公开(公告)号：US20060160958A1

公开(公告)日：2006-07-20

申请号：US11278459

申请日：2006-04-03

申请人： Naiyong Jing ,  Michael Yandrasits ,  Steven Hamrock

发明人： Naiyong Jing ,  Michael Yandrasits ,  Steven Hamrock

IPC分类号： C08F120/08

CPC分类号： B01D67/0093 ,  B01D69/141 ,  B01D71/32 ,  B01D2323/30 ,  C08F214/18 ,  C08F214/26 ,  C08J5/2237 ,  C08J2327/18 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/106 ,  H01M8/1081 ,  H01M8/1088 ,  Y02P70/56

摘要： A method is provided for obtaining crosslinked polymers having pendent sulfonic acid groups by crosslinking through the sulfonic acid groups or their precursors with aromatic crosslinkers or aromatic pendent crosslinking groups to form aromatic sulfones. Such crosslinked polymers may be used to make polymer electrolyte membranes (PEM's) that may be used in electrolytic cells such as fuel cells.

摘要翻译： 提供了一种通过使用芳族交联剂或芳族侧链交联基团通过磺酸基团或其前体进行交联以形成芳族砜来获得具有侧链磺酸基团的交联聚合物的方法。 这种交联聚合物可用于制备可用于诸如燃料电池的电解池中的聚合物电解质膜（PEM's）。

公开(公告)号：US20050107490A1

公开(公告)日：2005-05-19

申请号：US10712590

申请日：2003-11-13

申请人： Michael Yandrasits ,  Steven Hamrock ,  Klaus Hintzer ,  Arne Thaler ,  Tatsuo Fukushi ,  Naiyong Jing ,  Kai Lochhaas

发明人： Michael Yandrasits ,  Steven Hamrock ,  Klaus Hintzer ,  Arne Thaler ,  Tatsuo Fukushi ,  Naiyong Jing ,  Kai Lochhaas

IPC分类号： B01D67/00 ,  B01D71/32 ,  B01D71/36 ,  B01D71/82 ,  C08F114/26 ,  C08F214/26 ,  C08J3/28 ,  C08J5/22 ,  H01M8/10 ,  C08G2/00

CPC分类号： C08J5/225 ,  B01D67/009 ,  B01D71/32 ,  B01D71/82 ,  C08F114/26 ,  C08J3/28 ,  C08J2327/18 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  H01M8/1088 ,  H01M2300/0082 ,  Y02P70/56

摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, as well as the polymer so made, the method comprising application of electron beam radiation to a highly fluorinated fluoropolymer comprising: a backbone derived in part from tetrafluoro-ethylene monomer, first pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH or —O−M+, where M+ is a monovalent cation, and second pendent groups which include Br, Cl or I. Typically, the membrane has a thickness of 90 microns or less, more typically 60 or less, and most typically 30 microns or less.

摘要翻译： 提供了一种用于制造交联聚合物电解质的方法，该电解质通常是在诸如燃料电池的电解槽中用作聚合物电解质膜的膜形式，以及如此制备的聚合物，该方法包括施加电子束 辐射到高度氟化的含氟聚合物，其包含：部分由四氟乙烯单体衍生的主链，第一侧基，其包括根据式-SO 2 X的基团，其中X是F，Cl，Br ，OH或-O - ，其中M +是单价阳离子，第二侧基包括Br，Cl或I. 通常，膜具有90微米或更小，更通常为60或更小，最通常为30微米或更小的厚度。

公开(公告)号：US20050107489A1

公开(公告)日：2005-05-19

申请号：US10712589

申请日：2003-11-13

申请人： Michael Yandrasits ,  Steven Hamrock ,  Werner Grootaert ,  Miguel Guerra ,  Naiyong Jing

发明人： Michael Yandrasits ,  Steven Hamrock ,  Werner Grootaert ,  Miguel Guerra ,  Naiyong Jing

IPC分类号： C08J5/22 ,  C08G2/00

CPC分类号： C08J5/225 ,  C08J2327/12

摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1-15 carbon atoms and 0-4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.

