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1.
公开(公告)号:US12043588B2
公开(公告)日:2024-07-23
申请号:US18536405
申请日:2023-12-12
CPC分类号: C07C2/10 , B01J21/04 , B01J21/08 , B01J21/16 , B01J37/0215 , B01J37/20 , B01J37/26 , C07C2521/12
摘要: Oligomer products are produced by reacting an alpha olefin and a vinylidene compound in the presence of a solid catalyst, such as a solid oxide or a chemically-treated solid oxide. Metallocene compounds, organoaluminum compounds, and BF3 are not needed to perform the reaction. Oligomer products formed by processes disclosed herein have a trimer:tetramer weight ratio of at least 2:1.
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公开(公告)号:US20210213428A1
公开(公告)日:2021-07-15
申请号:US16319674
申请日:2017-06-22
发明人: Jan Mattheus BOTHA , Denzil James MOODLEY , Jana Heloise POTGIETER , Hendrik VAN RENSBURG , Jan VAN DE LOOSDRECHT , Prabashini MOODLEY
摘要: The present invention relates to catalysts, more particularly to a cobalt-containing catalyst composition. The present invention further relates to a process for preparing a cobalt-containing catalyst precursor, a process for preparing a cobalt-containing catalyst, and a hydrocarbon synthesis process wherein such a catalyst is used. According to a first aspect of the invention, there is provided a cobalt-containing catalyst composition comprising cobalt and/or a cobalt compound supported on and/or in a silica (SiO2) catalyst support wherein the average pore diameter of the catalyst support is more than 20 nm but less than 50 nm; the catalyst composition also including a titanium compound on and/or in the catalyst support, and a manganese compound on and/or in the catalyst support.
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公开(公告)号:US20210162373A1
公开(公告)日:2021-06-03
申请号:US17109515
申请日:2020-12-02
摘要: Oligomerization catalyst and method for oligomerization using the catalyst. The catalyst comprises a single Zn(II) or Ga(III) metal ion center directly bonded to a support through a shared oxygen atom, the catalyst having at least one M-O bond which forms an active site for oligomerization. The method includes reacting one or more C2 to C12 olefins with the oligomerization catalyst at a temperature of about 200° C. or higher to provide an oligomer product comprising C4 to C26 olefins.
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公开(公告)号:US20200172451A1
公开(公告)日:2020-06-04
申请号:US16639160
申请日:2018-08-13
IPC分类号: C07C2/10 , B01J27/04 , B01J27/043 , B01J12/00
摘要: Methods, catalysts, and systems for the production of 1,3-butadiene from a reaction mixture including ethylene and gaseous sulfur are described.
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公开(公告)号:US10654770B2
公开(公告)日:2020-05-19
申请号:US16324634
申请日:2017-08-18
发明人: Kun Wang , Lorenzo C. DeCaul , James R. Lattner
摘要: Disclosed herein are processes for producing neopentane. The processes generally relate to demethylating diisobutylene to produce neopentane. The diisobutylene may be provided by the dimerization of isobutylene.
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公开(公告)号:US10336663B2
公开(公告)日:2019-07-02
申请号:US15701577
申请日:2017-09-12
发明人: Graham R. Lief , Eric J. Haschke , Pasquale Iacono
IPC分类号: C07C2/04 , C07C2/06 , C07C2/08 , C07C2/10 , C07C5/03 , C07C5/05 , C07C2/32 , B01J31/14 , B01J31/22 , B01J8/18 , B01J21/12
摘要: The present invention discloses processes for oligomerizing an olefin feedstock containing C4 to C20 alpha olefins using a catalyst system containing a metallocene compound, an organoaluminum compound, and a suspension of a chemically-treated solid oxide. The liquid medium for the suspension of the chemically-treated solid oxide can be an alpha-olefin oligomer product formed by the oligomerization process.
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7.
公开(公告)号:US20180208524A1
公开(公告)日:2018-07-26
申请号:US15873421
申请日:2018-01-17
发明人: Faisal H. Alshafei , Munir D. Khokhar , Noor A. Sulais , Mohammed R. Alalouni , Sohel K. Shaikh
摘要: Embodiments of processes and multiple-stage catalyst systems for producing propylene comprising introducing a hydrocarbon stream comprising 2-butene to an isomerization catalyst zone to isomerize the 2-butene to 1-butene, passing the 2-butene and 1-butene to a metathesis catalyst zone to cross-metathesize the 2-butene and 1-butene into a metathesis product stream comprising propylene and C4-C6 olefins, and cracking the metathesis product stream in a catalyst cracking zone to produce propylene. The isomerization catalyst zone comprises a silica-alumina catalyst with a ratio by weight of alumina to silica from 1:99 to 20:80. The metathesis catalyst comprises a mesoporous silica catalyst support impregnated with metal oxide. The catalyst cracking zone comprises a mordenite framework inverted (MFI) structured silica catalyst.
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公开(公告)号:US20180127331A1
公开(公告)日:2018-05-10
申请号:US15860700
申请日:2018-01-03
发明人: Qing Yang , Uriah J. Kilgore , Max P. McDaniel , Brooke L. Small , Kenneth D. Hope , Eduardo J. Baralt
CPC分类号: C07C2/10 , C07C9/15 , C07C2521/04 , C07C2527/053 , C07C2527/06 , C07C2527/10 , C07C2527/12 , C07C11/02
摘要: The present invention discloses processes for oligomerizing a monomer containing C3 to C30 olefins using a chemically-treated solid oxide, such as fluorided silica-coated alumina and fluorided-chlorided silica-coated alumina.
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公开(公告)号:US20170174584A1
公开(公告)日:2017-06-22
申请号:US14977728
申请日:2015-12-22
发明人: Qing Yang , Uriah J. Kilgore , Max P. McDaniel , Brooke L. Small , Kenneth D. Hope , Eduardo J. Baralt
CPC分类号: C07C2/10 , C07C9/15 , C07C2521/04 , C07C2527/053 , C07C2527/06 , C07C2527/10 , C07C2527/12 , C07C11/02
摘要: Oligomerization processes include the steps of introducing a monomer containing a C3 to C30 olefin and a chemically-treated solid oxide into a reaction zone, and oligomerizing the monomer to form an oligomer product in the reaction zone. Fluorided silica-coated alumina and fluorided-chlorided silica-coated alumina are illustrative chemically-treated solid oxides that can be used in the oligomerization processes.
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公开(公告)号:US09682898B2
公开(公告)日:2017-06-20
申请号:US14901177
申请日:2014-06-25
IPC分类号: C07C2/08 , C07C2/10 , C10G50/00 , C07C4/02 , C07C5/03 , C07C5/48 , C07C29/04 , C07C41/06 , C07C45/50 , C07D305/10
CPC分类号: C07C2/08 , C07C2/10 , C07C4/02 , C07C5/03 , C07C5/48 , C07C29/04 , C07C41/06 , C07C45/505 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2523/755 , C07C2529/76 , C07D305/10 , C10G50/00 , C10G2300/1092 , C10G2400/02 , C10G2400/22 , C07C11/02
摘要: An OCTOL process is disclosed which by limitation of the conversion in its individual oligomerization steps is set up particularly for the productive utilization of C4 feedstock mixtures with a low 1-butene content and which nevertheless yields a C8 product mixture having an Iso index suitable for the preparation of plasticizer alcohols.
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