公开(公告)号：US07459216B2

公开(公告)日：2008-12-02

申请号：US10815164

申请日：2004-03-31

申请人： Min Zuo ,  Jenq-Tain Lin

发明人： Min Zuo ,  Jenq-Tain Lin

IPC分类号： B32B15/08 ,  C08G69/26

CPC分类号： C08G73/1042 ,  B32B15/08 ,  B32B27/34 ,  C08G73/1085 ,  H05K1/0346 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31721

摘要： A novel polyimide copolymer, which is a copolymer comprising two kinds of tetracarboxylic acid dianhydrides consisting of (A) isopropylidene-bis(4-phenyleneoxy-4-phthalic acid) dianhydride and (B) 3,3′,4,4′-biphenyltetracarboxylic acid dianhydride, and one kind of a diamine consisting of (C) 6-amino-2-(p-aminophenyl)benzimidazole, or two or three kinds of diamines consisting of component (C) and (D) at least one kind of diamines consisting of bis(4-amino-phenyl)ether (D1) and phenylenediamine (D2), and a metal laminate manufactured by laminating said polyimide copolymer to a metallic foil. The metal laminate comprising the novel polyimide copolymer as a layer on the metallic foil has a low curling susceptibility to cause curling, twisting, warping, etc. against temperature changes due to a low coefficient of linear thermal expansion of the polyimide copolymer, and also has satisfactory adhesiveness and thermal dimensional stability and a low water absorbability, and thus can be used as a suitable for a flexible, finely printed circuit board requiring a high dimensional stability.

摘要翻译： 一种新型的聚酰亚胺共聚物，它是包含由（A）异亚丙基 - 双（4-亚苯基氧基-4-邻苯二甲酸）二酐组成的两种四羧酸二酐和（B）3,3'，4,4'-联苯四羧酸 （C）6-氨基-2-（对氨基苯基）苯并咪唑组成的一种二胺或由组分（C）和（D）组成的二种或三种二胺，至少一种二胺 由双（4-氨基 - 苯基）醚（D1）和苯二胺（D2）组成的金属层压体，以及通过将所述聚酰亚胺共聚物层压到金属箔上制成的金属层压板。 由于聚酰亚胺共聚物的线性热膨胀系数低，所以包含作为金属箔上的层的新型聚酰亚胺共聚物的金属层叠体具有低卷曲敏感性，导致卷曲，扭曲，翘曲等导致温度变化，并且还具有 令人满意的粘合性和热尺寸稳定性和低吸水性，因此可以用作适合于需要高尺寸稳定性的柔性精细印刷电路板。

公开(公告)号：US06770733B2

公开(公告)日：2004-08-03

申请号：US10336343

申请日：2003-01-03

申请人： Min Zuo ,  Jenq-Tain Lin

发明人： Min Zuo ,  Jenq-Tain Lin

IPC分类号： C08G7310

CPC分类号： C08G73/1085 ,  C08G73/1042 ,  C08G73/1082 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31721

摘要： A film-formable polyimide copolymer, which comprises two kinds of tetracarboxylic acid dianhydride consisting of (A) pyromellitic acid dianhydride and (B) 3,3′,4,4′-benzophenonetetracarboxylic acid dianhydride, and (C) 6-amino-2-(p-aminophenyl)benzimidazole has a heat-resistant dimensional stability without any deterioration of mechanical properties inherent in the polyimide resin when used as a film.

摘要翻译： 一种可成膜聚酰亚胺共聚物，其包含由（A）均苯四酸二酐和（B）3,3'，4,4'-二苯甲酮四羧酸二酐组成的两种四羧酸二酐和（C）6-氨基-2 - （对 - 氨基苯基）苯并咪唑具有耐热尺寸稳定性，而在用作膜时聚酰亚胺树脂固有的机械性能没有任何劣化。

公开(公告)号：US07763321B2

公开(公告)日：2010-07-27

申请号：US12290518

申请日：2008-10-31

申请人： Min Zuo ,  Jenq-Tain Lin

发明人： Min Zuo ,  Jenq-Tain Lin

IPC分类号： B05D3/02

CPC分类号： C08G73/1042 ,  B32B15/08 ,  B32B27/34 ,  C08G73/1085 ,  H05K1/0346 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31721

摘要： A novel polyimide copolymer, which is a copolymer comprising two kinds of tetracarboxylic acid dianhydrides consisting of (A) isopropylidene-bis(4-phenyleneoxy-4-phthalic acid) dianhydride and (B) 3,3′,4,4′-biphenyltetracarboxylic acid dianhydride, and one kind of a diamine consisting of (C) 6-amino-2-(p-aminophenyl)benzimidazole, or two or three kinds of diamines consisting of component (C) and (D) at least one kind of diamines consisting of bis(4-amino-phenyl)ether (D1) and phenylenediamine (D2), and a metal laminate manufactured by laminating said polyimide copolymer to a metallic foil. The metal laminate comprising the novel polyimide copolymer as a layer on the metallic foil has a low curling susceptibility to cause curling, twisting, warping, etc. against temperature changes due to a low coefficient of linear thermal expansion of the polyimide copolymer, and also has satisfactory adhesiveness and thermal dimensional stability and a low water absorbability, and thus can be used as a suitable for a flexible, finely printed circuit board requiring a high dimensional stability.

