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    Ethynylation process
    1.
    发明授权
    Ethynylation process 有权
    乙炔化过程

    公开(公告)号：US07638658B2

    公开(公告)日：2009-12-29

    申请号：US10524762

    申请日：2003-08-09

    申请人： Werner Bonrath ,  Peter Scheer ,  Johannes Tschumi ,  Reto Zenhaeusern

    发明人： Werner Bonrath ,  Peter Scheer ,  Johannes Tschumi ,  Reto Zenhaeusern

    IPC分类号： C07C33/04 ,  C07C33/042 ,  C07C33/28

    CPC分类号： C07C29/42 ,  C07C33/042 ,  C07C33/048

    摘要： A process for the manufacture of an acetylenically unsaturated alcohol comprising reacting formaldehyde, an aldehyde or a ketone (a carbonyl compound) with acetylene in the presence of ammonia and an alkali metal hydroxide, the molar ratio of the alkali metal hydroxide to the carbonyl compound being less than 1:200. The reaction products, which depending on the starting carbonyl compound are propargyl alcohol or 1-monosubstituted or 1,1-disubstituted derivatives thereof, are of use as intermediates in the synthesis of many useful end products, inter alia in the field of vitamins and carotenoids.

    摘要翻译： 一种制备炔属不饱和醇的方法，包括在氨和碱金属氢氧化物的存在下使甲醛，醛或酮（羰基化合物）与乙炔反应，碱金属氢氧化物与羰基化合物的摩尔比为 小于1：200。 取决于起始羰基化合物的反应产物是炔丙醇或其1-取代或1,1-二取代的衍生物，可用作合成许多有用的终产物的中间体，特别是在维生素和类胡萝卜素领域 。

    Ethynylation process
    2.
    发明申请
    Ethynylation process 有权
    乙炔化过程

    公开(公告)号：US20050240066A1

    公开(公告)日：2005-10-27

    申请号：US10524762

    申请日：2003-08-09

    申请人： Werner Bonrath ,  Peter Scheer ,  Johannes Tschumi ,  Reto Zenhaeusern

    发明人： Werner Bonrath ,  Peter Scheer ,  Johannes Tschumi ,  Reto Zenhaeusern

    IPC分类号： C07C29/38 ,  C07B61/00 ,  C07C29/42 ,  C07C33/042 ,  C07C33/048 ,  C07C33/04

    CPC分类号： C07C29/42 ,  C07C33/042 ,  C07C33/048

    摘要： A process for the manufacture of an acetylenically unsaturated alcohol comprising reacting formaldehyde, an aldehyde or a ketone (a carbonyl compound) with acetylene in the presence of ammonia and an alkali metal hydroxide, the molar ratio of the alkali metal hydroxide to the carbonyl compound being less than 1:200. The reaction products, which depending on the starting carbonyl compound are propargyl alcohol or 1-monosubstituted or 1,1-disubstituted derivatives thereof, are of use as intermediates in the synthesis of many useful end products, inter alia in the field of vitamins and carotenoids.

    摘要翻译： 一种制备炔属不饱和醇的方法，包括在氨和碱金属氢氧化物的存在下使甲醛，醛或酮（羰基化合物）与乙炔反应，碱金属氢氧化物与羰基化合物的摩尔比为 小于1：200。 取决于起始羰基化合物的反应产物是炔丙醇或其1-取代或1,1-二取代的衍生物，可用作合成许多有用的终产物的中间体，特别是在维生素和类胡萝卜素领域 。

    Process for preparing organic sulfur acids or salts thereof
    4.
    发明申请
    Process for preparing organic sulfur acids or salts thereof 失效
    制备有机硫酸或其盐的方法

    公开(公告)号：US20020161255A1

    公开(公告)日：2002-10-31

    申请号：US09959648

    申请日：2001-11-02

    发明人： Yasutaka Ishii ,  Tatsuya Nakano

    IPC分类号： C07C35/02 ,  C07C33/04

    CPC分类号： C07C303/14 ,  C07C2601/14 ,  C07C2601/18 ,  C07C2603/74 ,  C07C309/25 ,  C07C309/04

    摘要： A process for producing organic sulfur acid or a salt thereof of the present invention allows an organic substrate to react with a sulfur oxide in the presence of a metallic compound catalyst and in the absence of N-hydroxy and N-oxo cyclic imide compounds and thereby yields a corresponding organic sulfur acid or a salt thereof. Such organic substrates include, for example, (a) homocyclic or heterocyclic compounds having a methylene group, (b) compounds having a methine carbon atom, (c) compounds having a methyl group or methylene group at the adjacent position to an unsaturated bond, (d) non-aromatic heterocyclic compounds having a carbon-hydrogen bond at the adjacent position to a hetero atom, and (e) straight-chain alkanes. The sulfur oxide includes, for example, sulfur dioxide. This production process can efficiently produce an organic sulfur acid or a salt thereof under mild conditions.

    摘要翻译： 本发明的有机硫酸或其盐的制造方法使有机基材在金属化合物催化剂的存在下和在不存在N-羟基和N-氧代环状酰亚胺化合物的情况下与硫氧化物反应，从而 得到相应的有机硫酸或其盐。 这些有机底物包括例如（a）具有亚甲基的双环或杂环化合物，（b）具有次甲基碳原子的化合物，（c）在与不饱和键相邻的位置具有甲基或亚甲基的化合物， （d）在与杂原子相邻位置具有碳 - 氢键的非芳族杂环化合物，和（e）直链烷烃。 硫氧化物包括例如二氧化硫。 该生产方法可以在温和的条件下有效地生产有机硫酸或其盐。

    Process for the preparation of nitrophenyl hydroxy substituted acetylene and conversion to nitrophenylacetylene
    8.
    发明授权
    Process for the preparation of nitrophenyl hydroxy substituted acetylene and conversion to nitrophenylacetylene 失效
    制备硝基苯基羟基取代乙炔并转化为硝基苯乙炔的方法

    公开(公告)号：US4128588A

    公开(公告)日：1978-12-05

    申请号：US840553

    申请日：1977-10-11

    申请人： Edward T. Sabourin ,  Charles M. Selwitz

    发明人： Edward T. Sabourin ,  Charles M. Selwitz

    IPC分类号： C07B61/00 ,  B01J31/00 ,  C07C67/00 ,  C07C201/00 ,  C07C205/06 ,  C07C205/19 ,  C07C79/10 ,  C07C33/04

    CPC分类号： C07C201/12

    摘要： Nitrophenyl hydroxy substituted acetylene, which can be converted to nitrophenylacetylene is prepared by reacting a nitrobromobenzene with a substituted terminal acetylene compound containing at least three carbon atoms and a hydroxy group on the carbon atom adjacent to the acetylene group in the presence of a dialkyl or trialkyl amine solvent and a catalyst system consisting of a palladium complex containing two halogen moities and two tri-substituted phosphine moieties. A cuprous iodide promoter is also employed in the reaction sequence.

    摘要翻译： 可以通过使硝基溴苯与在乙炔相邻的碳原子上含有至少三个碳原子和羟基的取代的末端乙炔化合物在乙炔基的存在下反应来制备可以转化为硝基苯基乙炔的{PG，1Nitrophenyl羟基取代的乙炔 二烷基或三烷基胺溶剂和由含有两个卤素部分和两个三取代膦部分的钯络合物组成的催化剂体系。 在反应顺序中也使用碘化亚铜助催化剂。