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公开(公告)号：US07189887B2
公开(公告)日：2007-03-13
申请号：US11010990
申请日：2004-12-13
IPC分类号： C07C6/00
CPC分类号： C07C7/14883 , Y10S203/06
摘要： A process for the reduction of naphthalene in process streams containing alkylaromatic solvents. Naphthalene is contacted with alkylbenzenes in a distillation column reactor in the presence of transalkylation catalyst to produce alkylnaphthalenes which are concurrently separated by fractional distillation as bottoms and the alkylbenzenes are separated as overheads.
摘要翻译： 一种在含有烷基芳族溶剂的工艺流中还原萘的方法。 在烷基转移催化剂存在下，萘在烷基苯中与烷基苯接触以产生烷基萘，其同时通过分馏作为底部分离并且烷基苯作为塔顶馏分分离。
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公开(公告)号：US07145049B2
公开(公告)日：2006-12-05
申请号：US10898506
申请日：2004-07-23
申请人： Mitchell E. Loescher , David G. Woods , Michael J. Keenan , Steven E. Silverberg , Paul W. Allen
发明人： Mitchell E. Loescher , David G. Woods , Michael J. Keenan , Steven E. Silverberg , Paul W. Allen
CPC分类号： C07C2/12 , C07C2529/70 , Y02P20/127 , C07C11/02
摘要： Alkenes, such as normal butenes in a mixed C4 stream are oligomerized, preferably to dimers, which are dimerized in a distillation column reactor over ZSM-57 zeolite catalyst at high conversions and high selectivity to octenes. Prior to oligomerization the mixed C4 stream is pretreated to remove dimethyl ether, butadienes and sulfur compounds.
摘要翻译： 烯烃，例如混合的C 4 H 4流中的正丁烯通过ZSM-57沸石催化剂在蒸馏塔反应器中以高转化率和对辛烯的高选择性被二聚体低聚，优选二聚体。 在低聚之前，将混合的C 4 H 3流预处理以除去二甲醚，丁二烯和硫化合物。
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公开(公告)号：US20090182183A1
公开(公告)日：2009-07-16
申请号：US12014406
申请日：2008-01-15
申请人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
发明人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
IPC分类号： C07C2/24
CPC分类号： C07C2/10 , C07C2521/06 , C07C2523/30 , Y02P20/52
摘要： A process for the oligomerization of propylene is disclosed wherein a tungstated zirconia catalyst prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms useful for preparing neo acids.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中在反应蒸馏区中在温度和压力条件下使用制备为蒸馏结构的钨酸氧化锆催化剂，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性，以用于制备新酸的优选异构形式。
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公开(公告)号：US07649123B2
公开(公告)日：2010-01-19
申请号：US12014406
申请日：2008-01-15
申请人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
发明人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
IPC分类号： C07C2/10
CPC分类号： C07C2/10 , C07C2521/06 , C07C2523/30 , Y02P20/52
摘要： A process for the oligomerization of propylene is disclosed wherein a tungstated zirconia catalyst prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms useful for preparing neo acids.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中在反应蒸馏区中在温度和压力条件下使用制备为蒸馏结构的钨酸氧化锆催化剂，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性，以用于制备新酸的优选异构形式。
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公开(公告)号：US07615673B2
公开(公告)日：2009-11-10
申请号：US11518372
申请日：2006-09-08
IPC分类号： C07C2/02
CPC分类号： C07C2/12 , Y02P20/127
摘要： A process for the oligomerization of propylene is disclosed wherein MCM-22 zeolite prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中作为蒸馏结构制备的MCM-22沸石在温度和压力的条件下用于反应蒸馏区，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性以获得优选的异构形式。
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公开(公告)号：US20080064911A1
公开(公告)日：2008-03-13
申请号：US11518372
申请日：2006-09-08
IPC分类号： C07C4/04
CPC分类号： C07C2/12 , Y02P20/127
摘要： A process for the oligomerization of propylene is disclosed wherein MCM-22 zeolite prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms.
摘要翻译： 公开了一种用于丙烯低聚的方法，其中作为蒸馏结构制备的MCM-22沸石在温度和压力的条件下用于反应蒸馏区，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离 在蒸馏塔反应器中进行分馏。 与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性以获得优选的异构形式。
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公开(公告)号：US07488861B2
公开(公告)日：2009-02-10
申请号：US11082263
申请日：2005-03-17
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C2529/70 , C07C2531/08 , Y02P20/127 , Y10S203/06 , C07C15/085 , C07C15/02
摘要： Cumene and secondary butyl benzene are produced simultaneously in a distillation column reactor by feeding propylene, butylene and benzene to the reactor. Unreacted benzene is removed as overheads and cumene and secondary butyl benzene are removed as products. The catalysts used are acid cation exchange resins, zeolites, particularly beta zeolite.
