High density renewable fuels based on the selective dimerization of pinenes
    2.
    发明授权
    High density renewable fuels based on the selective dimerization of pinenes 有权
    基于蒎烯选择性二聚的高密度可再生燃料

    公开(公告)号:US08227651B1

    公开(公告)日:2012-07-24

    申请号:US12550973

    申请日:2009-08-31

    IPC分类号: C07C13/28

    摘要: An effective method for producing high density fuel candidates from pinenes is provided. MMT-K10 is an efficient catalyst for the reaction, although significant amounts of p-cymene and camphene produced as byproducts limit the overall yield to about 80%. Nafion is also an excellent catalyst for pinene dimerization and was capable of producing dimers in up to 90% yield. Pinene dimers synthesized with these heterogenous catalysts have a density and net heat of combustion comparable to JP-10. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.

    摘要翻译: 提供了从蒎烯生产高密度燃料候选物的有效方法。 MMT-K10是用于反应的有效催化剂,尽管作为副产物产生的显着量的对甲基异丙基苯和camp烯将总产率限制在约80%。 Nafion也是蒎烯二聚化的优异催化剂,能够以高达90%的产率生产二聚体。 与这些异质催化剂合成的蒎烯二聚体具有与JP-10相当的密度和净燃烧热。 要强调的是,该摘要被提供以符合要求抽象的规则,允许搜索者或其他读者快速确定技术公开内容的主题。 提交它的理解是,它不会用于解释或限制权利要求的范围。

    Process and apparatus for the selective dimerization of terpenes and alpha-olefin oligomers with a single-stage reactor and a single-stage fractionation system
    5.
    发明授权
    Process and apparatus for the selective dimerization of terpenes and alpha-olefin oligomers with a single-stage reactor and a single-stage fractionation system 有权
    用单级反应器和单级分馏系统选择性二聚萜烯和α-烯烃低聚物的方法和设备

    公开(公告)号:US09266792B2

    公开(公告)日:2016-02-23

    申请号:US13426393

    申请日:2012-03-21

    IPC分类号: C10L1/16 C07C2/28 C07C5/03

    摘要: An improved process and apparatus for the selective reaction of terpenes (including mono-, sesqui-, di-terpenes, and others in the terpene family), alpha-olefin oligomers (OOA's), and related olefins to their respective dimeric product in high purity using heterogeneous acid catalyst concurrent with full utilization of energy created in the process. Embodiments of the invention carry out a unique and highly efficient dimerization of terpenes, alpha-olefin oligomers (OOA's), and olefins using cost effective catalysts and low cost equipment that are ideally suited for commercialization of jet/turbine and diesel biofuel processes producing fuels with high flashpoints and superb cold flow properties.

    摘要翻译: 一种用于萜烯(包括萜烯族中的单,双缩三萜烯,二萜烯等),α-烯烃低聚物(OOA's)和相关烯烃选择性反应的改进方法和装置,其各自的二聚产物具有高纯度 使用异构酸催化剂同时充分利用能源创造的过程。 本发明的实施方案使用成本有效的催化剂和低成本设备来实现萜烯,α-烯烃低聚物(OOA)和烯烃的独特且高效的二聚体,其理想地适用于生产燃料的喷射/涡轮机和柴油生物燃料过程的商业化 高闪点和极好的冷流特性。

    Diesel and Jet Fuels Based on the Oligomerization of Butene
    7.
    发明申请
    Diesel and Jet Fuels Based on the Oligomerization of Butene 有权
    基于丁烯低聚的柴油和喷气燃料

    公开(公告)号:US20120209045A1

    公开(公告)日:2012-08-16

    申请号:US12511796

    申请日:2009-07-29

    IPC分类号: C07C2/08 B01J31/14

    摘要: A renewable biofuel based on a highly efficient batch catalysis methodology for conversion of 1-butene to a new class of potential jet fuel blends. By tuning the catalyst and then using the dimer produced, the carbon use is about 95% or greater. This latter point will be particularly important in the future, where the source of raw materials (i.e., biomass/biofeedstock) is limited. Also noteworthy, the batch catalysis approach disclosed requires a minimal input of energy and hydrogen to make fuels that possess useful flash points, coldflow properties, and solution density/energy content. This new process affords a saturated hydrocarbon fuel that has a high solution density and thus possesses a higher calculated power density (per volume) than similar fuels made by the GTL Fischer-Tropsch processes. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.

    摘要翻译: 基于用于将1-丁烯转化为新型潜在喷气燃料混合物的高效批量催化方法的可再生生物燃料。 通过调节催化剂然后使用所生产的二聚体,碳的使用量约为95%或更高。 后一点在未来将是特别重要的,其中原料来源(即生物质/生物饲料)是有限的。 还值得注意的是,所公开的批量催化方法需要能量和氢的最小输入以制备具有有用闪点,冷流特性和溶液密度/能量含量的燃料。 该新方法提供了具有高溶液密度的饱和烃燃料,因此具有比由GTL费 - 托方法制备的类似燃料更高的计算功率密度(每体积)。 要强调的是,该摘要被提供以符合要求抽象的规则,允许搜索者或其他读者快速确定技术公开内容的主题。 提交它的理解是,它不会用于解释或限制权利要求的范围。

    HIGH DENSITY RENEWABLE FUELS BASED ON THE SELECTIVE DIMERIZATION OF PINENES
    8.
    发明申请
    HIGH DENSITY RENEWABLE FUELS BASED ON THE SELECTIVE DIMERIZATION OF PINENES 有权
    高密度可再生能源燃料基于PINENES的选择性二次化

    公开(公告)号:US20120205284A1

    公开(公告)日:2012-08-16

    申请号:US12550973

    申请日:2009-08-31

    IPC分类号: C10L1/04 C10G63/04

    摘要: An effective method for producing high density fuel candidates from pinenes is provided. MMT-K10 is an efficient catalyst for the reaction, although significant amounts of p-cymene and camphene produced as byproducts limit the overall yield to about 80%. Nafion is also an excellent catalyst for pinene dimerization and was capable of producing dimers in up to 90% yield. Pinene dimers synthesized with these heterogenous catalysts have a density and net heat of combustion comparable to JP-10. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.

    摘要翻译: 提供了从蒎烯生产高密度燃料候选物的有效方法。 MMT-K10是用于反应的有效催化剂,尽管作为副产物产生的显着量的对甲基异丙基苯和camp烯将总产率限制在约80%。 Nafion也是蒎烯二聚化的优异催化剂,能够以高达90%的产率生产二聚体。 与这些异质催化剂合成的蒎烯二聚体具有与JP-10相当的密度和净燃烧热。 要强调的是,该摘要被提供以符合要求抽象的规则,允许搜索者或其他读者快速确定技术公开内容的主题。 提交它的理解是,它不会用于解释或限制权利要求的范围。