摘要:
A polylactic acid composition (A) comprising a polylactic acid component (B) comprising at least 90 mol % of an L-lactic acid unit and less than 10% of copolymerizing component units other than L-lactic acid, and a polylactic acid component (C) comprising at least 90 mol % of a D-lactic acid unit and less than 10 mol % of copolymerizing component units other than D-lactic acid, which is a mixed composition with a (B)/(C) weight ratio of between 10/90 and 90/10.
摘要:
It is an object of the present invention to produce a polylactic acid having a high molecular weight such as a weight average molecular weight (Mw) of more than 100,000 from which only a stereocomplex crystal is grown even by repeating melting and crystallization. The present invention is a process of producing a polylactic acid, including the steps of: (i) obtaining a solid by kneading together poly(L-lactic acid) and poly(D-lactic acid) at a temperature of 160 to 225° C. and crystallizing the kneaded product; and (ii) melt kneading the obtained solid.
摘要:
It is an object of the present invention to produce a polylactic acid having a high molecular weight such as a weight average molecular weight (Mw) of more than 100,000 from which only a stereocomplex crystal is grown even by repeating melting and crystallization. The present invention is a process of producing a polylactic acid, including the steps of: (i) obtaining a solid by kneading together poly(L-lactic acid) and poly(D-lactic acid) at a temperature of 160 to 225° C. and crystallizing the kneaded product; and (ii) melt kneading the obtained solid.
摘要:
An object of the present invention is to provide a composition containing polylactic acid and having improved blow moldability and a blow molded product thereof.The polylactic acid composition meets the following requirements (a) to (g) at the same time: (a) the weight average molecular weight must be 70,000 to 700,000; (b) the total content (metal content) of Sn atom, Ti atom, Al atom and Ca atom must be 3 to 20 ppm; (c) the content of P atom must be 3 to 3,000 ppm; (d) the (total number of gram-atoms of Sn, Ti, Al and Ca)/(number of gram-atoms of P) value must be 0.01 to 5; (e) the content of a compound having a molecular weight of 150 or less must be not more than 0.2 wt %; (f) the COOH terminal group concentration must be not more than 30 equivalents/ton; and (g) the following expressions (1) and (2) must be satisfied: 10 Pa·s
摘要:
Provided is a fiber containing a composition obtained by mixing a compound having at least a ring structure containing one carbodiimide group, the first nitrogen and second nitrogen thereof being linked together through a linking group, with a polymer compound having an acidic group. Also provided is a fiber structure made thereof. A fiber and a fiber structure, which have improved hydrolysis resistance and from which no free isocyanate compounds are produced, can be provided.
摘要:
Provided is a fiber containing a composition obtained by mixing a compound having at least a ring structure containing one carbodiimide group, the first nitrogen and second nitrogen thereof being linked together through a linking group, with a polymer compound having an acidic group. Also provided is a fiber structure made thereof. A fiber and a fiber structure, which have improved hydrolysis resistance and from which no free isocyanate compounds are produced, can be provided.
摘要:
A manufacturing apparatus of polylactic acid having at least an inlet and an outlet of a substance to be reacted and an exhaust port provided in a horizontal reaction vessel not having continuous rotating shafts in a direction of center line of a rotating shaft of a stirring blade provided in the reaction vessel and a manufacture method. By removing low molecular weight substance in the polylactic acid, high-quality polylactic acid can be stably manufactured.
摘要:
Provided is a button obtained by using a biomass material. The button has a heat deformation temperature of 160° C. or more, and high quality as follows; excellent in heat resistance, high in strength, excellent in dyeing properties, and also capable of having transparency to semi-transparency and/or glossiness.
摘要:
A microneedle and a microneedle array, which have both aspects of safety and easiness to use and can administer a predetermined dose of a medical agent without causing a pain by smoothly running into the skin surface layer of a patient, includes a frustum and a forward end portion thereon, the forward end portion having a forward end apex angle in the range of 15 to 60° and a forward end diameter in the range of 1 to 20 μm and satisfying the expression H/D≧5, where H is a total height of the microneedle, and D is a diameter of a bottom surface of the frustum).
摘要:
A flame retardant resin composition which has high flame retardancy and excellent physical properties and comprises a resin obtained from a plant-derived raw material and a molded article thereof.The flame retardant resin composition comprises: (A) 100 parts by weight of a resin component (component A) which contains at least 50 wt % of a resin (component A-1) obtained from a plant-derived raw material; and (B) 1 to 100 parts by weight of an organic phosphorus compound (component B) represented by the following formula (1). (in the above formula, X1 and X2 are the same or different and each an aromatic substituted alkyl group represented by the following formula (2): ALAr)n (2) in the above formula, AL is a branched or linear aliphatic hydrocarbon group having 1 to 5 carbon atoms, Ar is a phenyl group which may have a substituent, naphthyl group which may have a substituent or anthryl group which may have a substituent, n is an integer of 1 to 3, and Ar may be bonded to any carbon atom contained in AL.)