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公开(公告)号：US20090182183A1
公开(公告)日：2009-07-16
申请号：US12014406
申请日：2008-01-15
申请人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
发明人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
IPC分类号： C07C2/24
CPC分类号： C07C2/10 , C07C2521/06 , C07C2523/30 , Y02P20/52
摘要： A process for the oligomerization of propylene is disclosed wherein a tungstated zirconia catalyst prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms useful for preparing neo acids.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中在反应蒸馏区中在温度和压力条件下使用制备为蒸馏结构的钨酸氧化锆催化剂，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性，以用于制备新酸的优选异构形式。
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公开(公告)号：US07649123B2
公开(公告)日：2010-01-19
申请号：US12014406
申请日：2008-01-15
申请人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
发明人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
IPC分类号： C07C2/10
CPC分类号： C07C2/10 , C07C2521/06 , C07C2523/30 , Y02P20/52
摘要： A process for the oligomerization of propylene is disclosed wherein a tungstated zirconia catalyst prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms useful for preparing neo acids.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中在反应蒸馏区中在温度和压力条件下使用制备为蒸馏结构的钨酸氧化锆催化剂，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性，以用于制备新酸的优选异构形式。
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公开(公告)号：US07189887B2
公开(公告)日：2007-03-13
申请号：US11010990
申请日：2004-12-13
IPC分类号： C07C6/00
CPC分类号： C07C7/14883 , Y10S203/06
摘要： A process for the reduction of naphthalene in process streams containing alkylaromatic solvents. Naphthalene is contacted with alkylbenzenes in a distillation column reactor in the presence of transalkylation catalyst to produce alkylnaphthalenes which are concurrently separated by fractional distillation as bottoms and the alkylbenzenes are separated as overheads.
摘要翻译： 一种在含有烷基芳族溶剂的工艺流中还原萘的方法。 在烷基转移催化剂存在下，萘在烷基苯中与烷基苯接触以产生烷基萘，其同时通过分馏作为底部分离并且烷基苯作为塔顶馏分分离。
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公开(公告)号：US20080064911A1
公开(公告)日：2008-03-13
申请号：US11518372
申请日：2006-09-08
IPC分类号： C07C4/04
CPC分类号： C07C2/12 , Y02P20/127
摘要： A process for the oligomerization of propylene is disclosed wherein MCM-22 zeolite prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中作为蒸馏结构制备的MCM-22沸石在温度和压力的条件下用于反应蒸馏区，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性以获得优选的异构形式。
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公开(公告)号：US07615673B2
公开(公告)日：2009-11-10
申请号：US11518372
申请日：2006-09-08
IPC分类号： C07C2/02
CPC分类号： C07C2/12 , Y02P20/127
摘要： A process for the oligomerization of propylene is disclosed wherein MCM-22 zeolite prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中作为蒸馏结构制备的MCM-22沸石在温度和压力的条件下用于反应蒸馏区，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性以获得优选的异构形式。
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公开(公告)号：US07507868B2
公开(公告)日：2009-03-24
申请号：US10509530
申请日：2003-03-28
申请人： Carolyn B. Duncan , Raphael Frans Caers , David W. Turner , Michael J. Keenan , Ernest E. Green , Ramzi Y. Saleh
发明人： Carolyn B. Duncan , Raphael Frans Caers , David W. Turner , Michael J. Keenan , Ernest E. Green , Ramzi Y. Saleh
IPC分类号： C07C2/12
CPC分类号： C07C303/06 , C07B37/02 , C07C2/12 , C07C2/66 , C07C29/16 , C07C2529/70 , C07C15/107 , C07C31/125 , C07C309/31
摘要： In a process for oligomerizing a C2 to C6 n-olefin feedstock over surface deactivated ZSM-23, the feedstock contains from about 0.1 wt % to about 25 wt % of an iso-olefin and the C12+ fraction of the oligomerized olefin product contains less than 0.5 atom % of quaternary carbon atoms.