摘要翻译： 一种新型的聚酰亚胺共聚物，它是包含由（A）异亚丙基 - 双（4-亚苯基氧基-4-邻苯二甲酸）二酐组成的两种四羧酸二酐和（B）3,3'，4,4'-联苯四羧酸 （C）6-氨基-2-（对氨基苯基）苯并咪唑组成的一种二胺或由组分（C）和（D）组成的二种或三种二胺，至少一种二胺 由双（4-氨基 - 苯基）醚（D1）和苯二胺（D2）组成的金属层压体，以及通过将所述聚酰亚胺共聚物层压到金属箔上制成的金属层压板。 由于聚酰亚胺共聚物的线性热膨胀系数低，所以包含作为金属箔上的层的新型聚酰亚胺共聚物的金属层叠体具有低卷曲敏感性，导致卷曲，扭曲，翘曲等导致温度变化，并且还具有 令人满意的粘合性和热尺寸稳定性和低吸水性，因此可以用作适合于需要高尺寸稳定性的柔性精细印刷电路板。

公开(公告)号：US20090133907A1

公开(公告)日：2009-05-28

申请号：US12290523

申请日：2008-10-31

申请人： Min Zuo ,  Jenq-Tain Lin

发明人： Min Zuo ,  Jenq-Tain Lin

IPC分类号： H05K1/00 ,  C08G69/26

CPC分类号： C08G73/1042 ,  B32B15/08 ,  B32B27/34 ,  C08G73/1085 ,  H05K1/0346 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31721

摘要： A novel polyimide copolymer, which is a copolymer comprising two kinds of tetracarboxylic acid dianhydrides consisting of (A) isopropylidene-bis(4-phenyleneoxy-4-phthalic acid) dianhydride and (B) 3,3′,4,4′-biphenyltetracarboxylic acid dianhydride, and one kind of a diamine consisting of (C) 6-amino-2-(p-aminophenyl)benzimidazole, or two or three kinds of diamines consisting of component (C) and (D) at least one kind of diamines consisting of bis(4-amino-phenyl)ether (D1) and phenylenediamine (D2), and a metal laminate manufactured by laminating said polyimide copolymer to a metallic foil. The metal laminate comprising the novel polyimide copolymer as a layer on the metallic foil has a low curling susceptibility to cause curling, twisting, warping, etc. against temperature changes due to a low coefficient of linear thermal expansion of the polyimide copolymer, and also has satisfactory adhesiveness and thermal dimensional stability and a low water absorbability, and thus can be used as a suitable for a flexible, finely printed circuit board requiring a high dimensional stability.

公开(公告)号：US20090136671A1

公开(公告)日：2009-05-28

申请号：US12290518

申请日：2008-10-31

申请人： Min Zuo ,  Jenq-Tain Lin

发明人： Min Zuo ,  Jenq-Tain Lin

IPC分类号： B05D3/00

CPC分类号： C08G73/1042 ,  B32B15/08 ,  B32B27/34 ,  C08G73/1085 ,  H05K1/0346 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31721

摘要： A novel polyimide copolymer, which is a copolymer comprising two kinds of tetracarboxylic acid dianhydrides consisting of (A) isopropylidene-bis(4-phenyleneoxy-4-phthalic acid) dianhydride and (B) 3,3′,4,4′-biphenyltetracarboxylic acid dianhydride, and one kind of a diamine consisting of (C) 6-amino-2-(p-aminophenyl)benzimidazole, or two or three kinds of diamines consisting of component (C) and (D) at least one kind of diamines consisting of bis(4-amino-phenyl)ether (D1) and phenylenediamine (D2), and a metal laminate manufactured by laminating said polyimide copolymer to a metallic foil. The metal laminate comprising the novel polyimide copolymer as a layer on the metallic foil has a low curling susceptibility to cause curling, twisting, warping, etc. against temperature changes due to a low coefficient of linear thermal expansion of the polyimide copolymer, and also has satisfactory adhesiveness and thermal dimensional stability and a low water absorbability, and thus can be used as a suitable for a flexible, finely printed circuit board requiring a high dimensional stability.

