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1.发明授权Two-stage milling process for preparing cocrystals of titanyl fluorophthalocyanine and titanyl phthalocyanine, and electrophotographic element containing same 失效用于制备钛氧基酞菁和氧钛酞菁的共晶的两阶段研磨方法和含有它们的电子照相元件公开(公告)号：US07033716B2
公开(公告)日：2006-04-25
申请号：US10655388
申请日：2003-09-04
CPC分类号： C09B67/0035 , G03G5/0696
摘要： An amorphous mixture consisting essentially of TiOFPc and TiOPc and containing more than 75 weight percent of substantially chlorine-free TiOPc is produced by forming a mixture of crude crystalline TiOFPc and crude crystalline, substantially chlorine-free TiOPc that contains less than 80 weight percent TiOPc, treating the mixture under conditions effective to form a substantially amorphous mixture of TiOFPc and TiOPc containing less than 75 weight percent TiOPc, which is then treated with water, and dried. A further amount of crude crystalline, substantially chlorine-free TiOPc sufficient to form a new mixture containing more than 75 weight percent of substantially chlorine-free TiOPc is added, and the new mixture is converted to a substantially amorphous mixture of TiOFPc and TiOPc. A nanoparticulate cocrystalline composition is obtained by forming a slurry in an organic solvent of the dried substantially amorphous mixture, and wet milling the slurry to form the cocrystalline composition.
摘要翻译： 通过形成粗结晶TiOFPc和含有少于80重量％TiOPc的粗结晶，基本上无氯的TiOPc的混合物，生成基本上由TiOFPc和TiOPc组成并且含有大于75重量％的基本上无氯的TiOPc的无定形混合物， 在有效形成含有小于75重量％TiOPc的TiOFPc和TiOPc的基本无定形混合物的条件下处理混合物，然后用水处理，并干燥。 加入足量形成含有超过75重量％基本上无氯TiOPc的新混合物的粗结晶，基本上无氯的TiOPc，并将新混合物转化为基本上无定形的TiOFPc和TiOPc混合物。 通过在干燥的基本无定形混合物的有机溶剂中形成浆料，并湿法研磨浆料以形成共晶组合物，获得纳米颗粒共晶组合物。
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2.发明授权公开(公告)号：US07026084B2
公开(公告)日：2006-04-11
申请号：US10655113
申请日：2003-09-04
CPC分类号： C09B67/0085 , G03G5/0696
摘要： In a process for forming an amorphous TiOPc/TiOFPc pigment mixture containing a low concentration of TiOFPc, a mixture containing phthalonitrile and titanium tetrachloride is subjected to reaction conditions effective to form lightly chlorine-substituted crude crystalline Cl—TiOPc. The lightly chlorine-substituted crude crystalline Cl—TiOPc is combined with crude crystalline TiOFPc in a weight ratio from about 75:25 Cl—TiOPc:TiOFPc to about 99.5:0.5 Cl—TiOPc:TiOFPC to form a crude crystalline pigment mixture, which is treated under conditions effective to form a substantially amorphous pigment mixture of Cl—TiOPc and TiOFPc. The substantially amorphous mixture can subsequently be converted to a nanocrystalline Cl—TiOPc/TiOFPc pigment composition containing a low concentration of TiOFPc.
