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1.发明授权Optical article containing a transmission medium exhibiting a high level of second order polarization susceptibility 失效含有表现出高水平二阶极化敏感性的传输介质的光学制品
公开(公告)号：US4886339A
公开(公告)日：1989-12-12
申请号：US101897
申请日：1987-09-28
CPC分类号： G02F1/377 , G02F1/065 , G02F1/3615
摘要： An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The molecular dipoles are held in polar alignment by a crosslinked polymeric binder.
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2.发明授权Optical article exhibiting a high level of second order polarization susceptibility 失效表现出高水平二阶极化敏感性的光学制品
公开(公告)号：US4792208A
公开(公告)日：1988-12-20
申请号：US101888
申请日：1987-09-28
申请人： Abraham Ulman , David J. Williams , Thomas L. Penner , Douglas R. Robello , Jay S. Schildkraut , Michael Scozzafava , Craig S. Willand
发明人： Abraham Ulman , David J. Williams , Thomas L. Penner , Douglas R. Robello , Jay S. Schildkraut , Michael Scozzafava , Craig S. Willand
CPC分类号： B82Y20/00 , G02B1/08 , G02F1/065 , G02F1/3613 , G02F1/3617 , G02F1/3618 , Y10S430/10 , Y10S430/122
摘要： An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of polar aligned noncentrosymmetric molecular dipoles. The molecular dipoles have an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor sulfonyl moiety.
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公开(公告)号：US4946235A
公开(公告)日：1990-08-07
申请号：US419818
申请日：1989-10-11
申请人： Michael Scozzafava , Phat T. Dao , Douglas R. Robello , Jay S. Schildkraut , Craig S. Willand , David J. Williams
发明人： Michael Scozzafava , Phat T. Dao , Douglas R. Robello , Jay S. Schildkraut , Craig S. Willand , David J. Williams
CPC分类号： G02F1/065 , Y10T428/31504
摘要： An optical article is disclosed containing contiguously overlying an organic layer for the nonlinear propagation of electromagnetic radiation an amorphous transmission enhancement layer of at least 0.5 .mu.m in thickness transmissive to the nonlinearly propagated electromagnetic radiation, exhibiting a refractive index less than that of the organic layer, and comprised of a low molecular weight aromatic compound.
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4.发明授权Optical article containing a linear polymer exhibiting a high level of second order polymerization susceptibility 失效含有显示高水平二级聚合敏感性的线性聚合物的光学制品
公开(公告)号：US4900127A
公开(公告)日：1990-02-13
申请号：US241740
申请日：1988-09-08
CPC分类号： G02F1/065 , C08F8/00 , G02F1/3613
摘要： An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of a linear polymer containing as pendant groups polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The linear polymer contains repeating units derived from vinyl addition polymerization, at least 5 percent of the repeating units incorporate the molecular dipoles as pendant groups, and the molecular dipoles include a sulfonyl electron acceptor moiety.
摘要翻译： 公开了一种光学制品，其包含用于传输电磁辐射的介质，其显示出大于10-9个静电单元的介质，所述静电单元包含由包含作为侧基极性取向的非中心对称分子偶极子的线性聚合物组成，所述非对称非对称性分子偶极子具有通过 与电子受体部分的共轭π键合系统，以允许在表现出第一偶极矩的基态和表现出不同偶极矩的激发态之间振荡分子偶极子。 线性聚合物含有衍生自乙烯基加成聚合的重复单元，至少5％的重复单元引入作为侧基的分子偶极子，分子偶极子包括磺酰基电子受体部分。
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5.发明授权Optical article containing a polymeric matrix exhibiting a high level of second order polarization susceptibility 失效含有表现出高水平二阶极化敏感性的聚合物基质的光学制品
公开(公告)号：US4796971A
公开(公告)日：1989-01-10
申请号：US101886
申请日：1987-09-28
CPC分类号： G02F1/3617 , G02B6/126 , G02F1/3613 , G02F1/3616
摘要： An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of organic polar aligned noncentrosymmetric molecular dipoles. The molecular dipoles form repeating units in a crosslinked polymeric matrix.
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公开(公告)号：US5501821A
公开(公告)日：1996-03-26
申请号：US19815
申请日：1993-02-19
CPC分类号： G02F1/3613 , G02F1/361 , G02F1/3617
摘要： An optical article, for the transmission of electromagnetic radiation. The optical article includes a medium, which exhibits a second-order electric susceptibility greater than 10.sup.-9 electrostatic units. The medium includes polar aligned dipole subunits. Each dipole subunit has a plurality of noncentrosymmetric molecular dipoles and a connector system. Each molecular dipole has an electron donor moiety, an electron acceptor moiety, and a linking moiety. The linking moiety has a pair of covalent bonds to the connector system. Each molecular dipole has a conjugated .pi. bonding system extending from the electron donor moiety along the linking moiety to the electron acceptor moiety to permit oscillation of the molecular dipole between a ground state and an excited state, which states differ in polarity. The connector system joins the linking moieties to complete a solitary ring or a system of fused rings, which retain the molecular dipoles in substantially parallel relative relation.
