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公开(公告)号：US06956141B1
公开(公告)日：2005-10-18
申请号：US09913979
申请日：2000-02-22
申请人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
发明人： Melanie Maas-Brunner , Jochem Henkelmann , Gerd Kaibel , Alois Kindler , Christian Knoll , Harald Rust , Christian Tragut , Manfred Stroezel , Udo Rheude , Rudolf Erich Lorenz , Juan Aiscar
IPC分类号： C07C29/17 , C07C29/42 , C07C33/042 , C07C33/04 , C07C33/044 , C07C33/046
CPC分类号： C07C29/42 , C07C29/172 , Y02P20/582 , C07C33/044 , C07C33/042 , C07C31/20
摘要： A process for preparing at least one unsaturated alcohol (B) comprises the steps (I) to (III) below: (I) reaction of at least one alkali metal hydroxide or alkaline earth metal hydroxide with at least one alcohol (A) in at least one organic solvent (L) to give a mixture (G-I) comprising at least the alcohol (A), the solvent (L) and an alkoxide (AL); (II) reaction of at least one carbonyl compound of the formula R—CO—R′ with at least one alkyne of the formula R″—C≡C—H and the mixture (G-I) obtained in step (I) to give a mixture (G-II) comprising at least the alcohol (A), the solvent (L) and an unsaturated alcohol (B); (III) distillation of the mixture (G-II) obtained in step (II) to give the alcohol or alcohols (B) and a mixture (G-III) comprising the solvent (L) and the alcohol (A), wherein the solvent (L) obtained in step (III) and the alcohol (A) obtained in step (III) are recycled as a mixture to step (I).
摘要翻译： 一种制备至少一种不饱和醇（B）的方法包括下列步骤（I）至（III）：（I）至少一种碱金属氢氧化物或碱土金属氢氧化物与至少一种醇（A）在 至少一种有机溶剂（L），得到至少包含醇（A），溶剂（L）和醇盐（AL）的混合物（GI） （II）至少一种式R-CO-R'的羰基化合物与至少一种式R'-C≡CH的炔和步骤（I）中获得的混合物（GI）的反应，得到混合物 至少包含醇（A），溶剂（L）和不饱和醇（B）的化合物（G-II）; （II）中获得的混合物（G-II）的蒸馏（III），得到醇或醇（B）和包含溶剂（L）和醇（A）的混合物（G-III），其中 将步骤（III）中获得的溶剂（L）和步骤（III）中获得的醇（A）作为步骤（I）的混合物再循环。
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2.发明授权公开(公告)号：US07319161B2
公开(公告)日：2008-01-15
申请号：US10467234
申请日：2002-02-15
申请人： Ralf Noe , Hartmut Hibst , Klaus Halbritter , Melanie Maas-Brunner , Boris Breitscheidel , Gerd Kaibel , Klemens Massonne , Axel Salden , Klaus Ebel , Eike Johannes Bergner , Frank Haese
发明人： Ralf Noe , Hartmut Hibst , Klaus Halbritter , Melanie Maas-Brunner , Boris Breitscheidel , Gerd Kaibel , Klemens Massonne , Axel Salden , Klaus Ebel , Eike Johannes Bergner , Frank Haese
CPC分类号： C08K5/12 , C07C67/08 , C07C2601/14 , C07C69/75
摘要： The invention relates to a process for preparing cyclohexanedicarboxylic acids or derivatives thereof, such as esters and/or anhydrides, encompassing the reaction of diene/maleic acid anhydride mixtures, in particular of butadiene/maleic acid anhydride mixtures or of mixtures of maleic acid anhydrides and C5-dienes to give alkyl-substituted or unsubstituted cyclohexenedicarboxylic acid anhydrides in the condensed phase, ester formation, and then hydrogenation to give the corresponding cyclohexanedicarboxylic acid derivative, and also to the use of the cyclohexanedicarboxylic acids or derivatives thereof prepared according to the invention as plasticizers for plastics.
