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1.发明授权Asymmetrical bisbenzotriazoles substituted by a perfluoroalkyl moiety and compositions stabilized therewith 有权由全氟烷基部分取代的不对称双苯并三唑和用其稳定的组合物公开(公告)号：US06337402B2
公开(公告)日：2002-01-08
申请号：US09766822
申请日：2001-01-22
IPC分类号： C07D24920
CPC分类号： B32B17/10743 , C08K5/3475 , C09J11/06 , F24S23/82 , Y02E10/40
摘要： Asymmetrical bisbenzotriazoles of the formula I where G2′ is perfluoroalkyl of 1 to 12 carbon atoms, preferably CF3, and where G2 does not contain said group are red-shifted and due to the asymmetry are particularly soluble and useful in a host of applications including automotive coatings, thermoplastics and especially in adhesive compositions, themselves useful in solar panels and other laminate structures.
摘要翻译： 式I的不对称双苯并三唑，其中G2'是1至12个碳原子的全氟烷基，优选CF 3，并且其中不含有所述基团的G2是红移的，并且由于不对称性是特别可溶的并且可用于包括汽车涂料 ，热塑性塑料，特别是粘合剂组合物，本身可用于太阳能电池板和其他层压结构。
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公开(公告)号：US06245915B1
公开(公告)日：2001-06-12
申请号：US09550724
申请日：2000-04-17
IPC分类号： C07D24920
CPC分类号： B32B17/10743 , C08K5/3475 , C09J11/06 , F24S23/82 , Y02E10/40
摘要： Asymmetrical bis benzotriazoles of the formula I where G2′ is perfluoroalkyl of 1 to 12 carbon atoms, preferably CF3, and where G2 does not contain said group are red-shifted and due to the asymmetry are particularly soluble and useful in a host of applications including automotive coatings, thermoplastics and especially in adhesive compositions, themselves useful in solar panels and other laminate structures.
摘要翻译： 式I的不对称双苯并三唑，其中G2'是1至12个碳原子的全氟烷基，优选CF 3，并且其中不含有所述基团的G2是红移的，并且由于不对称性是特别可溶的并且在许多应用中是有用的，包括汽车 涂料，热塑性塑料，特别是粘合剂组合物，本身可用于太阳能电池板和其他层压结构。
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3.发明申请Benzotriazole/HALS molecular combinations and compositions stabilized therewith 失效苯并三唑/ HALS分子组合和组合物公开(公告)号：US20050043543A1
公开(公告)日：2005-02-24
申请号：US10939731
申请日：2004-09-13
申请人： Mervin Wood , Jacqueline Lau , Ramanathan Ravichandran , Andrea Smith , Joseph Suhadolnik , Peter Solera , Joseph Puglisi , Carmen Hendricks-Guy , Stephen Pastor , Luther Hall
发明人： Mervin Wood , Jacqueline Lau , Ramanathan Ravichandran , Andrea Smith , Joseph Suhadolnik , Peter Solera , Joseph Puglisi , Carmen Hendricks-Guy , Stephen Pastor , Luther Hall
IPC分类号： C07D249/20 , C07D401/06 , C07D401/10 , C07D401/12 , C07D403/10 , C08K5/3472 , C08K5/3475 , C08L101/00 , C09K3/00 , C09K15/08 , C09K15/20 , C09K15/30 , C09K15/32 , C11C5/00 , C07D249/16 , C07D43/02
CPC分类号： C07D401/06 , C07D401/10 , C07D401/12 , C08K5/3475
摘要： Compounds which have a benzotriazole and a hindered amine moiety in the same molecule are typified by the formula A wherein at least one of G2, R1 or R2 contains a hindered amine moiety are extremely effective light stabilizers having both the UV absorbing activity of a benzotriazole and the light stabilizing efficacy of a hindered amine in the same molecule. These compounds are effective stabilizers for thermoset resin compositions, thermoplastic resin compositions, for photographic applications, for pigmented or dyed polypropylene, polyamide or polyester fibers, and for white, dyed, dipped, unscented and/or scented candle wax against discoloration and fading when incorporated therein alone or in combination with an antioxidant.