摘要翻译： 一种用于传输电磁辐射的光学制品。 光学制品包括介质，其表现出大于10-9静电单位的二次电磁化率。 介质包括极性对准的偶极子单元。 每个偶极子单元具有多个非中心对称分子偶极子和连接器系统。 每个分子偶极子具有电子供体部分，电子受体部分和连接部分。 连接部分与连接器系统具有一对共价键。 每个分子偶极具有从电子供体部分沿着连接部分延伸到电子受体部分的共轭π键合体系，以允许分子偶极子在基态和激发态之间的振荡，其状态极性不同。 连接器系统连接连接部分以完成孤立环或稠环系统，其将分子偶极保持为基本平行的相对关系。
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公开(公告)号：US5008043A
公开(公告)日：1991-04-16
申请号：US494376
申请日：1990-03-16
CPC分类号： B82Y20/00 , G02F1/3613 , G02F1/3615 , G02F1/3617 , G02F1/3618
摘要： An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of polar aligned noncentrosymmetric molecular dipoles. The molecular dipoles have a hydrophobic electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor sulfonyl moiety. The electron acceptor sulfonyl moiety includes at least two halogen substitutents of its .alpha. carbon atom.
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8.发明授权Optical article containing a linear condensation polymer exhibiting a high level of second order polarization susceptibility 失效包含线性聚合聚合物的光学文章展示了高级别的第二阶段极化可靠性
公开(公告)号：US5075043A
公开(公告)日：1991-12-24
申请号：US402725
申请日：1989-09-05
CPC分类号： G02F1/065 , G02F1/3616 , G02F1/377
摘要： An optical article is disclosed containing, for the transmission of electromagnetic radiation, a medium exhibiting a second order polarization susceptibility greater than 10.sup.-9 electrostatic units comprised of a linear polymer containing polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipole between a ground state exhibiting a first dipole moment and an excited state exhibiting a differing dipole moment. The linear polymer is a condensation polymer including in its backbone a plurality of molecular dipoles including sulfonyl electron acceptor moieties sequentially arranged to reinforce electron displacement along the polymer backbone.
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9.发明授权Optical article containing a polymer exhibiting a high level of second order polarization susceptibility 失效含有显示高水平二阶极化敏感性的聚合物的光学制品
公开(公告)号：US5410630A
公开(公告)日：1995-04-25
申请号：US154940
申请日：1993-11-18
CPC分类号： G02F1/3617
摘要： An optical article exhibits effects attributable to the nonlinear second order polarizability of electromagnetic radiation and comprises a polymer containing within its repeating units polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipoles between a ground state exhibiting a first dipole moment and an excited state exhibiting a different dipole moment, characterized in that the molecular dipoles include as an acceptor moiety a vinyl group geminally substituted by two strong electron withdrawing groups, at least one of which is a sulfonyl moiety.
摘要翻译： 光学制品表现出归因于电磁辐射的非线性二阶极化率的效果，并且包括在其重复单元内包含极性对准的非中心对称分子偶极子的聚合物，其具有通过共轭π键合系统连接到电子受体部分的电子给体部分，以允许振荡 表现出第一偶极矩的基态和表现出不同偶极矩的激发态之间的分子偶极子，其特征在于分子偶极子包括作为受体部分的由两个强吸电子基团取代的乙烯基，其中至少一个 是磺酰基部分。
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10.发明授权Optical article containing a polymer that exhibits nonlinear second order polarization susceptibility 失效含有显示非线性二阶极化敏感性的聚合物的光学制品
公开(公告)号：US5381507A
公开(公告)日：1995-01-10
申请号：US154804
申请日：1993-11-18
CPC分类号： G02F1/3617 , G02F1/3613
摘要： An optical article exhibits effects attributable to the nonlinear second order polarizability of electromagnetic radiation and comprises a polymer containing within its repeating units polar aligned noncentrosymmetric molecular dipoles having an electron donor moiety linked through a conjugated .pi. bonding system to an electron acceptor moiety to permit oscillation of the molecular dipoles between a ground state exhibiting a first dipole moment and an excited state exhibiting a different dipole moment, characterized in that the molecular dipoles include as an acceptor moiety a vinyl group geminally substituted by two strong electron withdrawing groups, at least one of which is a perfluoroalkylsulfonyl moiety.
摘要翻译： 光学制品表现出归因于电磁辐射的非线性二阶极化率的效果，并且包括在其重复单元内包含极性对准的非中心对称分子偶极子的聚合物，其具有通过共轭π键合系统连接到电子受体部分的电子给体部分，以允许振荡 表现出第一偶极矩的基态和表现出不同偶极矩的激发态之间的分子偶极子，其特征在于分子偶极子包括作为受体部分的由两个强吸电子基团取代的乙烯基，其中至少一个 是全氟烷基磺酰基部分。
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