxazolyl which is unsubstituted or mono- or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R4 is a pyrazole of the formula II  which is attached in the 4-position and where R5 is hydrogen, R6 is methyl, or an environmentally compatible salt thereof; b) an adjuvant comprising i) a C1-C5-alkyl C5-C22-alkanoate, ii) a C10-C20-carboxylic acid, iii) a partial phosphoric ester or a partial sulfuric ester of a monohydroxy-functional polyalkyl ether and iv) optionally an alkyl polyoxyalkylene polyether, wherein the compound of formula I and the adjuvat are present in synergistically effective amounts.

Abstract translation: 一种除草混合物，其包含a）除草有效量的式I的苯甲酰基化合物，其中：R 1，R 2是卤素，C 1 -C 6烷基，C 1 -C 6烷硫基，C 1 -C 6烷基亚磺酰基或C 1 -C 6烷基磺酰基 R 3是氢，卤素，C 1 -C 6 - 烷基; X是未被取代或被卤素，C 1 -C 6烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷基，C 1 -C 6 - 烷氧基取代或被单取代或多取代的4,5-二氢异恶唑基 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基; R 4是连接在4-位的式II的吡唑，其中R 5是氢，R 6是甲基或其环境相容的盐; b）佐剂，其包含：i） C1-C5烷基C5-C22-链烷酸酯，ii）C10-C20羧酸，iii）部分磷酸酯或单羟基官能聚烷基醚的部分硫酸酯，和/或任选的烷基聚氧化烯聚醚，其中化合物 并且佐剂以协同有效量存在。

公开(公告)号：US07842646B2

公开(公告)日：2010-11-30

申请号：US11079431

申请日：2005-03-14

Applicant: Bernd Sievernich ,  Max Landes ,  Elmar Kibler ,  Wolfgang von Deyn ,  Helmut Walter ,  Martina Otten ,  Karl-Otto Westphalen ,  Herve Vantieghem

Inventor： Bernd Sievernich ,  Max Landes ,  Elmar Kibler ,  Wolfgang von Deyn ,  Helmut Walter ,  Martina Otten ,  Karl-Otto Westphalen ,  Herve Vantieghem

IPC: A01N43/40

CPC classification number: A01N43/78 ,  A01N43/80 ,  A01N61/00 ,  A01N57/20 ,  A01N47/36 ,  A01N47/30 ,  A01N47/12 ,  A01N47/06 ,  A01N43/90 ,  A01N43/88 ,  A01N43/82 ,  A01N43/76 ,  A01N43/707 ,  A01N43/70 ,  A01N43/653 ,  A01N43/58 ,  A01N43/54 ,  A01N43/50 ,  A01N43/42 ,  A01N43/40 ,  A01N43/18 ,  A01N39/04 ,  A01N41/10 ,  A01N37/48 ,  A01N37/46 ,  A01N37/40 ,  A01N37/26 ,  A01N37/22 ,  A01N37/18 ,  A01N37/12 ,  A01N2300/00

Abstract: A synergistic herbicidal mixture comprising A) at least one compound of the formula I wherein R1, R3 are hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfinyl; R2 is optionally substituted thiazol-2-yl, thiazol-4-yl, thiazol-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) a synergistically effective amount of at least one herbicidal compound from the group of ACC inhibitors, ALS inhibitors, amides, aixin herbicides, auxin transport inhibitors, carotenoid biosynthesis inhibitors, ESPS inhibitors, glutamine synthetase inhibitors, lipid biosynthesis inhibitors, mitosis inhibitors, protoporphyrinogen IX oxidase inhibitors, photosynthesis inhibitors, synergists, growth substances, cell wall biosynthesis inhibitors and a variety of other herbicides. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.

Abstract translation: 一种协同除草混合物，其包含A）至少一种式I化合物，其中R 1，R 3是氢，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基亚磺酰基或烷基亚磺酰基; R 2是任选取代的噻唑-2-基，噻唑-4-基，噻唑-5-基，异恶唑-3-基，异恶唑-4-基，异恶唑-5-基，4,5-二氢异恶唑-3-基， 4,5-二氢异恶唑-4-基，4,5-二氢异恶唑-5-基; R4是氢，卤素或烷基; R5是烷基; R6是氢或烷基; 或其环境相容的盐之一; 和B）协同有效量的至少一种来自ACC抑制剂，ALS抑制剂，酰胺，aixin除草剂，生长素转运抑制剂，类胡萝卜素生物合成抑制剂，ESPS抑制剂，谷氨酰胺合成酶抑制剂，脂质生物合成抑制剂，有丝分裂抑制剂， 原卟啉原IX氧化酶抑制剂，光合作用抑制剂，增效剂，生长物质，细胞壁生物合成抑制剂和各种其它除草剂。 包含这些混合物的组合物，这些组合物的制备方法以及它们用于控制不期望的植物的用途。

