公开(公告)号：US5374419A

公开(公告)日：1994-12-20

申请号：US994069

申请日：1992-12-18

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

IPC分类号： A61K8/00 ,  A61K8/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  A61Q17/04 ,  C07C69/734 ,  C07C69/736 ,  C07C255/23 ,  C07C255/32 ,  C07C255/34 ,  C07C255/37 ,  C07C255/41 ,  C07C255/53 ,  C07C271/26 ,  C07C317/46 ,  C07C321/28 ,  C07C323/12 ,  C07C323/19 ,  C07C323/32 ,  C07C323/62 ,  C08G63/16 ,  C08G63/20 ,  C08G63/44 ,  C08G63/676 ,  C08G63/685 ,  C08G63/688 ,  C08G85/00 ,  C08J5/18 ,  C08K5/00 ,  C08L67/00 ,  C08L67/02 ,  C09K3/00 ,  A61K7/42 ,  A61K7/44 ,  C07C255/00

CPC分类号： A61Q17/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  C07C255/41 ,  C08G63/676 ,  C08G63/6858 ,  C08G63/6888 ,  C08G85/00 ,  Y10S514/938 ,  Y10T428/13 ,  Y10T428/1352

摘要： Disclosed are sunscreen compositions containing certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.

摘要翻译： 公开了含有具有式“IMAGE”的某些多次甲基化合物的防晒组合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。

公开(公告)号：US5194571A

公开(公告)日：1993-03-16

申请号：US746832

申请日：1991-08-19

申请人： Max A. Weaver ,  Clarence A. Coates ,  William W. Parham ,  Samuel D. Hilbert ,  James J. Krutak ,  Wayne P. Pruett

发明人： Max A. Weaver ,  Clarence A. Coates ,  William W. Parham ,  Samuel D. Hilbert ,  James J. Krutak ,  Wayne P. Pruett

IPC分类号： C08G63/685 ,  C08G63/688 ,  C08L101/00

CPC分类号： C08L101/00 ,  C08G63/6854 ,  C08G63/6884

摘要： Provided are polyester compositions having thermally stable colorants copolymerized therein, said colorants comprised of at least one electron-rich aromatic moiety attached to a negatively substituted 2,5-dioxypyrrolin-3-yl moiety and containing at least one, and preferably, two polyester reactive groups. Also provided are polyester color concentrates and blends of the colored polyester compositions with other thermoplastic polymers and shaped or formed articles comprised of same.

摘要翻译： 提供了在其中共聚有热稳定着色剂的聚酯组合物，所述着色剂由至少一个富含电子的芳族部分连接到负取代的2,5-二氧基吡咯啉-3-基部分上并含有至少一个，优选两个聚酯反应性 团体 还提供了聚酯颜色浓缩物和着色聚酯组合物与其它热塑性聚合物的混合物和由其组成的成形或成型制品。

公开(公告)号：US5057594A

公开(公告)日：1991-10-15

申请号：US395386

申请日：1989-08-17

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

IPC分类号： A61K8/00 ,  A61K8/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  A61Q17/04 ,  C07C69/734 ,  C07C69/736 ,  C07C255/23 ,  C07C255/32 ,  C07C255/34 ,  C07C255/37 ,  C07C255/41 ,  C07C255/53 ,  C07C271/26 ,  C07C317/46 ,  C07C321/28 ,  C07C323/12 ,  C07C323/19 ,  C07C323/32 ,  C07C323/62 ,  C08G63/16 ,  C08G63/20 ,  C08G63/44 ,  C08G63/676 ,  C08G63/685 ,  C08G63/688 ,  C08G85/00 ,  C08J5/18 ,  C08K5/00 ,  C08L67/00 ,  C08L67/02 ,  C09K3/00

CPC分类号： A61Q17/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  C07C255/41 ,  C08G63/676 ,  C08G63/6858 ,  C08G63/6888 ,  C08G85/00 ,  Y10S514/938 ,  Y10T428/13 ,  Y10T428/1352

摘要： Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.

公开(公告)号：US4999418A

公开(公告)日：1991-03-12

申请号：US401270

申请日：1989-08-31

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Wayne P. Pruett ,  William W. Parham

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Wayne P. Pruett ,  William W. Parham

IPC分类号： C08G63/685 ,  C08K5/18 ,  C08L67/00 ,  C08L67/02 ,  C09B1/26 ,  C09B69/10 ,  D01F6/62

CPC分类号： C09B1/26 ,  C08G63/6856 ,  C09B69/101

摘要： Disclosed are colored polyester compositions comprising a polyester having reacted therewith or copolymerized therein at least one residue of an anthraquinone compound having the formula ##STR1## wherein AQ is the residue of a 9,10-anthraquinone radical; R.sup.1 and R.sup.2 are the same or different and are unsubstituted or substituted alkyl, cycloalkyl or aryl; X is a group reactive with at least one of the functional groups of the monomers from which the polyester is prepared; and n is 1 or 2. The described anthraquinone compounds possess improved thermal stability and thus are not decomposed at the high temperatures at which polyesters are prepared. Also disclosed are shaped articles, particularly containers, fabricated from the colored polyester compositions.