摘要翻译： 提供了一种制备交联聚合物电解质的方法，通常是通过聚合物悬浮在基团上的腈基的三聚作用，在电解池如燃料电池中用作聚合物电解质膜的膜形式。 所得聚合物电解质膜包括高度氟化的聚合物，其包含：全氟化骨架，包含磺酸基团的第一侧基和包含根据下式的三价基团的交联：第一侧基通常根据下式：-R

公开(公告)号：US20050113528A1

公开(公告)日：2005-05-26

申请号：US10720906

申请日：2003-11-24

申请人： Naiyong Jing ,  Michael Yandrasits ,  Steven Hamrock

发明人： Naiyong Jing ,  Michael Yandrasits ,  Steven Hamrock

IPC分类号： B01D67/00 ,  B01D69/12 ,  B01D69/14 ,  B01D71/32 ,  B01D71/36 ,  B01D71/82 ,  C08F214/18 ,  C08F214/26 ,  C08J5/22 ,  H01M2/16 ,  H01M8/02 ,  H01M8/10 ,  C08F14/18

CPC分类号： B01D67/0093 ,  B01D69/141 ,  B01D71/32 ,  B01D2323/30 ,  C08F214/18 ,  C08F214/26 ,  C08J5/2237 ,  C08J2327/18 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/106 ,  H01M8/1081 ,  H01M8/1088 ,  Y02P70/56

摘要： A method is provided for obtaining crosslinked polymers having pendent sulfonic acid groups by crosslinking through the sulfonic acid groups or their precursors with aromatic crosslinkers or aromatic pendent crosslinking groups to form aromatic sulfones. Such crosslinked polymers may be used to make polymer electrolyte membranes (PEM's) that may be used in electrolytic cells such as fuel cells.

摘要翻译： 提供了一种通过使用芳族交联剂或芳族侧链交联基团通过磺酸基团或其前体进行交联以形成芳族砜来获得具有侧链磺酸基团的交联聚合物的方法。 这种交联聚合物可用于制备可用于诸如燃料电池的电解池中的聚合物电解质膜（PEM's）。

公开(公告)号：US20050131097A1

公开(公告)日：2005-06-16

申请号：US10733211

申请日：2003-12-11

申请人： Naiyong Jing ,  Steven Hamrock ,  Michael Yandrasits

发明人： Naiyong Jing ,  Steven Hamrock ,  Michael Yandrasits

IPC分类号： C08F14/18 ,  C08F214/18 ,  C08F214/26 ,  C08J3/28 ,  C08J5/22 ,  C08G2/00

CPC分类号： C08J3/28 ,  C08F14/18 ,  C08J5/225 ,  C08J2327/12

摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, as well as the polymer so made, the method comprising application of ultraviolet radiation to a highly fluorinated fluoropolymer comprising: a backbone derived in part from tetrafluoro-ethylene monomer, first pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH or —O−M+, where M+ is a monovalent cation, and second pendent groups which include Br, Cl or I. Typically, the membrane has a thickness of 90 microns or less, more typically 60 or less, and most typically 30 microns or less.

摘要翻译： 提供了一种制造交联聚合物电解质的方法，该电解质通常是在诸如燃料电池的电解槽中用作聚合物电解质膜的膜形式，以及如此制备的聚合物，该方法包括施加紫外线辐射 涉及一种高度氟化的含氟聚合物，其包含：部分由四氟乙烯单体衍生的主链，第一侧基，其包括根据式-SO 2 X的基团，其中X为F，Cl，Br， OH或-O - ，其中M + +是一价阳离子，第二侧基包括Br，Cl或I.通常 ，膜的厚度为90微米或更小，更通常为60或更小，最通常为30微米或更小。

公开(公告)号：US20070142563A1

公开(公告)日：2007-06-21

申请号：US11668270

申请日：2007-01-29

申请人： Michael Yandrasits ,  Steven Hamrock ,  Naiyong Jing

发明人： Michael Yandrasits ,  Steven Hamrock ,  Naiyong Jing

IPC分类号： C08F214/18

CPC分类号： C08J5/2293 ,  C08J2327/18 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  Y02P70/56

摘要： A method of making a crosslinked polymer is provided as well as the polymer so made, the method comprising the steps of: providing a highly fluorinated fluoropolymer, typically a perfluorinated fluoropolymer, comprising pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH, or —O−M+, where M+ is a monovalent cation, and exposing said fluoropolymer to electron beam radiation so as to result in the formation of crosslinks. Typically, the method according to the present invention additionally comprises the step of: forming said fluoropolymer into a membrane, typically having a thickness of 90 microns or less, more typically 60 microns or less, and most typically 30 microns or less.

