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1.发明授权Amorphous metal alloy compositions for reversible hydrogen storage and electrodes made therefrom 失效用于可逆储氢的无定形金属合金组合物和由其制成的电极
公开(公告)号：US4923770A
公开(公告)日：1990-05-08
申请号：US243109
申请日：1988-09-02
CPC分类号： C01B3/0052 , C01B3/0031 , C01B3/0047 , C01B3/0057 , C22C45/10 , H01M10/345 , H01M4/383 , Y02E60/327 , Y10S420/90
摘要： The present invention provides a novel amorphous metal alloy composition which reversibly stores hydrogen and is useful as the hydrogen storage electrode in an energy storage device. The amorphous metal alloy is made up of at least three elements with at least one element of Ag, Hg, or Pt; at least one element of Pb, Cu, Cr, Mo, W, Ni, Al, Co, Fe, Zn, Cd, Ru or Mn: and at least one element of Ca, Mg, Ti, Zr, Hf, Nb, V or Ta.
摘要翻译： 本发明提供了一种新颖的非晶态金属合金组合物，其可逆地储存氢气，并且可用作储能装置中的储氢电极。 无定形金属合金由至少三种元素与至少一种元素Ag，Hg或Pt组成; Pb，Cu，Cr，Mo，W，Ni，Al，Co，Fe，Zn，Cd，Ru或Mn中的至少一种元素：Ca，Mg，Ti，Zr，Hf，Nb， 或Ta。
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2.发明授权Electrolytic processes employing platinum based amorphous metal alloy oxygen anodes 失效采用铂基非晶态金属合金氧阳极的电解工艺
公开(公告)号：US4781803A
公开(公告)日：1988-11-01
申请号：US874617
申请日：1986-06-16
CPC分类号： H01M4/928 , C22C45/003 , H01M4/92 , H01M4/925 , H01M2004/8684
摘要： Improved electrolytic processes employing oxygen anodes. The improvement comprises the step of conducting a electrolysis process in an electrolytic cell having a platinum based amorphous metal alloy oxygen anode having the formulaPt.sub.p A.sub.a D.sub.dwhereA is Cr, Mo, W, Fe, Os, Ir, Cu, Ni, Rh, Pd, Ag, Ti, Ru, Nb, V, Ta, Au and mixtures thereof;D is B, C, Si, Al, Ge, P, As, Sb, Sn and mixtures thereof;p ranges from about 40 to 92;a ranges from about 0 to 40; andd ranges from about 8 to 60, with the proviso that p+a+d=100.
摘要翻译： 使用氧阳极的改进的电解方法。 该改进包括在具有式PtpAaDd的铂基非晶态金属合金氧阳极的电解槽中进行电解处理的步骤，其中A是Cr，Mo，W，Fe，Os，Ir，Cu，Ni，Rh，Pd， Ag，Ti，Ru，Nb，V，Ta，Au及其混合物; D是B，C，Si，Al，Ge，P，As，Sb，Sn及其混合物; p范围为约40至92; a在约0至40的范围内; 并且d的范围为约8至60，条件是p + a + d = 100。
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3.发明授权Anodes containing iridium based amorphous metal alloys and use thereof as halogen electrodes 失效含有铱基非晶态金属合金的阳极及其作为卤素电极的用途
公开(公告)号：US4705610A
公开(公告)日：1987-11-10
申请号：US867782
申请日：1986-05-27
CPC分类号： C22C45/003 , C25B11/0478 , C25B11/0494
摘要： Anodes comprising substrate materials coated with iridium based amorphous metal alloys having the formulaeIr.sub.i D.sub.d E.sub.e F.sub.fandIr.sub.i Y.sub.y D.sub.d E.sub.e F.sub.fwhereY is yttriumD is Ti, Zr, Y, Nb, Ta, Ru, W, Mo and mixtures thereof;E is C, B, Si, P, Al, Ge, As, N, Sb and mixtures thereof;F is Rh, Pt, Pd and mixtures thereof;i is 35 to 96 or 50 to 96, respectively;y is 4 to 40;d is 0 to 40;e is 4 to 40;f is 0 to 45; andi+d+e+f=100, i+y+d+e+f=100, and if E is Si and/or P, then B is also present.A process for the use of the foregoing iridium based alloys as anodes for the electrolysis of halide-containing electrolyte solutions is also provided.