摘要翻译： 一种新型的聚酰亚胺共聚物，它是包含由（A）异亚丙基 - 双（4-亚苯基氧基-4-邻苯二甲酸）二酐组成的两种四羧酸二酐和（B）3,3'，4,4'-联苯四羧酸 （C）6-氨基-2-（对氨基苯基）苯并咪唑组成的一种二胺或由组分（C）和（D）组成的二种或三种二胺，至少一种二胺 由双（4-氨基 - 苯基）醚（D1）和苯二胺（D2）组成的金属层压体，以及通过将所述聚酰亚胺共聚物层压到金属箔上制成的金属层压板。 由于聚酰亚胺共聚物的线性热膨胀系数低，所以包含作为金属箔上的层的新型聚酰亚胺共聚物的金属层叠体具有低卷曲敏感性，导致卷曲，扭曲，翘曲等导致温度变化，并且还具有 令人满意的粘合性和热尺寸稳定性和低吸水性，因此可以用作适合于需要高尺寸稳定性的柔性精细印刷电路板。

公开(公告)号：US06582885B2

公开(公告)日：2003-06-24

申请号：US09982634

申请日：2001-10-18

申请人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Nobuyuki Sensui

发明人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Nobuyuki Sensui

IPC分类号： G03F7037

CPC分类号： C08G73/1042 ,  C08G73/106 ,  C08G77/455 ,  Y10S430/106 ,  Y10S430/128

摘要： Polyimide is produced by reacting two kinds of diamine compounds consisting of diaminopolysiloxane and a carboxyl group-containing diamine or three kinds of diamine compounds consisting of diaminopolysiloxane, a carboxyl group-containing diamine and an aromatic or alicyclic diamine with a dicarboxylic acid anhydride having a 2,5-dioxotetrahydrofuryl group as one acid anhydride group, thereby once forming a polyamic acid, and subjecting the polyamic acid to polyimidization reaction. The resulting polyimide itself is soluble in low boiling organic solvents for general purpose use, typically methyl ethyl ketone. A photosensitive composition comprising the polyimide, a photo crosslinking agent and a photo acid-generating agent forms a negative type polyimide pattern upon development with an aqueous alkali solution.

公开(公告)号：US06486290B1

公开(公告)日：2002-11-26

申请号：US09259069

申请日：1999-02-26

申请人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Nobuyuki Sensui

发明人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Nobuyuki Sensui

IPC分类号： G03F7037

CPC分类号： C08G73/1042 ,  C08G73/106 ,  C08G77/455 ,  Y10S430/106 ,  Y10S430/128

摘要： Polyimide is produced by reacting two kinds of diamine compounds consisting of diaminopolysiloxane and a carboxyl group-containing diamine or three kinds of diamine compounds consisting of diaminopolysiloxane, a carboxyl group-containing diamine and an aromatic or alicyclic diamine with a dicarboxylic acid anhydride having a 2,5-dioxotetrahydrofuryl group as one acid anhydride group, thereby once forming a polyamic acid, and subjecting the polyamic acid to polyimidization reaction. The resulting polyimide itself is soluble in low boiling organic solvents for, general purpose use, typically methyl ethyl ketone. A photosensitive composition comprising the polyimide, a photo crosslinking agent and a photo acid-generating agent forms a negative type polyimide pattern upon development with an aqueous alkali solution.

摘要翻译： 聚酰亚胺通过将由二氨基聚硅氧烷和含羧基二胺组成的二种二胺化合物或由二氨基聚硅氧烷，含羧基的二胺和芳族或脂环族二胺组成的三种二胺化合物与二羧酸酐组成的二种二胺化合物 ，5-二氧代四氢呋喃基作为一个酸酐基，从而一次形成聚酰胺酸，并使聚酰胺酸进行聚酰亚胺化反应。 所得聚酰亚胺本身可溶于低沸点有机溶剂，通常用途，通常为甲基乙基酮。 包含聚酰亚胺，光交联剂和光酸发生剂的光敏组合物在用碱水溶液显影时形成负型聚酰亚胺图案。

公开(公告)号：US06245484B1

公开(公告)日：2001-06-12

申请号：US09496098

申请日：2000-02-01

申请人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Nobuyuki Sensui

发明人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Nobuyuki Sensui

IPC分类号： G03C173

CPC分类号： C08G73/1042 ,  C08G73/106 ,  C08G77/455 ,  Y10S430/106 ,  Y10S430/128

摘要： Polyimide is produced by reacting two kinds of diamine compounds consisting of diaminopolysiloxane and a carboxyl group-containing diamine or three kinds of diamine compounds consisting of diaminopolysiloxane, a carboxyl group-containing diamine and an aromatic or alicyclic diamine with a dicarboxylic acid anhydride having a 2,5-dioxotetrahydrofuryl group as one acid anhydride group, thereby once forming a polyamic acid, and subjecting the polyamic acid to polyimidization reaction. The resulting polyimide itself is soluble in low boiling organic solvents for general purpose use, typically methyl ethyl ketone. A photosensitive composition comprising the polyimide, a photo crosslinking agent and a photo acid-generating agent forms a negative type polyimide pattern upon development with an aqueous alkali solution.