摘要翻译： 在蒸馏塔反应器中同时产生枯烯和仲丁基苯，将丙烯，丁烯和苯进料到反应器中。 未反应的苯作为塔顶馏出物除去，异丙苯和仲丁基苯作为产物被除去。 所使用的催化剂是酸性阳离子交换树脂，沸石，特别是β沸石。
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公开(公告)号：US20090069608A1
公开(公告)日：2009-03-12
申请号：US11853351
申请日：2007-09-11
申请人： Christopher C. Boyer , Mitchell E. Loescher , Willibrord A. Groten , Mario J. Maraschino , Kerry L. Rock
发明人： Christopher C. Boyer , Mitchell E. Loescher , Willibrord A. Groten , Mario J. Maraschino , Kerry L. Rock
IPC分类号： C07C41/08
CPC分类号： C07C41/06 , Y02P20/127 , C07C43/046
摘要： A process for the production of tertiary ethers, including: feeding a hydrocarbon stream comprising isoolefins and propionitrile to a distillation column reactor system containing at least one etherification reaction zone; feeding a C2 to C6 monoalcohol or mixture thereof to the distillation column reactor; concurrently in the distillation column reactor system: reacting a portion of the isoolefins with a portion of the alcohols to form a tertiary ether; and separating the tertiary ether from unreacted isoolefins; withdrawing the tertiary ether and propionitrile from the distillation column reactor system as a bottoms; withdrawing the unreacted isoolefins from the distillation column reactor system as an overheads; and operating the distillation column reactor system such that the etherification reaction zone is substantially free of propionitrile.
摘要翻译： 一种生产叔醚的方法，包括：将含有异烯烃和丙腈的烃流进料到含有至少一个醚化反应区的蒸馏塔反应器系统中; 将C2至C6一元醇或其混合物加入蒸馏塔反应器中; 同时在蒸馏塔反应器系统中：使一部分异烯烃与一部分醇反应形成叔乙醚; 并将叔醚与未反应的异烯烃分离; 从蒸馏塔反应器系统中取出叔醚和丙腈作为底部物质; 从蒸馏塔反应器系统中取出未反应的异烯烃作为塔顶馏出物; 并操作蒸馏塔反应器系统，使得醚化反应区基本上不含丙腈。
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公开(公告)号：US07553995B2
公开(公告)日：2009-06-30
申请号：US11853351
申请日：2007-09-11
申请人： Christopher C. Boyer , Mitchell E. Loescher , Willibrord A. Groten , Mario J. Maraschino , Kerry L. Rock
发明人： Christopher C. Boyer , Mitchell E. Loescher , Willibrord A. Groten , Mario J. Maraschino , Kerry L. Rock
CPC分类号： C07C41/06 , Y02P20/127 , C07C43/046
摘要： A process for the production of tertiary ethers, including: feeding a hydrocarbon stream comprising isoolefins and propionitrile to a distillation column reactor system containing at least one etherification reaction zone; feeding a C2 to C6 monoalcohol or mixture thereof to the distillation column reactor; concurrently in the distillation column reactor system: reacting a portion of the isoolefins with a portion of the alcohols to form a tertiary ether; and separating the tertiary ether from unreacted isoolefins; withdrawing the tertiary ether and propionitrile from the distillation column reactor system as a bottoms; withdrawing the unreacted isoolefins from the distillation column reactor system as an overheads; and operating the distillation column reactor system such that the etherification reaction zone is substantially free of propionitrile.
摘要翻译： 一种生产叔醚的方法，包括：将含有异烯烃和丙腈的烃流进料到含有至少一个醚化反应区的蒸馏塔反应器系统中; 将C2至C6一元醇或其混合物加入蒸馏塔反应器中; 同时在蒸馏塔反应器系统中：使一部分异烯烃与一部分醇反应形成叔乙醚; 并将叔醚与未反应的异烯烃分离; 从蒸馏塔反应器系统中取出叔醚和丙腈作为底部物质; 从蒸馏塔反应器系统中取出未反应的异烯烃作为塔顶馏出物; 并操作蒸馏塔反应器系统，使得醚化反应区基本上不含丙腈。
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公开(公告)号：US08395002B2
公开(公告)日：2013-03-12
申请号：US12720173
申请日：2010-03-09
IPC分类号： C07C5/09
CPC分类号： C10G45/32 , C07C7/04 , C07C7/163 , C07C15/04 , C10G2400/30 , Y02P20/127 , Y02P20/132
摘要： A process for recovering benzene, the process including: feeding hydrogen and a hydrocarbon fraction comprising benzene, components lighter than benzene, components heavier than benzene, and diolefins to a catalytic distillation reactor system comprising at least one reaction zone comprising a hydrogenation catalyst; concurrently in the catalytic distillation reactor system: contacting the diolefins and hydrogen in the presence of the hydrogenation catalyst to selectively hydrogenate at least a portion of the diolefins; and fractionating the hydrocarbon fraction to form a fraction comprising benzene and other C6 hydrocarbons, and a heavies fraction comprising C7+ hydrocarbons; recovering the heavies fraction from the first catalytic distillation reactor system as a bottoms fraction; and withdrawing the fraction comprising benzene and other C6 hydrocarbons from the catalytic distillation reactor system as a benzene concentrate fraction.
摘要翻译： 一种回收苯的方法，该方法包括将包含苯，比苯轻的组分，比苯重的组分和二烯烃的氢气和烃馏分进料到包含至少一个包含氢化催化剂的反应区的催化蒸馏反应器系统; 同时在催化蒸馏反应器系统中：在氢化催化剂的存在下使二烯烃和氢气接触以选择性氢化至少一部分二烯烃; 并分馏烃馏分以形成包含苯和其它C 6烃的馏分，以及包含C7 +烃的重馏分; 从第一催化蒸馏反应器系统中回收重质馏分作为塔底馏分; 并从催化蒸馏反应器系统中抽出包含苯和其它C 6烃的馏分作为苯浓缩物馏分。
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