Polyisocyanide derivative having controlled helical main chain structure
    5.
    发明授权
    Polyisocyanide derivative having controlled helical main chain structure 有权
    具有受控螺旋主链结构的聚异氰酸酯衍生物

    公开(公告)号:US07619109B2

    公开(公告)日:2009-11-17

    申请号:US12085696

    申请日:2006-12-01

    IPC分类号: C07C229/00

    摘要: Disclosed are: a method for production of a polyisocyanide derivative having a stable helical main chain structure with a right-handed or left-handed helix or a mixture thereof from a single type of monomer by polymerizing an aromatic isocyanate having a substituent harboring a structure —CONH in the aromatic ring and a hydrophobic moiety having 6 or more carbon atoms in a polymerization solvent, wherein the direction of the helix depends on the polarity of the polymerization solvent; a poly(aromatic isocyanide) derivative produced by the method; and an aromatic isocyanide which is useful as a monomer for use in the production of the poly(aromatic isocyanide) derivative.

    摘要翻译: 本发明公开了一种通过使含有具有结构的取代基的芳香族异氰酸酯聚合,由单一类型的单体制备具有右旋或左旋螺旋的稳定螺旋主链结构或其混合物的多异氰化物衍生物的方法, CONH和在聚合溶剂中具有6个或更多个碳原子的疏水部分,其中螺旋的方向取决于聚合溶剂的极性; 通过该方法制备的聚(芳族异氰化物)衍生物; 以及可用作制备聚(芳族异氰化物)衍生物的单体的芳族异氰化物。

    Three dimensional display
    6.
    发明授权
    Three dimensional display 失效
    三维显示

    公开(公告)号:US06252624B1

    公开(公告)日:2001-06-26

    申请号:US09041243

    申请日:1998-03-12

    IPC分类号: H04N947

    摘要: A three-dimensional display is provided with a display device alternatively displaying an image for the right eye and an image for the left eye in division of the images at predetermined time periods. A liquid crystal shutter disposed in front of the display device is operated in synchronization with image switching of the display device, and the image transmitted through the liquid crystal shutter is observed as a three-dimensional image through polarized glasses of which polarizing directions differ in the right and left from each other. The liquid crystal cell which serves as a liquid crystal shutter has a structure of a ferroelectric liquid crystal held between two sheets of resin film substrates and the ferroelectric liquid crystal contains more than 10 wt % of ferroelectric liquid crystal polymer so that it can respond to a large size display device and a high speed motion. A retardation plate to compensate elliptical polarization of the polarized glasses prevents lowering of contrast of the display due to the elliptical polarization peculiar to the operation mode of the liquid crystal cell and reduces a double reflection of the image, by setting the condition of |&Dgr;n1d1−&Dgr;n2d2|≦50 nm in the range of light wavelength from 400 nm through 900 nm, for the retardation (&Dgr;n1d1) of the retardation plate and a retardation (&Dgr;n2d2) of a liquid crystal cell forming the liquid crystal shutter.

    摘要翻译: 三维显示器设置有显示设备,以在预定时间段内分割图像交替地显示用于右眼的图像和用于左眼的图像。 设置在显示装置前面的液晶快门与显示装置的图像切换同步地操作,并且通过液晶快门传输的图像通过偏振方向不同的偏振眼镜被观察为三维图像 左右彼此。 用作液晶快门的液晶单元具有保持在两片树脂膜基板之间的铁电液晶的结构,铁电液晶含有大于10重量%的铁电液晶聚合物,使得其可以响应于 大尺寸显示装置和高速运动。 用于补偿偏振眼镜的椭圆偏振的延迟板防止由于液晶单元的操作模式所特有的椭圆偏振而使显示器的对比度降低,并且通过将| DELTAn1d1- 对于延迟板的延迟(DELTAn1d1)和形成液晶快门的液晶单元的延迟(DELTAn2d2),在从400nm到900nm的光波长的范围内的DELTAn2d2 | <= 50nm。

    Novel Polyacetylene Derivatives
    7.
    发明申请
    Novel Polyacetylene Derivatives 失效
    新型聚乙炔衍生物

    公开(公告)号:US20070260028A1

    公开(公告)日:2007-11-08

    申请号:US11661721

    申请日:2005-08-26

    IPC分类号: C08F38/00

    摘要: Novel optically active polyacetylene derivatives exhibiting liquid crystallinity; liquid crystal compositions containing the derivatives; and moldings thereof. Specifically, polyacetylene derivatives which have helical structure of rigid-rod shape and which exhibit a liquid crystal phase either in a solvent containing an organic solvent as the main component or in a molten state as well as electric field orientation; liquid crystal compositions containing the derivatives; and moldings thereof. More specifically, polyacetylene derivatives having helical structure of rigid-rod shape as represented by the general formula [1]; liquid crystal compositions containing the derivatives; and moldings thereof: wherein R1 and R2 are each independently aminocarbonyl of an amino acid having an ester linkage with C2-22 alkyl or carbonylamino of an amino acid having an amide linkage with C2-22 alkyl, the amino acid being achiral one, or chiral one of (S)- or (R)-configuration, or a racemic mixture composed of both antipodes; and X is a number satisfying the relationship: 0