公开(公告)号：US5442086A

公开(公告)日：1995-08-15

申请号：US308863

申请日：1994-09-19

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

IPC分类号： A61K8/00 ,  A61K8/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  A61Q17/04 ,  C07C69/734 ,  C07C69/736 ,  C07C255/23 ,  C07C255/32 ,  C07C255/34 ,  C07C255/37 ,  C07C255/41 ,  C07C255/53 ,  C07C271/26 ,  C07C317/46 ,  C07C321/28 ,  C07C323/12 ,  C07C323/19 ,  C07C323/32 ,  C07C323/62 ,  C08G63/16 ,  C08G63/20 ,  C08G63/44 ,  C08G63/676 ,  C08G63/685 ,  C08G63/688 ,  C08G85/00 ,  C08J5/18 ,  C08K5/00 ,  C08L67/00 ,  C08L67/02 ,  C09K3/00 ,  C07C255/00

CPC分类号： A61Q17/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  C07C255/41 ,  C08G63/676 ,  C08G63/6858 ,  C08G63/6888 ,  C08G85/00 ,  Y10S514/938 ,  Y10T428/13 ,  Y10T428/1352

摘要： Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --0-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.

摘要翻译： 公开了具有式“IMAGE”的某些聚次甲基化合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。

公开(公告)号：US5302740A

公开(公告)日：1994-04-12

申请号：US968917

申请日：1992-10-30

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates, Jr. ,  Samuel D. Hilbert ,  Terry A. Oldfield ,  William W. Parham ,  Wayne P. Pruett

IPC分类号： A61K8/00 ,  A61K8/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  A61Q17/04 ,  C07C69/734 ,  C07C69/736 ,  C07C255/23 ,  C07C255/32 ,  C07C255/34 ,  C07C255/37 ,  C07C255/41 ,  C07C255/53 ,  C07C271/26 ,  C07C317/46 ,  C07C321/28 ,  C07C323/12 ,  C07C323/19 ,  C07C323/32 ,  C07C323/62 ,  C08G63/16 ,  C08G63/20 ,  C08G63/44 ,  C08G63/676 ,  C08G63/685 ,  C08G63/688 ,  C08G85/00 ,  C08J5/18 ,  C08K5/00 ,  C08L67/00 ,  C08L67/02 ,  C09K3/00

CPC分类号： A61Q17/04 ,  A61K8/40 ,  A61K8/46 ,  A61K8/85 ,  C07C255/41 ,  C08G63/676 ,  C08G63/6858 ,  C08G63/6888 ,  C08G85/00 ,  Y10S514/938 ,  Y10T428/13 ,  Y10T428/1352

摘要： Disclosed are certain poly-methine compounds having the formula ##STR1## wherein each R.sup.1 is independently selected from cyano; carboxy; alkenyloxycarbonyl; an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; an unsubstituted or substituted, carbocyclic or heterocyclic aryl radical; an unsubstituted or substituted alkanoyl, cycloalkanoyl or aroyl radical; an unsubstituted or substituted carbamoyl radical; or an unsubstituted or substituted alkylsulfonyl, cycloalkylsulfonyl or arylsulfonyl radical; each R.sup.2 is independently selected from cyano or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical; each A is independently selected from an unsubstituted or substituted 1,2-phenylene or 1,2-naphthylene radical; each Z is independently selected from --O-- or --S--; and L is an organic linking group bonded by non-oxo carbon atoms to each Z atom. Also disclosed are sunscreen formulations and polymeric compositions containing at least one of the poly-methine compounds or the reactive residue thereof.

摘要翻译： 公开了具有式“IMAGE”的某些聚次甲基化合物，其中每个R 1独立地选自氰基; 羧基; 烯氧基羰基; 未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 未取代或取代的碳环或杂环芳基; 未取代或取代的烷酰基，环烷酰基或芳酰基; 未取代或取代的氨基甲酰基; 或未取代或取代的烷基磺酰基，环烷基磺酰基或芳基磺酰基; 每个R 2独立地选自氰基或未取代或取代的烷氧基羰基，环烷氧基羰基或芳氧基羰基; 每个A独立地选自未取代或取代的1,2-亚苯基或1,2-亚萘基; 每个Z独立地选自-O-或-S-; L是通过非氧代碳原子键合到每个Z原子上的有机连接基团。 还公开了含有至少一种多次甲基化合物或其反应残余物的防晒制剂和聚合物组合物。

公开(公告)号：US5102980A

公开(公告)日：1992-04-07

申请号：US679819

申请日：1991-04-01

申请人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates ,  William W. Parham ,  Terry A. Oldfield ,  Wayne P. Pruett ,  Samuel D. Hilbert

发明人： James J. Krutak ,  Max A. Weaver ,  Clarence A. Coates ,  William W. Parham ,  Terry A. Oldfield ,  Wayne P. Pruett ,  Samuel D. Hilbert

IPC分类号： C08G63/688 ,  C09B69/10

CPC分类号： C09B69/10 ,  C08G63/688

摘要： Provided are novel polyester compositions containing copper phthalocyanine sulfonamide colorants copolymerized therein. Also provided are amorphous color concentrates, partially-crystalline color concentrates and semi-crystalline color concentrates. These polyester compositions are particularly useful for use as colored packaging materials and for colorants for personal, medical, and home care products where non-extractability of the colorant residue is important.