摘要翻译： 聚酰亚胺通过将由二氨基聚硅氧烷和含羧基二胺组成的二种二胺化合物或由二氨基聚硅氧烷，含羧基的二胺和芳族或脂环族二胺组成的三种二胺化合物与二羧酸酐组成的二种二胺化合物 ，5-二氧代四氢呋喃基作为一个酸酐基，从而一次形成聚酰胺酸，并使聚酰胺酸进行聚酰亚胺化反应。 所得聚酰亚胺本身可溶于用于通用目的的低沸点有机溶剂，通常为甲基乙基酮。 包含聚酰亚胺，光交联剂和光酸发生剂的光敏组合物在用碱水溶液显影时形成负型聚酰亚胺图案。

公开(公告)号：US6077924A

公开(公告)日：2000-06-20

申请号：US259479

申请日：1999-02-26

申请人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Nobuyuki Sensui

发明人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Nobuyuki Sensui

IPC分类号： G03F7/037 ,  C08G73/10 ,  C08G77/455 ,  G03F7/038 ,  C08G69/26 ,  C08G77/04

CPC分类号： C08G77/455 ,  C08G73/1042 ,  C08G73/106

摘要： Polyimide is produced by reacting two kinds of diamine compounds consisting of diaminopolysiloxane and a hydroxyl group-containing diamine or three kinds of diamine compounds consisting of diaminopolysiloxane, a hydroxyl group-containing diamine and an aromatic or alicyclic diamine with a dicarboxylic acid anhydride having a 2,5-dioxotetrahydrofuryl group as one acid anhydride group, thereby once forming a polyamic acid, and subjecting the polyamic acid to polyimidization reaction. The resulting polyimide itself is soluble in low boiling organic solvents for general purpose use, typically methyl ethyl ketone. A photosensitive composition comprising the polyimide, a photo crosslinking agent and a photo acid-generating agent forms a negative type polyimide pattern upon development with an aqueous alkali solution.

摘要翻译： 聚酰亚胺通过将由二氨基聚硅氧烷和含羟基的二胺组成的二种二胺化合物或由二氨基聚硅氧烷，含羟基的二胺和芳香族或脂环族二胺组成的三种二胺化合物与二羧酸酐 ，5-二氧代四氢呋喃基作为一个酸酐基，从而一次形成聚酰胺酸，并使聚酰胺酸进行聚酰亚胺化反应。 所得聚酰亚胺本身可溶于用于通用目的的低沸点有机溶剂，通常为甲基乙基酮。 包含聚酰亚胺，光交联剂和光酸发生剂的光敏组合物在用碱水溶液显影时形成负型聚酰亚胺图案。

公开(公告)号：US5986038A

公开(公告)日：1999-11-16

申请号：US35324

申请日：1998-03-05

申请人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Haruyoshi Tatsu ,  Lev Moiseevich Kogan ,  Anatoli Stepanovich Skornyakov ,  Tat'yana Borisovna Zapevalova ,  Olga Viktorinovna Blagodatova ,  Sergei Vasil'evich Sokolov

发明人： Lin-chiu Chiang ,  Jenq-Tain Lin ,  Haruyoshi Tatsu ,  Lev Moiseevich Kogan ,  Anatoli Stepanovich Skornyakov ,  Tat'yana Borisovna Zapevalova ,  Olga Viktorinovna Blagodatova ,  Sergei Vasil'evich Sokolov

IPC分类号： C08G59/40 ,  C08G73/00 ,  C08L63/00 ,  C08L79/02 ,  C09J127/16 ,  C09J163/00 ,  C09J179/08 ,  C08L79/00

CPC分类号： C09J127/16 ,  C08L63/00 ,  C08L79/02

摘要： An adhesive composition comprising a fluorinated elastomer having dicyclopropane rings formed by reaction of chloroform with unsaturated bonds introduced into the molecule of fluorinated elastomer by an alkali treatment, as an adhesive component has a good room temperature adhesiveness and very distinguished electric characteristics perse such as a high insulation resistance, a low dielectric constant, a low dielectric loss tangent, etc. and is effectively applied to adhesion of electronic materials in printed substrates, etc.

摘要翻译： 作为粘合剂组分，含有通过氯仿与通过碱处理引入氟化弹性体分子中的不饱和键反应形成的具有二环丙烷环的氟化弹性体的粘合剂组合物具有良好的室温粘合性和非常显着的电特性如高 绝缘电阻，低介电常数，低介电损耗角正切等，并且有效地应用于印刷基板等中的电子材料的附着。