    摘要翻译: 显示液晶性的新型光学活性聚乙炔衍生物; 含有衍生物的液晶组合物; 及其成型品。 具体地说,具有刚性棒状螺旋结构并且在以有机溶剂为主要成分或熔融状态的溶剂以及电场取向中呈液晶相的聚乙炔衍生物, 含有衍生物的液晶组合物; 及其成型品。 更具体地,由通式[1]表示的具有刚性棒状螺旋结构的聚乙炔衍生物; 含有衍生物的液晶组合物; 及其成型物:其中R 1和R 2各自独立地为与C 2-22-22烷基具有酯键的氨基酸的氨基羰基或 与C 2-22烷基具有酰胺键的氨基酸的羰基氨基,氨基酸是非手性的,或(S) - 或(R) - 构型的手性的,或由外消旋的混合物组成的 的两个对映体 X为满足0

    Polyacetylene derivatives
    8.
    发明授权
    Polyacetylene derivatives 失效
    聚乙炔衍生物

    公开(公告)号:US07691291B2

    公开(公告)日:2010-04-06

    申请号:US11661721

    申请日:2005-08-26

    IPC分类号: C09K19/00 C09K19/06 C09K19/52

    摘要: Novel optically active polyacetylene derivatives exhibiting liquid crystallinity; liquid crystal compositions containing the derivatives; and moldings thereof. Specifically, polyacetylene derivatives which have helical structure of rigid-rod shape and which exhibit a liquid crystal phase either in a solvent containing an organic solvent as the main component or in a molten state as well as electric field orientation; liquid crystal compositions containing the derivatives; and moldings thereof. More specifically, polyacetylene derivatives having helical structure of rigid-rod shape as represented by the general formula [1]; liquid crystal compositions containing the derivatives; and moldings thereof: wherein R1 and R2 are each independently aminocarbonyl of an amino acid having an ester linkage with C2-22 alkyl or carbonylamino of an amino acid having an amide linkage with C2-22 alkyl, the amino acid being achiral one, or chiral one of (S)- or (R)-configuration, or a racemic mixture composed of both antipodes; and X is a number satisfying the relationship: 0

    摘要翻译: 显示液晶性的新型光学活性聚乙炔衍生物; 含有衍生物的液晶组合物; 及其成型品。 具体地说,具有刚性棒状螺旋结构并且在以有机溶剂为主要成分或熔融状态的溶剂以及电场取向中呈液晶相的聚乙炔衍生物, 含有衍生物的液晶组合物; 及其成型品。 更具体地,由通式[1]表示的具有刚性棒状螺旋结构的聚乙炔衍生物; 含有衍生物的液晶组合物; 和其成型物:其中R 1和R 2各自独立地为与C 2-6烷基或与C 22-22烷基具有酰胺键的氨基酸的羰基氨基具有酯键的氨基酸的氨基羰基,氨基酸是非手性的,或手性的 (S) - 或(R) - 构型之一,或由两个对映体组成的外消旋混合物; X是满足关系的数:0

    Polyisocyanide Derivative Having Controlled Helical Main Chain Structure
    9.
    发明申请
    Polyisocyanide Derivative Having Controlled Helical Main Chain Structure 有权
    具有控制螺旋主链结构的聚异氰酸酯衍生物

    公开(公告)号:US20090030227A1

    公开(公告)日:2009-01-29

    申请号:US12085696

    申请日:2006-12-01

    IPC分类号: C07C233/01

    摘要: The object is to provide: a method for producing a polymer having a stable right-handed or left-handed helical structure from a single type of monomer in a per-selective manner and controlling the proportion between a polymer having the right-handed helical structure and a polymer having the left-handed helical structure; and a polymeric material which can be used for the formation of any of the right-handed and left-handed helical structures. Thus, disclosed are: a method for production of a polyisocyanide derivative having a stable helical main chain structure with a right-handed or left-handed helix or a mixture thereof from a single type of monomer by polymerizing an aromatic isocyanate having a substituent harboring a structure —CONH in the aromatic ring and a hydrophobic moiety having 6 or more carbon atoms in a polymerization solvent, wherein the direction of the helix depends on the polarity of the polymerization solvent; a poly(aromatic isocyanide) derivative produced by the method; and an aromatic isocyanide which is useful as a monomer for use in the production of the poly(aromatic isocyanide) derivative.

    摘要翻译: 本发明的目的是提供一种用于从单一类型的单体以每种选择的方式制备具有稳定的右旋或左旋螺旋结构的聚合物的方法,并且控制具有右旋螺旋结构的聚合物之间的比例 和具有左旋螺旋结构的聚合物; 以及可以用于形成任何右旋螺旋结构和左旋螺旋结构的聚合物材料。 因此,公开了以下方法:通过使含有具有取代基的取代基的芳族异氰酸酯聚合,从单一类型的单体制备具有具有右旋或左旋螺旋的稳定螺旋主链结构或其混合物的多异氰化物衍生物的方法 芳香环中的结构-CONH和在聚合溶剂中具有6个或更多个碳原子的疏水部分,其中螺旋的方向取决于聚合溶剂的极性; 通过该方法制备的聚(芳族异氰化物)衍生物; 以及可用作制备聚(芳族异氰化物)衍生物的单体的芳族异氰化物。