摘要翻译： 包含具有式IriDdEeFf和IriYyDdEeFf的铱基非晶态金属合金的基体材料的阳极，其中Y是钇D是Ti，Zr，Y，Nb，Ta，Ru，W，Mo及其混合物; E是C，B，Si，P，Al，Ge，As，N，Sb及其混合物; F是Rh，Pt，Pd及其混合物; 我分别是35到96或50到96; y为4〜40; d为0〜40; e是4到40; f为0〜45; 并且i + d + e + f = 100，i + y + d + e + f = 100，并且如果E是Si和/或P，则B也存在。 还提供了使用上述铱基合金作为用于电解含卤化物的电解质溶液的阳极的方法。
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4.发明授权Method of forming amorphous metal alloy compositions for reversible hydrogen storage 失效形成用于可逆储氢的非晶态金属合金组合物的方法
公开(公告)号：US4814002A
公开(公告)日：1989-03-21
申请号：US143493
申请日：1988-01-13
CPC分类号： C01B3/0047 , B22F9/004 , C01B3/0031 , C01B3/0052 , C01B3/0057 , C22C45/10 , Y02E60/327 , Y10S420/90
摘要： Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; and M' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.
摘要翻译： 具有可逆储存氢能力的新型材料是式AaMbM'c的非晶金属合金，其中A是选自Ag，Au，Hg，Pd和Pt中的至少一种金属; M是选自Pb，Ru，Cu，Cr，Mo，Si，W，Ni，Al，Sn，Co，Fe，Zn，Cd，Ga和Mn中的至少一种金属; M'是选自Ca，Mg，Ti，Y，Zr，Hf，Nb，V，Ta和稀土中的至少一种金属; 并且其中a在大于0至约0.80的范围内; b范围从零到大约0.70; c在约0.08至约0.95的范围内; 其特征在于：（1）大部分的A设置在所述材料的表面上和/或（2）所述材料用作活性表面层，用于与包含可逆氢的大量储存材料一起吸附/解吸氢 储存材料。
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公开(公告)号：US4728580A
公开(公告)日：1988-03-01
申请号：US717428
申请日：1985-03-29
CPC分类号： C01B3/0047 , B22F9/004 , C01B3/0031 , C01B3/0052 , C01B3/0057 , C22C45/10 , Y02E60/327 , Y10S420/90 , Y10T428/12458 , Y10T428/12806 , Y10T428/12875 , Y10T428/12944
摘要： Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co. Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.
摘要翻译： 具有可逆储存氢能力的新型材料是式AaMbM'c的非晶金属合金，其中A是选自Ag，Au，Hg，Pd和Pt中的至少一种金属; M是选自Pb，Ru，Cu，Cr，Mo，Si，W，Ni，Al，Sn，Co，Fe，Zn，Cd，Ga和Mn中的至少一种金属; M'是选自Ca，Mg，Ti，Y，Zr，Hf，Nb，V，Ta和稀土中的至少一种金属; 并且其中a在大于0至约0.80的范围内; b范围从零到大约0.70; c在约0.08至约0.95的范围内; 其特征在于：（1）大部分的A设置在所述材料的表面上和/或（2）所述材料用作活性表面层，用于与包含可逆氢的大量储存材料一起吸附/解吸氢 储存材料。
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公开(公告)号：US4902579A
公开(公告)日：1990-02-20
申请号：US242095
申请日：1988-09-08
CPC分类号： C22C45/10 , B22F9/004 , C01B3/0031 , C01B3/0047 , C01B3/0052 , C01B3/0057 , Y02E60/327 , Y10S420/90 , Y10T428/12458 , Y10T428/12806 , Y10T428/12875 , Y10T428/12944
摘要： Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.