摘要翻译： 在形成含有低浓度TiOFPc的无定形TiOPc / TiOFPc颜料混合物的方法中，将含有邻苯二腈和四氯化钛的混合物进行有效形成轻氯取代的粗结晶Cl-TiOPc的反应条件。 将轻氯取代的粗结晶Cl-TiOPc与粗结晶TiOFPc以约75:25 Cl-TiOPc：TiOFPc至约99.5:0.5 Cl-TiOPc：TiOFPC的重量比组合以形成粗结晶颜料混合物，其为 在有效形成Cl-TiOPc和TiOFPc的基本上无定形的颜料混合物的条件下进行处理。 随后将基本上无定形的混合物转化成含有低浓度TiOFPc的纳米晶体Cl-TiOPc / TiOFPC颜料组合物。
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3.发明授权
公开(公告)号：US5766810A
公开(公告)日：1998-06-16
申请号：US734799
申请日：1996-10-23
CPC分类号： G03G5/0696 , C09B67/0035
摘要： Amorphous and cocrystallized unsubstituted titanyl phthalocyanine-titanyl fluorophthalocyanine compositions, preparation methods, and electrophotographic elements utilizing the compositions. The method has the steps of: admixing crude titanyl phthalocyanine and crude titanyl fluorophthalocyanine to provide a pigment mixture; increasing the amorphousness of the pigment mixture as determined by X-ray crystallography using X-radiation characteristic of Cu K.alpha. at a wavelength of 1.541 .ANG. of the Bragg angle 2.theta. to provide an amorphous pigment mixture; contacting the amorphous pigment mixture with a non-crystallizing solvent.
摘要翻译： 无定形和共结晶的未取代的氧钛酞菁 - 钛氧基酞菁组合物，制备方法和使用该组合物的电子照相元件。 该方法具有以下步骤：将粗钛酞菁和粗钛氧基酞菁混合以提供颜料混合物; 通过X射线晶体学使用在布拉格角2θ的波长为1.541的CuKα的X射线特性来确定颜料混合物的非晶性，以提供无定形颜料混合物; 使非晶颜料混合物与非结晶溶剂接触。
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4.发明授权
公开(公告)号：US5614342A
公开(公告)日：1997-03-25
申请号：US434148
申请日：1995-05-02
CPC分类号： G03G5/0696 , C09B67/0035
摘要： Cocrystallized titanyl phthalocyanine-titanyl fluorophthalocyanine compositions, preparation methods, and electrophotographic elements utilizing the compositions. The method has the steps of: admixing crude titanyl phthalocyanine and crude titanyl fluorophthalocyanine to provide a pigment mixture; increasing the amorphousness of the pigment mixture as determined by X-ray crystallography using X-radiation characteristic of Cu K.alpha. at a wavelength of 1.541 .ANG. of the Bragg angle 2.theta. to provide an amorphous pigment mixture; contacting the amorphous pigment mixture with organic solvent having a gamma.sub.c hydrogen bonding parameter of less than 8.0; and prior to the contacting, substantially excluding the amorphous pigment mixture from contact with organic solvent having a gamma.sub.c hydrogen bonding parameter greater than 9.0.
摘要翻译： 结晶的氧钛酞菁 - 钛氧基酞菁组合物，制备方法和使用该组合物的电子照相元件。 该方法具有以下步骤：将粗钛酞菁和粗钛氧基酞菁混合以提供颜料混合物; 通过X射线晶体学使用在布拉格角2θ的波长为1.541的CuKα的X射线特性来确定颜料混合物的非晶性，以提供无定形颜料混合物; 使无定形颜料混合物与具有小于8.0的gammac氢键参数的有机溶剂接触; 并且在接触之前，基本上排除非晶颜料混合物与具有大于9.0的gammac氢键参数的有机溶剂接触。
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5.发明授权
公开(公告)号：US5204198A
公开(公告)日：1993-04-20
申请号：US783590
申请日：1991-10-28
IPC分类号： G03G5/026
CPC分类号： G03G5/026
摘要： The present invention relates to a photoelectrographic element having a conductive layer in electrical contact with an acid photogenerating layer which is free of photopolymerizable materials and contains an electrically insulating binder and a nonionic sulfonic acid photogenerator. A method of forming images with this element is also disclosed.