摘要翻译： 提供制备交联聚合物的方法以及如此制备的聚合物，该方法包括以下步骤：提供高度氟化的含氟聚合物，通常为全氟化含氟聚合物，其包含侧基，其包括根据式-SO _{2 X，其中X是F，Cl，Br，OH或-O - ，其中M + 是单价阳离子，并将所述含氟聚合物暴露于电子束辐射，从而导致交联的形成。 通常，根据本发明的方法另外包括以下步骤：将所述含氟聚合物形成膜，通常具有90微米或更小，更典型地为60微米或更小，最通常为30微米或更小的厚度。}

公开(公告)号：US20060205829A1

公开(公告)日：2006-09-14

申请号：US11419515

申请日：2006-05-22

申请人： Michael Yandrasits ,  Steven Hamrock ,  Werner Grootaert ,  Miguel Guerra ,  Naiyong Jing

发明人： Michael Yandrasits ,  Steven Hamrock ,  Werner Grootaert ,  Miguel Guerra ,  Naiyong Jing

IPC分类号： C08J5/20

CPC分类号： C08J5/225 ,  C08J2327/12

摘要： A method is provided for making a crosslinked polymer electrolyte, typically in the form of a membrane for use as a polymer electrolyte membrane in an electrolytic cell such as a fuel cell, by trimerization of nitrile groups contained on groups pendant from the polymer. The resulting polymer electrolyte membrane comprises a highly fluorinated polymer comprising: a perfluorinated backbone, first pendent groups which comprise sulfonic acid groups, and crosslinks comprising trivalent groups according to the formula: The first pendent groups are typically according to the formula: —R1—SO3H, where R1 is a branched or unbranched perfluoroalkyl or perfluoroether group comprising 1-15 carbon atoms and 0-4 oxygen atoms, most typically —O—CF2—CF2—CF2—CF2—SO3H or —O—CF2—CF(CF3)—O—CF2—CF2—SO3H.

摘要翻译： 提供了一种制备交联聚合物电解质的方法，通常是通过聚合物悬浮在基团上的腈基的三聚作用，在电解池如燃料电池中用作聚合物电解质膜的膜形式。 所得聚合物电解质膜包括高度氟化的聚合物，其包含：全氟化骨架，包含磺酸基团的第一侧基和包含根据下式的三价基团的交联：第一侧基通常根据下式：-R

公开(公告)号：US20050107488A1

公开(公告)日：2005-05-19

申请号：US10712361

申请日：2003-11-13

申请人： Michael Yandrasits ,  Steven Hamrock ,  Naiyong Jing

发明人： Michael Yandrasits ,  Steven Hamrock ,  Naiyong Jing

IPC分类号： C08G2/00 ,  C08J3/28 ,  C08J5/22 ,  H01M8/10

CPC分类号： C08J5/2293 ,  C08J2327/18 ,  H01M8/1004 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  Y02P70/56

摘要： A method of making a crosslinked polymer is provided as well as the polymer so made, the method comprising the steps of: providing a highly fluorinated fluoropolymer, typically a perfluorinated fluoropolymer, comprising pendent groups which include a group according to the formula —SO2X, where X is F, Cl, Br, OH, or —O−M+, where M+ is a monovalent cation, and exposing said fluoropolymer to electron beam radiation so as to result in the formation of crosslinks. Typically, the method according to the present invention additionally comprises the step of: forming said fluoropolymer into a membrane, typically having a thickness of 90 microns or less, more typically 60 microns or less, and most typically 30 microns or less.

