Solid catalyst component for polymerization of olefins, catalyst comprising the same and use thereof

    公开(公告)号:US07388061B2

    公开(公告)日:2008-06-17

    申请号:US10503515

    申请日:2003-01-30

    IPC分类号: C08F4/42

    摘要: The present invention provides a solid catalyst component for the polymerization of olefins, comprising magnesium, titanium, a halogen and an electron donor, wherein said electron donor comprises at least one selected from the group consisting of ester of polyol of the formula (I): R1CO—O—CR3R4—A—CR5R6—O—CO—R2  (I) wherein, R1 and R2 groups, which may be identical or different, can be substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R3-R6 groups, which may be identical or different, can be selected from the group consisting of hydrogen, halogen or substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R1-R6 groups optionally contain one or more hetero-atoms replacing carbon, hydrogen atom or the both, said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom, two or more of R3-R6 groups can be linked to form saturated or unsaturated monocyclic or polycyclic ring A is a single bond or bivalent linking group with chain length between two free radicals being 1-10 atoms, wherein said bivalent linking group is selected from the group consisting of aliphatic, alicyclic and aromatic bivalent radicals, and can carry C1-C20 linear or branched substituents one or more of carbon atom and/or hydrogen atom on above-mentioned bivalent linking group and substituents can be replaced by a hetero-atom selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus, and halogen atom, and two or more said substituents on the linking group as well as above-mentioned R3-R6 groups can be linked to form saturated or unsaturated monocyclic or polycyclic ring.

    Silicon ether compound, a method for the preparation thereof and use thereof
    10.
    发明授权
    Silicon ether compound, a method for the preparation thereof and use thereof 有权
    硅醚化合物,其制备方法和用途

    公开(公告)号:US06822109B2

    公开(公告)日:2004-11-23

    申请号:US10620508

    申请日:2003-07-16

    IPC分类号: C07F704

    摘要: The present invention relates to a silicon ether compound having general formula (I): wherein, R and R1-R10 groups, which may be Identical or different, represent hydrogen, halogen, C1-C20 linear or branched alkyl, C3-C20 cycloalkyl, C8-C20 aryl, C7-C20 alkaryl or C7-C20 aralkyl group, and two or more R groups can be linked to form saturated or unsaturated condensed ring structure which is optionally substituted by a group having the same meanings with that of R1, R and R1-R10 groups optionally contain one or more hetero-atoms replacing carbon atom, hydrogen atom or the both, said heteroatom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom, and A represents carbon atom or silicon atom. The present invention also relates to a method for the preparation of the silicon ether compounds of general formula (I) and a process for polymerization of olefins.

    摘要翻译: 本发明涉及具有通式(I)的硅醚化合物:其中,R和R 1 -R 10基团可以相同或不同,表示氢,卤素,C 1 -C 20直链或支链烷基,C 3 -C 20环烷基, C8-C20芳基,C7-C20烷芳基或C7-C20芳烷基,并且两个或更多个R基团可连接形成饱和或不饱和稠环结构,其任选被具有与R 1,R 并且R 1 -R 10基团任选地含有一个或多个取代碳原子,氢原子或二者的杂原子,所述杂原子选自氮,氧,硫,硅,磷和卤素原子,A表示碳原子 或硅原子。 本发明还涉及制备通式(I)的硅醚化合物的方法和烯烃聚合方法。