摘要翻译： 本发明涉及一种光电元件，其具有与不含可光聚合材料并含有电绝缘粘合剂和非离子磺酸光电发生器的酸性光生电层电接触的导电层。 还公开了用该元件形成图像的方法。
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公开(公告)号：US5629418A
公开(公告)日：1997-05-13
申请号：US330396
申请日：1994-10-27
CPC分类号： C09B67/0016 , C09B67/0019 , G03G5/0696
摘要： Titanyl fluorophthalocyanines, and electrophotographic elements, and a method for preparing titanyl fluorophthalocyanine having the steps of: dissolving titanyl fluorophthalocyanine in acid to form a solution; admixing the solution and water to precipitate out amorphous titanyl fluorophthalocyanine; washing the amorphous titanyl fluorophthalocyanine until substantially all of the acid is removed; and retaining the amorphous titanyl fluorophthalocyanine under ambient conditions of wetness/dryness and temperature exclusive of conditions combining both dryness and a temperature of greater than about 50.degree. C.
摘要翻译： 钛氧基酞菁和电子照相元件，以及制备钛氧基酞菁的方法，其具有以下步骤：将钛氧基酞菁溶于酸中以形成溶液; 混合溶液和水以沉淀出无定形氧钛酞菁; 洗涤无定形氧钛酞菁直到基本上除去所有的酸; 并且在环境湿润/干燥和温度条件下保留无定形氧钛酞菁，不包括结合干燥和温度大于约50℃的条件。
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7.发明授权Newtonian, ultrasonic-insensitive charge generating layer dispersion composition and a method for producing the composition 失效牛顿型，超声波不敏感电荷产生层分散体组合物和制备该组合物的方法公开(公告)号：US07550240B2
公开(公告)日：2009-06-23
申请号：US10857307
申请日：2004-05-28
申请人： Michel F. Molaire , Jane R. Cowdery-Corvan , Lloyd Lobo , Theodore Zubil , Edward T. Miskinis , Dennis R. Fronheiser
发明人： Michel F. Molaire , Jane R. Cowdery-Corvan , Lloyd Lobo , Theodore Zubil , Edward T. Miskinis , Dennis R. Fronheiser
CPC分类号： G03G5/0596 , G03G5/0542 , G03G5/0546 , G03G5/056 , G03G5/0589 , G03G5/0592 , G03G5/0696
摘要： This invention relates to electrophotographic elements containing a layer formed from coating compositions containing a mixture of polymeric binders, including a polyvinyl butyral and a polyester ionomer and a crystalline mixture of unsubstituted titanyl phthalocyanine pigment, titanyl phthalocyanine pigments or mixtures thereof dispersed in the mixture. More particularly the invention relates to electrophotographic elements containing photoconductive layers which are especially useful for forming a photoconductive layer that is very uniform and highly absorptive at relatively thin coverage with good inter layer adhesion. The electrophotographic elements produced using this coating composition are particularly suited for high quality applications such as providing copy images with very low grain.
摘要翻译： 本发明涉及含有由包含聚乙烯醇缩丁醛和聚酯离聚物的聚合物粘合剂的混合物的涂料组合物形成的层的电子照相元件以及分散在该混合物中的未取代的氧钛酞菁颜料，钛氧基酞菁颜料或其混合物的结晶混合物。 更具体地，本发明涉及含有光电导层的电子照相元件，其特别可用于形成在相对薄的覆盖层具有良好的层间粘合性的非常均匀和高吸收性的光电导层。 使用该涂料组合物制备的电子照相元件特别适用于高质量应用，例如提供具有非常低的晶粒的复印图像。
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8.发明授权公开(公告)号：US07544382B2
公开(公告)日：2009-06-09
申请号：US11022210
申请日：2004-12-21
申请人： Michel F. Molaire
发明人： Michel F. Molaire
CPC分类号： B05D1/18 , G03G5/047 , G03G5/05 , G03G5/051 , G03G5/0525
摘要： A method for controlling the thickness and uniformity of a dip coated layer, using a coating apparatus in a normal coating environment, includes the following steps: forming under normal coating conditions of ambient temperature and relative humidity a series of coated layers on a metal substrate having a thickness of at least about 500 microns, using variations in coating solution viscosity m, coating substrate withdrawal speed v, capillary number Ca, coating solution surface tension S, and boiling point bp (a correlative of evaporation rate)of the coating solution solvent, a coated layer including at least a portion of uniform thickness T(even) and, optionally, a portion of non-uniform thickness L (uneven); statistically analyzing measurements carried out on the series of coated layers and generating the constants, a, b, c, d, and e for Equations 2, 3, and 4: T(even)=a+b(m*v) (Equation 2) L(uneven)=c+d*(v*bp)+e*(Ca*bp) (Equation 3) v(even)=−c/bp*(d+e*m/S) (Equation 4) using Equation 4, determining the coating speed v(even) producing the maximum thickness of a coated layer having a completely uniform thickness for a given set of coating solution characteristics; and using Equation 2, determining the thickness T(even) of the portion of the coated layer having uniform thickness for a given set of coating solution characteristics and the coating speed determined in step (c).