摘要翻译： 提供了含有铜酞菁磺酰胺着色剂的新型聚酯组合物。 还提供了无定形浓缩液，部分结晶色浓缩物和半结晶色浓缩物。 这些聚酯组合物特别可用作彩色包装材料和用于个人，医疗和家庭护理产品的着色剂，其中着色剂残余物的非萃取性是重要的。

公开(公告)号：US5281659A

公开(公告)日：1994-01-25

申请号：US971001

申请日：1992-11-02

申请人： Max A. Weaver ,  Clarence A. Coates ,  William W. Parham ,  Samuel D. Hilbert ,  James J. Krutak ,  Wayne P. Pruett

发明人： Max A. Weaver ,  Clarence A. Coates ,  William W. Parham ,  Samuel D. Hilbert ,  James J. Krutak ,  Wayne P. Pruett

IPC分类号： C08G63/685 ,  C08G63/688 ,  C08L101/00 ,  C08J3/20 ,  C08G63/00 ,  C08L23/00 ,  C08L77/00

CPC分类号： C08L101/00 ,  C08G63/6854 ,  C08G63/6884

摘要： Provided are polyester compositions having thermally stable colorants copolymerized therein, said colorants comprised of at least one electron-rich aromatic moiety attached to a negatively substituted 2,5-dioxypyrrolin-3-yl moiety and containing at least one, and preferably, two polyester reactive groups. Also provided are polyester color concentrates and blends of the colored polyester compositions with other thermoplastic polymers and shaped or formed articles comprised of same.

摘要翻译： 提供了在其中共聚有热稳定着色剂的聚酯组合物，所述着色剂由至少一个富含电子的芳族部分连接到负取代的2,5-二氧基吡咯啉-3-基部分上并含有至少一个，优选两个聚酯反应性 团体 还提供了聚酯颜色浓缩物和着色聚酯组合物与其它热塑性聚合物的混合物和由其组成的成形或成型制品。

公开(公告)号：US5274072A

公开(公告)日：1993-12-28

申请号：US878273

申请日：1992-05-04

申请人： Max A. Weaver ,  James J. Krutak ,  Clarence A. Coates, Jr. ,  William W. Parham ,  Wayne P. Pruett ,  Samuel D. Hilbert

发明人： Max A. Weaver ,  James J. Krutak ,  Clarence A. Coates, Jr. ,  William W. Parham ,  Wayne P. Pruett ,  Samuel D. Hilbert

IPC分类号： C07D413/04 ,  C07D413/14 ,  C07D417/14 ,  C08G63/685 ,  C08G63/688 ,  C08L101/00 ,  C08G63/08 ,  C07D277/62 ,  C07D307/02

CPC分类号： C07D413/14 ,  C07D413/04 ,  C07D417/14 ,  C08G63/685 ,  C08G63/688 ,  C08L101/00

摘要： Provided are certain novel substituted 2(5H)furanone compounds which are useful as ultraviolet/visible light absorbing compounds. Also provided are polyester compositions having such compounds copolymerized therein and shaped or formed articles comprised of such polyester compositions.

摘要翻译： 提供可用作紫外/可见光吸收化合物的某些新的取代的2（5H）呋喃酮化合物。 还提供了具有共聚合的这种化合物的聚酯组合物和由这种聚酯组合物组成的成形或成型制品。

公开(公告)号：US5030708A

公开(公告)日：1991-07-09

申请号：US628974

申请日：1990-12-17

申请人： James J. Krutak ,  William W. Parham ,  Clarence A. Coates, Jr. ,  Terry A. Oldfield ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Max A. Weaver

发明人： James J. Krutak ,  William W. Parham ,  Clarence A. Coates, Jr. ,  Terry A. Oldfield ,  Wayne P. Pruett ,  Samuel D. Hilbert ,  Max A. Weaver

IPC分类号： C08G63/685 ,  C08G63/688 ,  C09B23/00 ,  C09B23/01 ,  C09B69/10

CPC分类号： C09B69/105 ,  C08G63/685 ,  C08G63/688 ,  C09B23/00 ,  C09B23/0091

摘要： Provided are novel methine colorants derived from acetaldehyde, 1,3-dihydro-7-methoxycarbonyl-1,1,3-trimethyl-2H-benz[e]indol-2-ylidine and polyester compositions and concentrates having these colorants copolymerized therein. Also provided are novel intermediates useful for making the colorants.

摘要翻译： 提供衍生自乙醛，1,3-二氢-7-甲氧基羰基-1,1,3-三甲基-2H-苯并[e]吲哚-2-基，和具有这些着色剂的聚酯组合物和浓缩物的新型次甲基着色剂。 还提供了可用于制备着色剂的新型中间体。