公开(公告)号：US20100190794A1

公开(公告)日：2010-07-29

申请号：US12663795

申请日：2008-06-11

Applicant: Eike Hupe ,  William Karl Moberg ,  Robert Reinhard ,  Bernd Sievernich ,  Elmar Kibler

Inventor： Eike Hupe ,  William Karl Moberg ,  Robert Reinhard ,  Bernd Sievernich ,  Elmar Kibler

IPC: A01N43/60 ,  A01N43/70 ,  A01P13/02

CPC classification number: A01N37/46 ,  A01N43/60 ,  A01N33/18 ,  A01N43/10 ,  A01N43/40 ,  A01N43/42 ,  A01N43/50 ,  A01N43/54 ,  A01N43/70 ,  A01N43/80 ,  A01N43/82 ,  A01N47/12 ,  A01N47/30 ,  A01N2300/00

Abstract: The present invention relates to herbicidally active compositions comprising at least one piperazinedione compound of the formula I in which: Rx, Ry are each hydrogen or together are a chemical bond; R1 is cyano or nitro; R2 is hydrogen, fluorine, chlorine, C1-C2-alkyl, ethenyl or C1-C2-alkoxy; R3 is fluorine or hydrogen; R4 is methyl; R5 is hydrogen, methyl or ethyl; R6 is hydrogen, methyl or ethyl; and R7 is hydrogen or halogen; and at least one further active compound selected from the group consisting of b1) lipid biosynthesis inhibitors; b2) acetolactate synthase inhibitors (ALS inhibitors); b3) photosynthesis inhibitors; b4) protoporphyrinogen-IX oxidase inhibitors, b5) bleacher herbicides; b6) enolpyruvyl shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7) glutamine synthetase inhibitors; b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9) mitose inhibitors; b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11) cellulose biosynthesis inhibitors; b12) decoupler herbicides; b13) auxin herbicides; b14) auxin transport inhibitors; b15) other herbicides, and C) safeners.

Abstract translation: 本发明涉及包含至少一种式I的哌嗪二酮化合物的除草活性组合物，其中：Rx，Ry各自为氢或一起为化学键; R1是氰基或硝基; R2是氢，氟，氯，C1-C2-烷基，乙烯基或C1-C2-烷氧基; R3是氟或氢; R4是甲基; R5是氢，甲基或乙基; R6是氢，甲基或乙基; 并且R 7是氢或卤素; 和至少一种选自b1）脂质生物合成抑制剂的其它活性化合物; b2）乙酰乳酸合酶抑制剂（ALS抑制剂）; b3）光合作用抑制剂; b4）原卟啉原-Ⅸ氧化酶抑制剂，b5）漂白剂除草剂; b6）烯醇丙酮酸莽沙鱼磷酸合酶抑制剂（EPSP抑制剂）; b7）谷氨酰胺合成酶抑制剂; b8）7,8-二氢叶酸合酶抑制剂（DHP抑制剂）; b9）丝裂抑制剂; b10）非常长链脂肪酸（VLCFA抑制剂）的合成抑制剂; b11）纤维素生物合成抑制剂; b12）除草剂除草剂; b13）生长素除草剂; b14）生长素运输抑制剂; b15）其他除草剂，和C）安全剂。

公开(公告)号：US20100152047A1

公开(公告)日：2010-06-17

申请号：US12663784

申请日：2008-06-11

Applicant: Eike Hupe ,  Thomas Seitz ,  Matthias Witschel ,  Dschun Song ,  William Karl Moberg ,  Liliana Parra Rapado ,  Frank Stelzer ,  Andrea Vescovi ,  Trevor William Newton ,  Robert Reinhard ,  Bernd Sievernich ,  Klaus Grossmann ,  Thomas Ehrhardt ,  Michael Rack ,  Elmar Kibler