摘要翻译： 在同一分子中具有苯并三唑和受阻胺部分的化合物以式A为代表，其中G2，R1或R2中的至少一个含有受阻胺部分是非常有效的具有苯并三唑的紫外线吸收活性的光稳定剂和 受阻胺在同一分子中的光稳定效力。 这些化合物是热固性树脂组合物，用于照相应用的热塑性树脂组合物，着色或染色的聚丙烯，聚酰胺或聚酯纤维以及白色，染色，浸渍，无色和/或有香味的蜡烛蜡的有效稳定剂，其在掺入时可防止变色和褪色 其中单独或与抗氧化剂组合。
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4.发明授权2H-benzotriazole UV absorders substituted with 1,1-diphenylalkyl groups and compositions stabilized therewith 失效2H-苯并三唑用1,1-二苯基烷基取代的UV绝缘体和用其稳定的组合物公开(公告)号：US06392056B1
公开(公告)日：2002-05-21
申请号：US09632218
申请日：2000-08-03
申请人： Mervin G. Wood , Ramanathan Ravichandran , Joseph Suhadolnik , David Bramer , Jacqueline Lau , Anthony DeBellis
发明人： Mervin G. Wood , Ramanathan Ravichandran , Joseph Suhadolnik , David Bramer , Jacqueline Lau , Anthony DeBellis
IPC分类号： C07D24920
CPC分类号： C07D249/20 , C08K5/3475
摘要： 2H-Benzotriazole UV absorbers substituted at the 3-position or at the 5-position of the phenyl ring by a 1,1-diphenylalkyl moiety, particularly a 1,1-diphenylethyl group, are particularly photostable in automotive coatings, and are of low color and exhibit low volatility in thermoplastic compositions.
摘要翻译： 在苯环的3位或5位被1,1-二苯基烷基部分，特别是1,1-二苯基乙基取代的2H-苯并三唑UV吸收剂在汽车涂料中特别光稳定，并且低 并且在热塑性组合物中表现出低挥发性。
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5.发明授权Benzotriazole/HALS molecular combinations and compositions stabilized therewith 失效苯并三唑/ HALS分子组合和组合物公开(公告)号：US07419513B2
公开(公告)日：2008-09-02
申请号：US10939731
申请日：2004-09-13
申请人： Mervin G. Wood , Jacqueline Lau , Ramanathan Ravichandran , Andrea R. Smith , Joseph Suhadolnik , Peter Solera , Joseph S. Puglisi , Carmen Hendricks-Guy , Stephen D. Pastor , Luther A. R. Hall
发明人： Mervin G. Wood , Jacqueline Lau , Ramanathan Ravichandran , Andrea R. Smith , Joseph Suhadolnik , Peter Solera , Joseph S. Puglisi , Carmen Hendricks-Guy , Stephen D. Pastor , Luther A. R. Hall
IPC分类号： C11C5/00
CPC分类号： C07D401/06 , C07D401/10 , C07D401/12 , C08K5/3475
摘要： Compounds which have a benzotriazole and a hindered amine moiety in the same molecule are typified by the formula A wherein at least one of G2, R1 or R2 contains a hindered amine moiety are extremely effective light stabilizers having both the UV absorbing activity of a benzotriazole and the light stabilizing efficacy of a hindered amine in the same molecule. These compounds are effective stabilizers for thermoset resin compositions, thermoplastic resin compositions, for photographic applications, for pigmented or dyed polypropylene, polyamide or polyester fibers, and for white, dyed, dipped, unscented and/or scented candle wax against discoloration and fading when incorporated therein alone or in combination with an antioxidant.
