摘要:
The present invention relates to reactive compositions containing A) one or more blocked polyurethane prepolymers which have a content of blocked isocyanate groups (calculated as NCO) of 0.1 to 20 wt. % and are prepared from i) at least one aromatic, aliphatic, araliphatic and/or cycloaliphatic diisocyanate having a content of free NCO groups of 5 to 60 wt. %, ii) a polyol component containing at least one polyester polyol, and/or at least one polyether polyol and/or at least one polycarbonate polyol, iii) CH-acidic cyclic ketones corresponding to formula (I) as blocking agents wherein X represents an electron-attracting group, R1 and R2 independently of one another represent the radicals H, C1-C20 (cyclo)alkyl, C6-C24 aryl, C1-C20 (cyclo)alkyl ester or amide, C6-C24 aryl ester or amide, mixed aliphatic/aromatic radicals with 1 to 24 carbon atoms that can also be part of a 4- to 8-membered ring, n is an integer from 0 to 5, and B) one or more OH-functional compounds in which the OH component undergoes activation by a deposition amine component. The present invention also relates to a composite system containing two adherends bonded together with the reactive composition according to the invention.
摘要:
The present invention relates to reactive polyurethanes having a low monomeric diisocyanate content and also to their preparation and their use in reactive one- and two-component adhesives/sealants, assembly foams, casting compounds, and also flexible, rigid and integral foams. The polyurethanes are prepared in the presence of zirconium(IV) acetylacetonate complexes as catalyst, where at least one acetylacetonate ligand present in the catalyst bears a fluorine substituent.
摘要:
The present invention relates to a process for the production of MDI fractions containing 2,4′-MDI, and in which the 2,2′-MDI component from the MDA production is largely removed from the isomer mixture. Highly reactive monomeric MDI products can be produced in this way. These MDI products are characterised in their processing by significantly reduced emissions of MDI monomers.
摘要:
Reactive polyurethane hotmelts comprising crystallizing polyesterpolyols based on fumaric acid and 1,6-hexanediol. These hotmelts exhibit good pressure-sensitive adhesive (PSA) properties over a very broad temperature range. The reactive polyurethane hotmelts are prepared by mixing a polyol mixture containing at least on crystallizing polyesterpolyol with an excess of polyisocyanates.
摘要:
The invention relates to moisture-curable adhesive or sealant compositions comprising a) prepolymers based on aliphatic polyisocyanates and having isocyanate contents of 2 to 20 wt. %, and b) bis(dimethylaminoethyl)ether as catalyst. The compositions exhibit good storability, processability can be adjusted within wide limits and also provide rapid through-hardening.
摘要:
The invention relates to a composition based on alkoxysilane-functional polyurethane prepolymers suitable for a reactive hot-melt adhesive which is stable to storage at a high temperature but cures very rapidly under the action of moisture from the atmosphere or from the materials glued to one another and which is suitable for joining the most diverse materials. The invention also relates to the process for gluing the most diverse substrates using the reactive hot-melt adhesive according to the invention.
摘要:
The invention relates to a composition based on alkoxysilane-functional polyurethane prepolymers suitable for a reactive hot-melt adhesive which is stable to storage at a high temperature but cures very rapidly under the action of moisture from the atmosphere or from the materials glued to one another and which is suitable for joining the most diverse materials. The invention also relates to the process for gluing the most diverse substrates using the reactive hot-melt adhesive according to the invention.
摘要:
The present invention relates to low-viscosity polyurethane prepolymers (PU prepolymers) based on 2,4′-MDI, to a process for preparing them and to their use.
摘要:
The present invention relates to a process for the production of MDI fractions containing 2,4′-MDI, and in which the 2,2′-MDI component from the MDA production is largely removed from the isomer mixture. Highly reactive monomeric MDI products can be produced in this way. These MDI products are characterised in their processing by significantly reduced emissions of MDI monomers.
摘要:
Method for the production of adhesive-coated articles, articles obtainable thereby and their use A method for the production of adhesive-coated articles comprises the steps of: (I) providing a substrate; (II) applying a first polyurethane and/or polyurethane-polyurea polymer onto the substrate, the first polyurethane and/or polyurethane-polyurea polymer being capable of attaining an at least partially crystalline state with a final degree of crystallinity and wherein during and/or after the application the first polyurethane and/or polyurethane-polyurea polymer is present in a non-crystalline state. The method further comprises the steps: (III) applying onto the first polyurethane and/or polyurethane-polyurea polymer of step (II) a composition comprising a mixture of a second polyurethane and/or polyurethane-polyurea polymer and furthermore an acrylate polymer, wherein the application is performed while the degree of crystallinity of the first polyurethane-polyurea polymer is lower than its final degree of crystallinity; and (IV) cooling the article obtained to a temperature below the glass transition temperature of the acrylate polymer.