Inventor： Eike Hupe ,  Thomas Seitz ,  Matthias Witschel ,  Dschun Song ,  William Karl Moberg ,  Liliana Parra Rapado ,  Frank Stelzer ,  Andrea Vescovi ,  Trevor William Newton ,  Robert Reinhard ,  Bernd Sievernich ,  Klaus Grossmann ,  Thomas Ehrhardt ,  Michael Rack ,  Elmar Kibler

IPC: A01N43/58 ,  C07D403/10 ,  C07D401/10 ,  C07D241/02 ,  C07D413/10 ,  A01N43/54 ,  A01N43/60 ,  A01P13/00

CPC classification number: C07D241/08 ,  C07D403/10 ,  C07D407/10 ,  C07D409/10 ,  C07D413/10 ,  C07D417/10

Abstract: The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. In formula I, the variables have the following meanings: R1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R11, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R11 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4-alkynyl; R5 is hydrogen, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkynyl or a group C(═O)R51 in which R51 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; R6 is C1-C4-alkyl, C1-C4-hydroxyalkyl or C1-C4-haloalkyl; R7, R8 independently of one another are hydrogen, OH, C1-C4-alkoxy, C1-C4-haloalkyloxy, C1-C4-alkyl or C1-C4-haloalkyl; and R9, R10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy and C1-C4-haloalkoxy.

Abstract translation: 本发明涉及下面定义的通式I的哌嗪化合物及其作为除草剂的用途。 此外，本发明涉及用于作物保护的组合物和用于防治不想要的植物的方法。 在式I中，变量具有以下含义：R 1选自卤素，氰基，硝基，Z-C（= O）-R 11，苯基和具有1， 2,3或4个选自O，N和S作为环原子的杂原子，其中苯基和杂环基是未取代的或可以具有1,2,3或4个取代基R 1a; Z是共价键或CH2基; R11是氢，C1-C6-烷基，C3-C6-环烷基，C2-C6-烯基，C5-C6-环烯基，C2-C6-炔基等; R2是氢，卤素，硝基，氰基，C1-C4-烷基，C1-C4卤代烷基，C2-C4-烯基，C1-C4-烷氧基，C1-C4-卤代烷氧基，苄基或基团S（O） 其中R 21为C 1 -C 4烷基或C 1 -C 4卤代烷基，n为0,1或2; R3是氢或卤素; R4是C1-C4-烷基，C3-C4-烯基或C3-C4-炔基; R 5为氢，C 1 -C 4 - 烷基，C 3 -C 4 - 烯基，C 3 -C 4 - 炔基或C（= O）R 51，其中R 51为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基， C 4 - 烷氧基或C 1 -C 4 - 卤代烷氧基; R 6是C 1 -C 4烷基，C 1 -C 4羟基烷基或C 1 -C 4卤代烷基; R 7，R 8彼此独立地是氢，OH，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4 - 烷基或C 1 -C 4卤代烷基; R 9，R 10彼此独立地选自氢，卤素，CN，NO 2，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 2 -C 4 - 烯基，C 1 -C 4 - 烷氧基和C 1 -C 4 卤代烷氧基。

公开(公告)号：US07521395B2

公开(公告)日：2009-04-21

申请号：US10521806

申请日：2003-07-22

Applicant: William B. O'Neal ,  Elmar Kibler ,  Dan E. Westberg ,  Matthias Witschel ,  Herve R. Vantieghem

Inventor： William B. O'Neal ,  Elmar Kibler ,  Dan E. Westberg ,  Matthias Witschel ,  Herve R. Vantieghem

IPC: A01N43/64 ,  A01N43/00 ,  A01N43/66 ,  A01N63/00 ,  A01N43/653

CPC classification number: A01N43/56 ,  A01N47/36 ,  A01N61/00 ,  A01N43/70 ,  A01N43/10 ,  A01N43/88 ,  A01N2300/00

Abstract: A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoly derivative of the formula I in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl, R6 is hydrogen or alkyl; or one of its environmentally compatible salts; B) nicosulfuron (II) or one of its environmentally compatible salts; and C) at least one herbicidal compound from the group triazines or one of their environmentally compatible salts, in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesirable plants.

