摘要:
The present invention relates to elastic articles comprising a crosslinked or crosslinkable ethylene polymer and a method for making the same. In particular, the invention relates to a shaped article (e.g. film or fiber) characterized by improved elasticity at elevated temperatures and comprising a substantially cured, irradiated, or crosslinked (or curable, irradiated or crosslinkable) homogeneously branched ethylene polymer. The improved elastic article of the present invention is particularly suitable for use in applications where good elasticity must be maintained at elevated temperatures such as, for example, personal hygiene items and disposable infection-control garments at body temperatures of about 100° F. (38° C.).
摘要:
The present invention relates to elastic articles comprising a crosslinked or crosslinkable ethylene polymer and a method for making the same. In particular, the invention relates to a shaped article (e.g. film or fiber) characterized by improved elasticity at elevated temperatures and comprising a substantially cured, irradiated, or crosslinked (or curable, irradiated or crosslinkable) homogeneously branched ethylene polymer. The improved elastic article of the present invention is particularly suitable for use in applications where good elasticity must be maintained at elevated temperatures such as, for example, personal hygiene items and disposable infection-control garments at body temperatures of about 100° F. (38° C.).
摘要:
The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.
摘要翻译:本发明涉及由包含至少一种氢化嵌段共聚物和任选的至少一种其它聚合物制备的纤维,所述其它聚合物选自反应性定制的液体聚氨酯,弹性体或磺化乙烯/乙烯基芳族互聚物, 弹性体乙烯/ C 3 -C 20α-烯烃互聚物,C 3 -C 20α-烯烃/共轭二烯互聚物,弹性聚丙烯聚合物,增强聚丙烯聚合物,弹性体热塑性聚氨酯,弹性共聚酯,部分氢化嵌段共聚物,弹性体 聚酰胺,羟基官能化聚醚(或聚醚胺),苯乙烯/共轭二烯互聚物和弹性体茂金属催化的合成聚合物或其共混物或配制体系。
摘要:
Durable stretch fabrics are made and processed from one or more crosslinked, heat-resistant olefin elastic fibers, e.g., a substantially linear, homogeneously branched ethylene polymer. The fabrics can be made by any process, e.g., weaving, knitting, etc., and from any combination of crosslinked, heat-resistant olefin elastic and inelastic (“hard”) fibers, e.g., cotton and wool. These fabrics exhibit excellent chemical, e.g., chlorine, resistance and durability, e.g., they retain their shape and feel (“hand”) over repeated exposure to processing conditions, e.g., stone-washing, dye-stripping, PET-dyeing and the like, and service conditions, e.g., washing, drying, etc.
摘要:
The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.). The elastic article (or articles) comprises a homogeneously branched ethylene interpolymer (preferably a substantially linear ethylene interpolymer), a substantially hydrogenated block polymer, or a combination of the two. The heat-resistant elastic articles (especially fibers) are useful in various durable or repeated-use fabric applications such as, but not limited to, clothing, under-garments, and sports apparel. The heat-resistant elastic fibers can be conveniently formed into fabrics using well-known techniques such as, for example, by using co-knitting techniques with cotton, nylon, and/or polyester fibers.
摘要:
A reversible, heat-set covered fiber is described, the covered fiber comprising: A. A core comprising an elastic fiber comprising a substantially crosslinked, temperature-stable, olefin polymer, and B. A cover comprising an inelastic fiber. The fiber is heat-set by a method comprising: (a) Stretching the covered fiber by applying a stretching force to the covered fiber; (b) Heating the stretched covered fiber of (a) to a temperature in excess of the crystalline melting point of the olefin polymer for a period of time sufficient to at least partially melt the olefin polymer; (c) Cooling the stretched and heated covered fiber of (b) to a temperature below the crystalline melting point of the olefin polymer for a period of time sufficient to solidify the polymer; and (d) Removing the stretching force from the covered fiber.
摘要:
The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.). The elastic article (or articles) comprises a homogeneously branched ethylene interpolymer (preferably a substantially linear ethylene interpolymer), a substantially hydrogenated block polymer, or a combination of the two. The heat-resistant elastic articles (especially fibers) are useful in various durable or repeated-use fabric applications such as, but not limited to, clothing, under-garments, and sports apparel. The heat-resistant elastic fibers can be conveniently formed into fabrics using well-known techniques such as, for example, by using co-knitting techniques with cotton, nylon, and/or polyester fibers.
摘要:
Durable stretch fabrics are made and processed from one or more crosslinked, heat-resistant olefin elastic fibers, e.g., a substantially linear, homogeneously branched ethylene polymer. The fabrics can be made by any process, e.g., weaving, knitting, etc., and from any combination of crosslinked, heat-resistant olefin elastic and inelastic (“hard”) fibers, e.g., cotton and wool. These fabrics exhibit excellent chemical, e.g., chlorine, resistance and durability, e.g., they retain their shape and feel (“hand”) over repeated exposure to processing conditions, e.g., stone-washing, dye-stripping, PET-dyeing and the like, and service conditions, e.g., washing, drying, etc.
摘要:
The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.
摘要:
Fibers having improved resistance to moisture at elevated temperatures comprise at least two elastic polymers, one polymer heat-settable and the other polymer heat-resistant, the heat-resistant polymer comprising at least a portion of the exterior surface of the fiber. The fibers typically have a bicomponent and/or a biconstituent core/sheath morphology. Typically, the core comprises an elastic thermoplastic urethane, and the sheath comprises a homogeneously branched polyolefin, preferably a homogeneously branched substantially linear ethylene polymer.