Abstract:
A monomer composition contains: a tin-free catalyst (A); and a (meth)acrylate monomer (D) that is a reaction product of an iso(thio)cyanate compound (B) and an alcohol compound (C). In this monomer composition, a content of an amide compound containing at least one of a carboxylic acid amide group or a sulfonamide group is less than 1 ppm by mass with respect to a total amount of the monomer composition.
Abstract:
It is an object of the present invention to provide a monomer which can provide a cured product having both high toughness and rigidity. The present invention is a (meth)acrylate (D) which is a reaction product of a thiol compound (A) having two or more mercapto groups; an iso(thio)cyanate compound (B) having two or more iso(thio)cyanato groups; and a hydroxy (meth)acrylate compound (C) having one or more polymerizable groups.
Abstract:
Disclosed is a polymerizable composition for an optical material containing polyisocyanate (a) including aliphatic polyisocyanate (a1) and a modified aliphatic polyisocyanate (a2); and polythiol (b) having a di- or higher functional thiol group, in which the modified aliphatic polyisocyanate (a2) is contained in the polyisocyanate (a) in the amount of less than or equal to 60 weight %.
Abstract:
An optical material of the present invention has the following characteristics (1) to (4) in a transmittance curve which is measured at a thickness of 2 mm of the optical material. (1) the transmittance curve has a maximum transmittance value at 400 nm to 440 nm and the maximum transmittance thereof is 50% or more. (2) the transmittance curve has a minimum transmittance value at 471 nm to 500 nm. (3) The transmittance at 540 nm is 60% or more. (4) The minimum transmittance value at 471 nm to 500 nm is seven-tenths or less of the maximum transmittance at 400 nm to 440 nm and is seven-tenths or less of the transmittance at 540 nm.
Abstract:
A (meth)acrylate includes a reaction product of a thiol compound containing two or more thiol groups, and a (meth)acrylate compound containing two or more (meth)acryloyloxy groups.
Abstract:
A polymerizable composition for an optical material including (A) an isocyanate compound; (B) an active hydrogen compound; and (C) one or more types of ultraviolet absorber represented by General Formula (1) and having a maximum absorption peak in a range of equal to or more than 350 nm and equal to or less than 370 nm. (In General Formula (1) above, R1 and R2 represent, an alkyl group having 1 to 8 carbon atoms and may be same or different from each other, a plurality of R1 present or a plurality of R2 present may be same or different, m represents an integer of 0 to 3, n represents an integer of 0 to 3, and R3 represents a functional group having 2 to 15 carbon atoms which includes an ester bond.)
Abstract:
An internal release agent includes at least one phosphodiester represented by the following general formula (1). In the formula, R1 and R2 independently represent a hydrocarbon group having 1 to 30 carbon atoms, which is optionally substituted with at least one hydroxyl group, and R3 represents an alkylene group having 2 to 4 carbon atoms. A plurality of R3's may be the same as or different from each other. M represents a hydrogen atom, an ammonium ion, an alkali metal ion, or a monovalent/divalent alkali earth metal ion, and n is an integer of 1 to 60.
Abstract:
A method for producing meta-xylylenediamines includes a reaction step in which monohalogenated benzenes, formaldehydes, and an amide compound having a primary amide group or a secondary amide group are allowed to react in the presence of an acidic liquid, a dehalogenation step in which the halogen atom derived from the monohalogenated benzenes is replaced with a hydrogen atom, and a deprotection step in which the primary amide group or the secondary amide group derived from the amide compound is converted to an amino group. In the reaction step, the acidic liquid contains inorganic acid, the equivalent ratio of the hydrogen atom of the inorganic acid relative to the monohalogenated benzenes is more than 16; the acidic liquid has an inorganic acid concentration of more than 80 mass %; and the reaction temperature is more than 40° C.
Abstract:
A method for producing meta-xylylenediisocyanates includes a reaction step in which monohalogenated benzenes, formaldehydes, and an amide compound represented by general formula (1) below are allowed to react in the presence of an acidic liquid to produce a bisamide compound; a dehalogenation step in which in the bisamide compound, the halogen atom derived from the monohalogenated benzenes is replaced with a hydrogen atom; and a thermal decomposition step in which the bisamide compound from which the halogen atom is eliminated is subjected to thermal decomposition. In the reaction step, the acidic liquid contains inorganic acid, the equivalent ratio of the hydrogen atom of the inorganic acid relative to the monohalogenated benzenes is more than 14, the acidic liquid has an inorganic acid concentration of more than 90 mass %, and the reaction temperature is more than 10° C. General formula (1): wherein R1 represents an alkoxy group or an amino group.
Abstract:
A method for producing a (meth)acrylamide compound, comprising synthesizing a (meth)acrylamide compound (X) by reacting a (meth)acrylic acid with a primary amine compound in the presence of a condensing agent.