摘要翻译： 具有可逆储存氢能力的新型材料是式AaMbM'c的非晶金属合金，其中A是选自Ag，Au，Hg，Pd和Pt中的至少一种金属; M是选自Pb，Ru，Cu，Cr，Mo，Si，W，Ni，Al，Sn，Co，Fe，Zn，Cd，Ga和Mn中的至少一种金属; M'是选自Ca，Mg，Ti，Y，Zr，Hf，Nb，V，Ta和稀土中的至少一种金属; 并且其中a在大于0至约0.80的范围内; b范围从零到大约0.70; c在约0.08至约0.95的范围内; 其特征在于：（1）大部分的A设置在所述材料的表面上和/或（2）所述材料用作活性表面层，用于与包含可逆氢的大量储存材料一起吸附/解吸氢 储存材料。
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公开(公告)号：US4609442A
公开(公告)日：1986-09-02
申请号：US748023
申请日：1985-06-24
申请人： Michael A. Tenhover , Richard S. Henderson , Jonathan H. Harris , Robert K. Grasselli , Michael D. Ward
发明人： Michael A. Tenhover , Richard S. Henderson , Jonathan H. Harris , Robert K. Grasselli , Michael D. Ward
CPC分类号： C25B11/04 , C25B11/0447
摘要： Amorphous metal alloys have the formulaM.sup.1.sub.a M.sup.2.sub.b M.sup.3.sub.cwhereM.sup.1 is Fe, Co, Ni, Pd and combination thereof;M.sup.2 is Ti, Zr, Hf, V, Nb, Ta and combination thereof;M.sup.3 is Rh, Os, Ir, Pt and combinations thereof;a ranges from about 0 to 60;b ranges from about 10 to 70; andc ranges from about 5 to 70, with the proviso that a+b+c=100.These alloys have utility as anodes in electrolytic processes and a process for the generation of halogens from halide-containing solutions includes a step of conducting electrolysis of the solutions in an electrolytic cell having an amorphous metal alloy anode of the formulaM.sup.1.sub.a M.sup.2.sub.b M.sup.3.sub.c.
摘要翻译： 无定形金属合金具有式M1aM2bM3c，其中M1是Fe，Co，Ni，Pd及其组合; M2是Ti，Zr，Hf，V，Nb，Ta及其组合; M3是Rh，Os，Ir，Pt及其组合; a范围为约0至60; b的范围为约10至70; 且c的范围为约5至70，条件是a + b + c = 100。 这些合金在电解方法中具有阳极的用途，并且从含卤素溶液中产生卤素的方法包括在具有式M1aM2bM3c的非晶金属合金阳极的电解池中进行电解电解的步骤。
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8.发明授权Electrolysis of halide-containing solutions with platinum based amorphous metal alloy anodes 失效用铂类非晶态金属合金阳极电解含卤化物溶液
公开(公告)号：US4560454A
公开(公告)日：1985-12-24
申请号：US705687
申请日：1985-02-26
IPC分类号： C02F1/461 , C02F1/467 , C22C45/00 , C25B11/04 , C25B11/08 , H01M4/86 , H01M4/90 , H01M4/92 , C25B1/24
CPC分类号： H01M4/928 , C02F1/46109 , C22C45/003 , C25B11/0478 , H01M4/90 , H01M4/92 , H01M4/925 , C02F1/4674 , C02F2001/46138 , H01M2004/8684
摘要： A process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having a platinum based amorphous metal alloy anode having the formulaPt.sub.p A.sub.a D.sub.dwhereA is Cr, Mo, W, Fe, Os, Cu, Ni, Ag, V, Au and mixtures thereof;D is B, Si, Al, Ge, P, As, Sb, Sn and mixtures thereof;p ranges from about 40 to 92;a ranges from about 0 to 40; andd ranges from about 8 to 60, with the proviso that p+a+d=100.Such amorphous metal alloy anodes are also based on the formulaPt.sub.p E.sub.e F.sub.fwhereE is Cr, Mo, W, Fe, Os, Ir, Cu, Ni, Rh, Pd, Ag, Ti, Ru, Nb, V, Ta, Au and mixtures thereof;F is B, Al, Ge, As, Sb, Sn and mixtures thereof;p ranges from about 40 to 92;e ranges from about 0 to 40; andf ranges from about 8 to 60, with the proviso that p+e+f=100.