摘要翻译： 本发明涉及一种制备环己烷二羧酸或其衍生物的方法，例如酯和/或酸酐，其包括二烯/马来酸酐混合物，特别是丁二烯/马来酸酐混合物或马来酸酐混合物的反应和 C5-二烯，在缩合相中得到烷基取代或未取代的环己烯二羧酸酐，酯形成，然后氢化得到相应的环己烷二羧酸衍生物，还可以使用根据本发明制备的环己烷二羧酸或其衍生物作为 塑料增塑剂
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公开(公告)号：US07022824B2
公开(公告)日：2006-04-04
申请号：US10479967
申请日：2002-06-10
CPC分类号： B01J23/462 , B01J21/08 , B01J35/1019 , B01J35/1023 , B01J37/18 , C07C29/132 , C07C31/26
摘要： A process is described for preparing sorbitol by catalytic hydrogenation of a monosaccharide forming sorbitol on hydrogenation in the liquid phase, which comprises the catalyst being obtainable by: i) single or multiple treatment of an amorphous silicon dioxide based support material with a halogen-free aqueous solution of a low-molecular-weight ruthenium compound and subsequent drying of the treated support material at below 200° C., ii) reducing the solid obtained in i) with hydrogen at from 100 to 350° C., step ii) being carried out immediately after step i).
摘要翻译： 描述了通过在液相中氢化制备单糖形成山梨糖醇的催化氢化制备山梨糖醇的方法，该方法包括催化剂，其可通过以下步骤获得：i）用无卤素水溶液单独或多次处理无定形二氧化硅基载体材料 低分子量钌化合物的溶液，随后在低于200℃下干燥经处理的载体材料，ii）在100-350℃下用氢还原在i）中获得的固体，步骤ii） 在步骤i之后立即出现）。
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公开(公告)号：US20080210222A1
公开(公告)日：2008-09-04
申请号：US12118201
申请日：2008-05-09
IPC分类号： C13J1/00
CPC分类号： C07C29/132 , B01J21/08 , B01J23/462 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/1009 , B01J35/1014 , B01J35/1023 , B01J35/1042 , B01J37/0201 , B01J37/18 , C07C31/26 , C07C31/18
摘要： Sugar alcohols are prepared by catalytically hydrogenating the corresponding monosaccharides and oligosaccharides in the liquid phase over a heterogeneous ruthenium catalyst, with the exception of the preparation of sorbitol, wherein the heterogeneous ruthenium catalyst is prepared by: i) treating a support material based on amorphous silicon dioxide comprising at least 95% by weight of silicon dioxide and less than 1% by weight aluminum oxide, calculated as Al2O3, one or more times with a halogen-free aqueous solution of a low molecular weight ruthenium compound which is a ruthenium (III) salt or a metal ruthenate and subsequently drying the treated support material at a temperature below 200° C., and ii) reducing the solid obtained in i) by means of hydrogen at a temperature ranging from 100 to 350° C., wherein step ii) is carried out directly after step i), and wherein the ruthenium content in the catalyst ranges from 0.1 to 5% by weight, based on the support material.
摘要翻译： 糖醇通过在异相钌催化剂上催化氢化相应的液相中的单糖和寡糖而制备，除了制备山梨糖醇之外，其中非均相钌催化剂通过以下制备：i）处理基于非晶硅的载体材料 二氧化物包含至少95重量％的二氧化硅和小于1重量％的氧化铝，以Al 2 O 3 3计算，用卤素 - 游离的低分子量钌化合物的水溶液，其是钌（III）盐或金属钌酸盐，随后在低于200℃的温度下干燥经处理的载体材料，和ii）通过方法还原在i）中获得的固体 的氢气，其中步骤ii）在步骤i）之后直接进行，并且其中催化剂中的钌含量为0.1至5重量％，基于载体 材料。
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公开(公告)号：US07618917B2
公开(公告)日：2009-11-17
申请号：US10480284
申请日：2002-06-10
IPC分类号： B01J23/46
CPC分类号： C07C29/132 , B01J21/08 , B01J23/462 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/1009 , B01J35/1014 , B01J35/1023 , B01J35/1042 , B01J37/0201 , B01J37/18 , C07C31/26 , C07C31/18
摘要： Novel ruthenium catalysts can be obtained by: i) treating a support material based on amorphous silicon dioxide one or more times with a halogen-free aqueous solution of a low molecular weight ruthenium compound and subsequently drying the treated support material at below 200° C., ii) reducing the solid obtained in i) by means of hydrogen at from 100 to 350° C., where step ii) is carried out directly after step i). These catalysts can be used for the catalytic hydrogenation of monosaccharides and disaccharides to produce sugar alcohols, with the exception of sorbitol.
摘要翻译： 新型钌催化剂可以通过以下方式获得：i）用低分子量钌化合物的无卤素水溶液处理基于无定形二氧化硅的载体材料一次或多次，随后将处理的载体材料在低于200℃下干燥。 ，ii）通过在100至350℃的氢气还原在i）中获得的固体，其中步骤ii）在步骤i）之后直接进行。 除了山梨糖醇之外，这些催化剂可用于单糖和二糖的催化氢化以制备糖醇。
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