摘要翻译： 在通过表面失活的ZSM-23使C2至C6-烯烃原料低聚的方法中，原料含有约0.1wt％至约25wt％的异烯烃，并且低聚烯烃产物的C12 +馏分含有少于 0.5原子％的季碳原子。
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公开(公告)号：US07145049B2
公开(公告)日：2006-12-05
申请号：US10898506
申请日：2004-07-23
申请人： Mitchell E. Loescher , David G. Woods , Michael J. Keenan , Steven E. Silverberg , Paul W. Allen
发明人： Mitchell E. Loescher , David G. Woods , Michael J. Keenan , Steven E. Silverberg , Paul W. Allen
CPC分类号： C07C2/12 , C07C2529/70 , Y02P20/127 , C07C11/02
摘要： Alkenes, such as normal butenes in a mixed C4 stream are oligomerized, preferably to dimers, which are dimerized in a distillation column reactor over ZSM-57 zeolite catalyst at high conversions and high selectivity to octenes. Prior to oligomerization the mixed C4 stream is pretreated to remove dimethyl ether, butadienes and sulfur compounds.
摘要翻译： 烯烃，例如混合的C 4 H 4流中的正丁烯通过ZSM-57沸石催化剂在蒸馏塔反应器中以高转化率和对辛烯的高选择性被二聚体低聚，优选二聚体。 在低聚之前，将混合的C 4 H 3流预处理以除去二甲醚，丁二烯和硫化合物。
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公开(公告)号：US5731486A
公开(公告)日：1998-03-24
申请号：US503134
申请日：1995-07-17
CPC分类号： C07C2/30 , C07C11/113 , C07C51/14
摘要： A method for producing 3-methyl-2-pentene which is substantially free of any other C.sub.6 olefin, except 2-ethyl-1-butene, by first producing a stream that contains 2-ethyl-1-butene from the trimerization of ethylene, and second by recovering the 2-ethyl-1-butene as 3-methyl-2-pentene via etherification, separation of the ether, and decomposition of the ether back to predominantly 3-methyl-2-pentene with some 2-ethyl-1-butene.
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公开(公告)号：US06255262B1
公开(公告)日：2001-07-03
申请号：US09188849
申请日：1998-11-09
IPC分类号： C10M10538
CPC分类号： C10M105/40 , C07C67/26 , C10M2207/289 , C10N2240/00 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/14 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C07C69/30
摘要： A process for reproducibly forming a thermally and oxidatively stable high hydroxyl glycerol di-ester compound which is particularly useful as a lubricant. The glycerol di-ester compound is formed by reacting a glycidyl ester with an excess of a neo acid salt. The di-ester product is produced in a nearly quantitative conversion and is readily recoverable from the reaction mixture via a water wash, vacuum dry, and a mild wiped film evaporator treatment.
摘要翻译： 一种可重复形成热和氧化稳定的高羟基甘油二酯化合物的方法，其特别用作润滑剂。 甘油二酯化合物通过使缩水甘油酯与过量的新酸盐反应形成。 二酯产物以几乎定量的转化率生产，并且通过水洗，真空干燥和温和的擦膜蒸发器处理容易地从反应混合物中回收。
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公开(公告)号：US5463157A
公开(公告)日：1995-10-31
申请号：US146374
申请日：1993-10-29
IPC分类号： C07C1/20 , C07C2/30 , C07C11/113 , C07C41/06 , C07C51/14 , C07C2/04 , C07C2/24 , C07C2/26 , C07C2/34
CPC分类号： C07C2/30 , C07C1/20 , C07C11/113 , C07C41/06 , C07C51/14 , C07C2521/04 , C07C2521/16 , C07C2529/06 , C07C2531/02 , C07C2531/08 , C07C2531/14 , Y02P30/42
摘要： A method for producing 3-methyl-2-pentene which is substantially free of any other C.sub.6 olefin, except 2-ethyl-1-butene, by first producing a stream that contains 2-ethyl-1-butene from the trimerization of ethylene, and second by recovering the 2-ethyl-1-butene as 3-methyl-2-pentene via etherification, separation of the ether, and decomposition of the ether back to predominantly 3-methyl-2-pentene with some 2-ethyl-1-butene.
摘要翻译： 通过首先从乙烯的三聚反应产生含有2-乙基-1-丁烯的物流，生产除2-乙基-1-丁烯之外基本上不含任何其它C 6烯烃的3-甲基-2-戊烯的方法， 其次是通过醚化作为3-甲基-2-戊烯回收2-乙基-1-丁烯，乙醚的分离和乙醚的分解回到主要是3-甲基-2-戊烯与一些2-乙基-1 丁烯。
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