摘要翻译： 在同一分子中具有苯并三唑和受阻胺部分的化合物以式A为代表，其中G 2，R 1或R 2中的至少一个 含有受阻胺部分是具有苯并三唑的紫外线吸收活性和受阻胺在同一分子中的光稳定效能两者的非常有效的光稳定剂。 这些化合物是热固性树脂组合物，用于照相应用的热塑性树脂组合物，着色或染色的聚丙烯，聚酰胺或聚酯纤维以及白色，染色，浸渍，无色和/或有香味的蜡烛蜡的有效稳定剂，其在掺入时可防止变色和褪色 其中单独或与抗氧化剂组合。
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6.发明授权Benzotriazoles containing &agr;-cumyl groups substituted by heteroatoms and compositions stabilized therewith 失效含有被杂原子取代的α-异丙苯基的苯并三唑和用其稳定的组合物公开(公告)号：US06451887B1
公开(公告)日：2002-09-17
申请号：US09632216
申请日：2000-08-03
申请人： Mervin G. Wood , Joseph Suhadolnik , Ramanathan Ravichandran , Jacqueline Lau , Carmen Hendricks-Guy , Christophe Bulliard
发明人： Mervin G. Wood , Joseph Suhadolnik , Ramanathan Ravichandran , Jacqueline Lau , Carmen Hendricks-Guy , Christophe Bulliard
IPC分类号： C08K53475
CPC分类号： C08K5/3475 , C07D249/20
摘要： 2H-Benzotriazole UV absorbers substituted at the 3-position and/or the 5-position of the phenyl ring by &agr;-cumyl moiety which is substituted by a heteroatom are particularly photostable in automotive coatings, and are of low color and exhibit low volatility in thermoplastic compositions.
摘要翻译： 在苯环的3-位和/或5-位取代的2-苯并三唑UV吸收剂被被杂原子取代的α-枯基部分特别是在汽车涂料中是稳定的，并且颜色低，表现出低挥发性 热塑性组合物。
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7.发明授权Benzotriazole/hals molecular combinations and compositions stabilized therewith 失效苯并三唑/分子组合和用其稳定的组合物公开(公告)号：US06846929B2
公开(公告)日：2005-01-25
申请号：US09824147
申请日：2001-04-02
申请人： Mervin G. Wood , Jacqueline Lau , Ramanathan Ravichandran , Andrea R. Smith , Joseph Suhadolnik , Peter Solera , Joseph S. Puglisi , Carmen Hendricks-Guy , Stephen D. Pastor , Luther A. R. Hall
发明人： Mervin G. Wood , Jacqueline Lau , Ramanathan Ravichandran , Andrea R. Smith , Joseph Suhadolnik , Peter Solera , Joseph S. Puglisi , Carmen Hendricks-Guy , Stephen D. Pastor , Luther A. R. Hall
IPC分类号： C07D249/20 , C07D401/06 , C07D401/10 , C07D401/12 , C07D403/10 , C08K5/3472 , C08K5/3475 , C08L101/00 , C09K3/00 , C09K15/08 , C09K15/20 , C09K15/30 , C09K15/32 , C11C5/00
CPC分类号： C07D401/06 , C07D401/10 , C07D401/12 , C08K5/3475
摘要： Compounds which have a benzotriazole and a hindered amine moiety in the same molecule are typified by the formula A wherein at least one of G2, R1 or R2 contains a hindered amine moiety are extremely effective light stabilizers having both the UV absorbing activity of a benzotriazole and the light stabilizing efficacy of a hindered amine in the same molecule. These compounds are effective stabilizers for thermoset resin compositions, thermoplastic resin compositions, for photographic applications, for pigmented or dyed polypropylene, polyamide or polyester fibers, and for white, dyed, dipped, unscented and/or scented candle wax against discoloration and fading when incorporated therein alone or in combination with an antioxidant.