Abstract translation: 一种协同除草混合物，其包含A）至少一种式I的3-杂环基取代的苯并多羟基衍生物，其中变量具有以下含义：R 1，R 3为卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基亚磺酰基或烷基磺酰基; R2是任选取代的杂环基团，其选自异恶唑-3-基，异恶唑-4-基，异恶唑-5-基，4,5-二氢异恶唑-3-基，4,5-二氢异恶唑-4-基和 4,5-二氢异恶唑-5-基; R4是氢，卤素或烷基; R5是烷基，R6是氢或烷基; 或其环境相容的盐之一; B）烟嘧磺隆（II）或其与环境相容的盐之一; 和C）至少一种来自组合三嗪或其环境相容性盐之一的除草化合物，其协同有效量。 包含这些混合物的组合物，这些组合物的制备方法以及它们用于控制不期望的植物的用途。

公开(公告)号：US20050256002A1

公开(公告)日：2005-11-17

申请号：US10521806

申请日：2003-07-22

Applicant: William O'Neal ,  Elmar Kibler ,  Dan Westberg ,  Matthias Witschel ,  Herve Vantiegheim

Inventor： William O'Neal ,  Elmar Kibler ,  Dan Westberg ,  Matthias Witschel ,  Herve Vantiegheim

IPC: A01N43/80 ,  A01N43/10 ,  A01N43/56 ,  A01N43/647 ,  A01N43/70 ,  A01N43/713 ,  A01N43/88 ,  A01N47/36

CPC classification number: A01N43/56 ,  A01N47/36 ,  A01N61/00 ,  A01N43/70 ,  A01N43/10 ,  A01N43/88 ,  A01N2300/00

Abstract: A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydro-isoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) the compound of formula II or one of its environmentally compatible salts; and C) at least one further herbicidal compound from the group of the acetolactate synthase inhibitors (ALS), lipid biosynthesis inhibitors and photosynthesis inhibitors; in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.

Abstract translation: 一种协同除草混合物，其包含A）至少一种式I的3-杂环基取代的苯甲酰基衍生物，其中变量具有以下含义：R 1，R 3， 卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基亚磺酰基或烷基磺酰基; R 2是任选取代的杂环基，其选自异恶唑-3-基，异恶唑-4-基，异恶唑-5-基，4,5-二氢异恶唑-3-基， 5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢，卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 和B）式II化合物或其环境相容的盐之一; 和C）来自乙酰乳酸合酶抑制剂（ALS），脂质生物合成抑制剂和光合作用抑制剂的至少一种另外的除草化合物; 协同有效量。 包含这些混合物的组合物，这些组合物的制备方法以及它们用于控制不期望的植物的用途。

公开(公告)号：US06479437B1

公开(公告)日：2002-11-12

申请号：US09701875

申请日：2000-12-05

Applicant: Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler

Inventor： Matthias Bratz ,  Rainer Berghaus ,  Martina Otten ,  Bernd Sievernich ,  Elmar Kibler

IPC: A01N4356

CPC classification number: C05G3/02 ,  A01N43/78 ,  A01N43/80 ,  A01N2300/00

Abstract: A herbicidal mixture comprising a) a herbicidally active amount of a 3-heterocyclyl-substituted benzoyl derivative of the formula I  in which the variables have the following meanings: R1,R2 are hydrogen, halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy; R3 is hydrogen, halogen, C1-C6-alkyl; X is a heterocycle from amongst the group consisting of isoxazolyl, 4,5-dihydroisoxazolyl and thiazolyl, it being possible for the heterocycle to be optionally monosubstituted or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R5 is hydrogen or C1-C6-alkyl, R6 is C1-C6-alkyl, or their environmentally compatible salts; b) a nitrogenous fertilizer in a synergistically effective amount and c) an adjuvant in a synergistically effective amount.

Abstract translation: 一种除草混合物，其包含a）除草活性量的式I的3-杂环基取代的苯甲酰基衍生物，其中所述变量具有以下含义：R 1，R 2是氢，卤素，C 1 -C 6 - 烷基，C 1 -C 6 - 烷硫基 ，C 1 -C 6烷基亚磺酰基，C 1 -C 6烷基磺酰基，C 1 -C 6卤代烷基，C 1 -C 6 - 烷氧基，C 1 -C 6卤代烷氧基; R 3是氢，卤素，C 1 -C 6烷基; X是 由异唑基，4,5-二氢异恶唑基和噻唑基组成的组，可以将杂环任选被卤素，C 1 -C 6 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基; R 5是氢或C 1 -C 6烷基，R 6是C 1 -C 6 - 烷基或其环境相容的盐; b）具有协同有效量的含氮肥料，和c）协同有效的佐剂 量。