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9.发明申请公开(公告)号：US20070292799A1
公开(公告)日：2007-12-20
申请号：US11453408
申请日：2006-06-15
申请人： Michel F. Molaire
发明人： Michel F. Molaire
IPC分类号： G03G9/093
CPC分类号： G03G9/09335 , G03G9/09307 , G03G9/09364 , G03G9/09385
摘要： The present invention is an electrostatographic core shell toner which includes as a core material of at least two nonpolymeric compounds each independently corresponding to the structure (R1Y1)p[(Z1Y2)mR2Y3]nZ2Y4R3. M is zero or one, n is zero up to an integer at which said compound starts to become a polymer and p is an integer of from one to eight. Each of R1 and R3 is independently a monovalent aliphatic or cycloaliphatic hydrocarbon group an aromatic group or a multicyclic aromatic nucleus. Each of R2, Z1 and Z2 independently represent multivalent aliphatic or cycloaliphatic hydrocarbon groups or an aromatic group. Y1, Y2, Y3 and Y4 each independently represent one or more linking groups. The core material is surrounded by a shell that includes an amorphous matrix.
摘要翻译： 本发明是一种静电核心壳调色剂，其包含作为至少两种非聚合化合物的核心材料，每种非聚合化合物各自独立地对应于结构（R 1，Y 1， [（Z 1）2 2 Y 4 3 3 3 M为0或1，n为0，直至所述化合物开始变成聚合物并且p为1至8的整数的整数。 R 1和R 3各自独立地是一价脂族或脂环族烃基，芳基或多环芳族核。 R 2，Z 1和Z 2各自独立地表示多价脂族或脂环族烃基或芳族基团。 Y 1，Y 2，Y 3和Y 4各自独立地表示一个或多个连接基团。 核心材料被包含无定形基质的壳包围。
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10.发明授权Uniform cocrystals of titanyl fluorophthalocyanine and titanyl phthalocyanine formed in trichloroethane, and charge generating layer containing same 失效在三氯乙烷中形成的钛氧基酞菁和氧钛酞菁的均匀共晶体，以及含有它们的电荷产生层公开(公告)号：US07033715B2
公开(公告)日：2006-04-25
申请号：US10653573
申请日：2003-09-02
申请人： Michel F. Molaire
发明人： Michel F. Molaire
CPC分类号： G03G5/0696 , C09B67/0023
摘要： In a process for forming a nanoparticulate crystalline titanium phthalocyanine pigment composition, a titanium phthalocyanine pigment is contacted with substantially pure 1,1,2-trichloroethane (TCE) under conditions effective to convert the titanium phthalocyanine pigment to the nanoparticulate crystalline composition.
摘要翻译： 在形成纳米颗粒结晶钛酞菁颜料组合物的方法中，钛酞菁颜料在有效将钛酞菁颜料转化为纳米颗粒结晶组合物的条件下与基本上纯的1,1,2-三氯乙烷（TCE）接触。
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