摘要翻译： 在同一分子中具有苯并三唑和受阻胺部分的化合物以式A为代表，其中G2，R1或R2中的至少一个含有受阻胺部分是非常有效的光稳定剂，其具有苯并三唑的UV吸收活性和 受阻胺在同一分子中的光稳定效力。 这些化合物是热固性树脂组合物，用于照相应用的热塑性树脂组合物，着色或染色的聚丙烯，聚酰胺或聚酯纤维以及白色，染色，浸渍，无色和/或有香味的蜡烛蜡的有效稳定剂，其在掺入时可防止变色和褪色 其中单独或与抗氧化剂组合。
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8.发明授权2H-benzotriazole UV absorbers substituted with 1,1-diphenylalkyl groups and compositions stabilized therewith 失效被1,1-二苯基烷基取代的2H-苯并三唑UV吸收剂和用其稳定的组合物公开(公告)号：US06489383B1
公开(公告)日：2002-12-03
申请号：US10071989
申请日：2002-02-07
申请人： Mervin G. Wood , Ramanathan Ravichandran , Joseph Suhadolnik , David Bramer , Jacqueline Lau , Anthony DeBellis
发明人： Mervin G. Wood , Ramanathan Ravichandran , Joseph Suhadolnik , David Bramer , Jacqueline Lau , Anthony DeBellis
IPC分类号： C08K534
CPC分类号： C07D249/20 , C08K5/3475
摘要： 2H-Benzotriazole UV absorbers substituted at the 3-position or at the 5-position of the phenyl ring by a 1,1-diphenylalkyl moiety, particularly a 1,1-diphenylethyl group, are particularly photostable in automotive coatings, and are of low color and exhibit low volatility in thermoplastic compositions.
摘要翻译： 在苯环的3位或5位被1,1-二苯基烷基部分，特别是1,1-二苯基乙基取代的2H-苯并三唑UV吸收剂在汽车涂料中特别光稳定，并且低 并且在热塑性组合物中表现出低挥发性。
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公开(公告)号：US20120009481A1
公开(公告)日：2012-01-12
申请号：US13235881
申请日：2011-09-19
CPC分类号： C08G65/333 , C08G73/0206 , C08G73/024 , C08J5/2256 , H01M8/1027 , H01M8/103 , H01M8/1072 , H01M10/0525 , H01M10/0565 , Y02P70/56
摘要： A room temperature crosslinkable polymer system comprising an anhydride containing polymer and an oxyalkylene amine and a polymer electrolyte derived therefrom are prepared and employed as ion conducting materials for batteries such as lithium ion battery, solar cells and electrochromic devices is disclosed.
摘要翻译： 制备包含含酸酐的聚合物和氧化烯胺和由其衍生的聚合物电解质的室温可交联聚合物体系，并且用作锂离子电池，太阳能电池和电致变色装置等电池的离子导电材料。
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公开(公告)号：US06566507B2
公开(公告)日：2003-05-20
申请号：US09871369
申请日：2001-05-31
申请人： Mervin G. Wood , Deborah DeHessa , Joseph Suhadolnik , Andrew B. Naughton , Jerome Sanders , Jacqueline Lau , Rong Xiong , Joseph Babiarz
发明人： Mervin G. Wood , Deborah DeHessa , Joseph Suhadolnik , Andrew B. Naughton , Jerome Sanders , Jacqueline Lau , Rong Xiong , Joseph Babiarz
IPC分类号： C09B4100
CPC分类号： C07D249/20 , C07C245/08
摘要： Provided is a process for preparing 2H-benzotriazole UV absorbers containing a perfluoroalkyl moiety at the 5-position of the benzo ring, for example a trifluoromethyl group, which involves diazotizing the perfluoroalkyl substituted o-nitroaniline using concentrated sulfuric acid plus sodium nitrite or nitrosylsulfuric acid to form the corresponding monoazobenzene intermediate via the diazonium salt intermediate which is reduced to the corresponding 5-perfluoroalkyl substituted 2H-benzotriazole UV absorber compound by conventional reduction means. Also provided is a novel one-pot, multiphase reaction for the preparation of 2(2-nitrophenylazo) substituted phenols, which are precursors for 2H-benzotriazole UV absorbers.
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