摘要翻译： 用于从含卤素溶液中产生卤素的方法包括在具有式PtpAaDd的铂基非晶态金属合金阳极的电解池中进行电解电解的步骤，其中A是Cr，Mo，W，Fe，Os， Cu，Ni，Ag，V，Au及其混合物; D是B，Si，Al，Ge，P，As，Sb，Sn及其混合物; p范围为约40至92; a在约0至40的范围内; 并且d的范围为约8至60，条件是p + a + d = 100。 这种无定形金属合金阳极也基于式PtpEeFf，其中E是Cr，Mo，W，Fe，Os，Ir，Cu，Ni，Rh，Pd，Ag，Ti，Ru，Nb，V，Ta，Au和混合物 的; F是B，Al，Ge，As，Sb，Sn及其混合物; p范围为约40至92; e范围为约0至40; f为约8至60，条件是p + e + f = 100。
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公开(公告)号：US4615967A
公开(公告)日：1986-10-07
申请号：US700428
申请日：1985-02-11
CPC分类号： G11B7/243 , G11B2007/24312 , G11B2007/24316 , G11B2007/24324 , G11B7/2531 , G11B7/257
摘要： A thin film device for recording information in readable form that decreases its light absorbancy in response to increased temperature. The film includes two elements from column IVa of the Periodic Table, such as silicon, germanium, tin and lead, bound with one of or a mixture of sulfur and selenium.The as-deposited inventive materials contain tetrahedral units, some ethane-like units and some rings and chains. Upon heating the ethane-like units are converted to rings and chains and tetrahedral units producing a dramatically decreased light absorbancy. The materials are stable at relatively high operating temperatures.
摘要翻译： 用于记录可读形式的信息的薄膜装置，其响应于升高的温度降低其光吸收。 该膜包括周期表列IVa中的两个元素，例如硅，锗，锡和铅，与硫和硒中的一种或其混合物结合。 沉积的本发明材料包含四面体单元，一些乙烷样单元和一些环和链。 在加热时，乙烷样单元转化成环和链和四面体单元，产生显着降低的光吸收。 材料在较高的工作温度下是稳定的。
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公开(公告)号：US4696703A
公开(公告)日：1987-09-29
申请号：US755247
申请日：1985-07-15
CPC分类号： C22C45/006
摘要： An amorphous metal alloy composition exhibiting corrosion resistance in acidic environments of the formula:Cr.sub.a M.sub.b B.sub.c C.sub.d R.sub.ewhereinM is at least one metal selected from the group consisting of Mo, W, Nb and Ta;R is at least one element selected from the group consisting of N, P, As, S and Se; andwhereina ranges from about greater than 0.4 to about 0.6;b ranges from about 0.15 to about less than 0.4; andc ranges from zero to about 0.16.d ranges from zero to about 0.2; ande ranges from zero to about 0.3;with the proviso that the sum of (c+d+e) ranges from about 0.04 to about 0.35.
摘要翻译： 一种在酸性环境中具有耐腐蚀性的无定形金属合金组合物，其结构式如下：CraMbBcCdRe其中M是选自Mo，W，Nb和Ta中的至少一种金属; R是选自N，P，As，S和Se中的至少一种元素; 并且其中a在约大于0.4至约0.6的范围内; b在约0.15至约小于0.4的范围内; c范围从零到大约0.16。 d范围从零到约0.2; e范围从0到约0.3; 条件是（c + d + e）的和为约0.04至约0.35。
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