摘要翻译： 提供制备交联聚合物的方法以及如此制备的聚合物，该方法包括以下步骤：提供高度氟化的含氟聚合物，通常为全氟化含氟聚合物，其包含侧基，其包括根据式-SO _{2 X，其中X是F，Cl，Br，OH或-O - ，其中M + 是单价阳离子，并将所述含氟聚合物暴露于电子束辐射，从而导致交联的形成。 通常，根据本发明的方法另外包括以下步骤：将所述含氟聚合物形成膜，通常具有90微米或更小，更典型地为60微米或更小，最通常为30微米或更小的厚度。}

公开(公告)号：US20050119417A1

公开(公告)日：2005-06-02

申请号：US10984031

申请日：2004-11-09

申请人： Steven Hamrock ,  Naiyong Jing ,  Shane Mao ,  L. Hardy

发明人： Steven Hamrock ,  Naiyong Jing ,  Shane Mao ,  L. Hardy

IPC分类号： C08F8/26 ,  C08F8/36 ,  C08J5/22 ,  C08L27/16 ,  C08L27/22 ,  H01B1/06 ,  H01B13/00 ,  H01M8/02 ,  H01M8/10 ,  C08F14/18

CPC分类号： C08L27/22 ,  C08F8/26 ,  C08J5/225 ,  C08L27/16 ,  C08L2205/02 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1072 ,  Y02P70/56 ,  C08F14/18 ,  C08L2666/04

摘要： Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar-An, wherein X is selected from O, S or NR, where R is selected from H and C1-C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6-C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.

摘要翻译： 提供通过以下方式制备酸官能含氟聚合物的方法：a）用脱氟化氢剂使起始含氟聚合物脱氟化氢以形成不饱和含氟聚合物; b）将可酸化的亲核官能化剂加入到不饱和含氟聚合物的双键中; 和c）酸化所添加的酸化功能。 还提供了酸官能含氟聚合物及其离子传导膜，包括具有下式的侧基的酸官能含氟聚合物：-X-Ar-A N，其中X选自O，S或NR， 其中R选自H和任选取代的C 1 -C 30烷基或芳基，其中Ar是任选取代的C 6 -C 30芳族基团，其中A是酸性官能团或其盐，其中a可以独立地选自 为1,2或3。

公开(公告)号：US20050131096A1

公开(公告)日：2005-06-16

申请号：US10730238

申请日：2003-12-08

申请人： Naiyong Jing ,  Steven Hamrock

发明人： Naiyong Jing ,  Steven Hamrock

IPC分类号： C08J3/24 ,  C08J5/22 ,  C08G2/00

CPC分类号： C08J5/225 ,  C08J3/24 ,  C08J2327/12

摘要： A method is provided for obtaining crosslinked polymers, particularly fluorinated polymers having pendent sulfonic acid groups, by crosslinking through pendent groups which include a sulfonyl chloride group (—SO2Cl). The sulfonyl chloride group may be removed by application of electromagnetic radiation, typically in the ultraviolet band, or a radical initiator, leaving behind a radical which readily binds covalently to other polymer strands or to crosslinking agents to form crosslinks. Typically, the polymer is made by providing a polymer comprising pendent groups which include a group according to the formula —SO2F and converting at least a portion of the —SO2F groups to —SO2Cl. After crosslinking, the remaining —SO2F groups may be converted to sulfonic acid groups, yielding a crosslinked polymer electrolyte. Such crosslinked polymer electrolytes may be used to make polymer electrolyte membranes (PEM's) that may be used in electrolytic cells such as fuel cells.

摘要翻译： 提供一种用于获得交联聚合物，特别是具有侧链磺酸基的氟化聚合物的方法，通过通过包括磺酰氯基团（-SO 2 Cl）的侧基进行交联。 可以通过施加通常在紫外线带中的电磁辐射或自由基引发剂来除去磺酰氯基团，留下易于与其它聚合物链或交联剂共价结合以形成交联的基团。 通常，通过提供包含侧基的聚合物制备聚合物，所述侧基包括根据式-SO 2 F的基团，并将至少一部分-SO 2 F基团取代-SO 2 Cl。 交联后，剩余的-SO 2 F基团可以转化为磺酸基团，得到交联聚合物电解质。 这种交联聚合物电解质可用于制备可用于电解池如燃料电池的聚合物电解质膜（PEM）。